FLUORO

作品数：277被引量：340H指数：8
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相关领域：理学医药卫生更多>>
相关作者：胡祥国王韧郑军李洪鹏佟晓杰更多>>
相关机构：大连理工大学中南民族大学中国医科大学江西师范大学更多>>
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相关基金：国家自然科学基金国家重点基础研究发展计划中国博士后科学基金北京市自然科学基金更多>>
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Selective Oxidation of Tertiary Alcohols to Ketones via Synergistic Catalysis of (NH_(4))_(2)Ce(NO_(3))_(6) and Trifluoroacetic Acid With Oxygen
《cMat》2025年第1期1-8,共8页Xin-Rui Xiao Ying Chen Feng-Lin Chen Xiao-Xue Li Hong-Wei Zhou Chao Chen Hong-En Cao Lei Yu 
We thank the Cooperation Project of Yangzhou City with Yangzhou University(No.YZ2023209);Jiaxing Key Laboratory for Creation of Animal Models&Synthesis of Lead Compounds of New Drug(No.jxsz21006);Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)for financial support.
Tertiary alcohols are generally considered difficult to oxidize.However,in this work,it was found that catalyzed by (NH_(4))_(2)Ce(NO_(3))_(6)(CAN)and in the presence of catalytic trifluoroacetic acid(TFA),the selecti...
关键词：CERIUM oxidation synergistic catalysis tertiary alcohol trifluoroacetic acid 
Tuning the ion-dipole interactions between fluoro and carbonyl(EC)by electrolyte design for stable lithium metal batteries
《Chinese Chemical Letters》2025年第1期579-584,共6页Guihuang Fang Ying Liu Yangyang Feng Ying Pan Hongwei Yang Yongchuan Liu Maoxiang Wu 
supported by National Natural Science Foundation of China(Nos.12275274 and 22209182);the Fujian Provincial STS program supporting project of Chinese Academy of sciences(No.2022T3001)。
Ethylene carbonate(EC)is the conventional and promising solvent to achieve high energy lithium metal battery.However,the innate low energy level of lowest unoccupied molecular orbital(LUMO)in EC makes it incompatible ...
关键词：Lithium-ion batteries LiMn_(0.8)Fe_(0.2)PO_(4) HIGH-VOLTAGE Solvation structure Ethylene carbonate Bis(2 2 2-trifluoroethyl)carbonate 
Lithium Salt Combining Fluoroethylene Carbonate Initiates Methyl Methacrylate Polymerization Enabling Dendrite-Free Solid-State Lithium Metal Battery
《Energy & Environmental Materials》2024年第6期50-59,共10页Xue Ye Jianneng Liang Baorong Du Yongliang Li Xiangzhong Ren Dazhuan Wu Xiaoping Ouyang Qianling Zhang Jianhong Liu 
funded by the National Key Research and Development Program of China(no.2020YFC1909604);Shenzhen Key Projects of Technological Research(JSGG20200925145800001);Shenzhen Basic Research Project(no.JCYJ20190808145203535).
This work demonstrates a novel polymerization-derived polymer electrolyte consisting of methyl methacrylate,lithium bis(trifluoromethanesulfonyl)imide and fluoroethylene carbonate.The polymerization of MMA was initiat...
关键词：in situ polymerization lithium anode polymer electrolyte solid-state lithium batteries 
Biological Evaluation of a Novel 2’-Fluoro Derivative 5-Azacytidine as a Potent DNA Methyltransferase Inhibitor
《Pharmacology & Pharmacy》2024年第11期388-402,共15页Elena Kalinichenko Tatyana Bozhok Roman Zilberman Alesya Panibrat 
Background: DNA methyltransferases (DNMTs) are key epigenetic regulatory enzymes involved in the expression of many genes and are considered as an attractive target for cancer treatment, especially hematological malig...
关键词：Drug Discovery DECITABINE 2’-Fluorodeoxy-Arabino Analog DNA Methyltransferase Enzyme Inhibition Cell Cycle Apoptosis 
The Smallest Monofluorodiazoethane Reagent and Its[3+2]Cycloaddition Reactions
《CCS Chemistry》2024年第11期2825-2834,共10页Xiaodong Tang Ming-Yue He Ran Guo Hao-Nan Liu Jing Nie Ilan Marek Jun-An Ma Fa-Guang Zhang 
financial support provided by the National Natural Science Foundation of China(NSFC,grant nos.92156025 and 22271212);the National Key Research and Development Program of China(grant nos.2019YFA0905100 and 2021YFF0701700);X.T.thanks the China Postdoctoral Science Foundation(grant no.2022M712350).
Given the widespread applications of fluorinated substances in pharmaceuticals,biology,and materials,the development of fluorine-containing building blocks remains an important topic in organic chemistry.In the repert...
关键词：monofluoromethyl group diazo reagent cycloaddition reaction TETRAZOLE ISOXAZOLE fluorine chemistry 
刚柔并济的仿生凝胶聚合物电解质助力稳定的锂电池
《Science China Materials》2024年第7期2256-2265,共10页周天易 徐若晨 曹曦 张江涛 王佳运 黄茹玲 平小凡 白盼星 孙周婷 刘明义 王晓龙 
supported by the Huaneng Clean Energy Research Institute Found Project(CERI/TU-23-CERI01).
凝胶聚合物电解质(GPE)因其优良的热稳定性和卓越的电化学性能而具备增强锂离子电池性能的潜力,从而受到越来越多的认可.尽管其具有上述优点,但传统GPE的实际应用通常因其溶胀性和有限的机械强度而受到阻碍.为了解决这些问题,本项研究...
关键词：gel polymer electrolyte polyethylene oxide(PEO) poly(vinylidene fluoride-co-hexafluoropropylene)(PVDF-HFP) Kevlar fiber cartilage structure 
Effects of water molecules on luminescence in europium and terbium coordination polymers with p-fluorobenzoic acid as ligand
《Journal of Rare Earths》2024年第7期1258-1264,I0003,共8页Xiaoqi Zhao Puyan Hao Yami Ling Mengzhen Jia Rui Zhu Jiawen Liu Qiang Xu Jianhong Zhou 
Project supported by the Natural Science Foundation of Shaanxi Province(2021JQ-799);Key Scientific Research Plan of Shaanxi Provincial Department of Education(22JC001)。
Our previous experimental observations show that the crystal structure of lanthanide luminescent complexes synthesized in aqueous solution usually contains a large number of coordination water molecules or free water ...
关键词：Lanthanide complexes Photoluminescence Luminescent quenching Rare earths 
Synergistic coupling among Mg_(2)B_(2)O_(5),polycarbonate and N,Ndimethylformamide enhances the electrochemical performance of PVDF-HFP-based solid electrolyte
《Journal of Energy Chemistry》2024年第7期158-168,共11页Yutong Jing Qiang Lv Yujia Chen Bo Wang Bochen Wu Cheng Li Shengbo Yang Zhipeng He Dianlong Wang Huakun Liu Shixue Dou 
supported by the National Natural Science Foundation of China(Grant Nos.51604089,51874110,22173066,and 21903058);Natural Science Foundation of Heilongjiang Province(Grant No.YQ2021B004).
Polymer solid electrolytes(SPEs)based on the[solvate-Li+]complex structure have promising prospects in lithium metal batteries(LMBs)due to their unique ion transport mechanism.However,the solvation structure may compr...
关键词：Composite solid electrolytes Safe Li metal batteries Synergistic coupling effect Poly(vinylidene fluoride-co-hexafluoropro pylene) 
Improved performance of LiMn_(0.8)Fe_(0.2)PO_(4) by addition of fluoroethylene carbonate electrolyte additive
《Chinese Chemical Letters》2024年第6期229-233,共5页Guihuang Fang Wei Chen Hongwei Yang Haisheng Fang Chuang Yu Maoxiang Wu 
supported by National Natural Science Foundation of China(Nos.51874155 and 52177214);the Fujian Provincial STS program supporting project of Chinese Academy of sciences(No.2022T3001)。
The addition of electrolyte additives is an effective strategy for tuning the property of the electrolyte to engineer the electrode/electrolyte interface,and there exist obvious discrepancies regarding the effect of f...
关键词：Lithium-ion batteries LiMn_(0.8)Fe_(0.2)PO_(4) CATHODE Electrolyte additives Fluoroethylene carbonate 
Characteristics of perfluoromethyl vinyl ether:A new eco-friendly alternative gas for SF_(6)被引量：1
《High Voltage》2024年第3期509-517,共9页Song Xiao Yijiang Chen Mingjun Tang Shuangshuang Tian Haoran Xia Yifan Wang Ju Tang Yi Li Xiaoxing Zhang 
National Natural Science Foundation of China,Grant/Award Number:52377156。
The exploration of eco-friendly insulating gas to substitute the most potent greenhouse gas sulphur hexafluoride(SF6)has consistently garnered significant attention.Herein,the au-thors evaluated the feasibility of uti...
关键词：SURFACE DIELECTRIC VINYL 
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