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INTERMEDIATES: 作品数：164被引量：255H指数：8; 导出分析报告; 相关领域：理学更多>>; 相关作者：王彦广钱荣郭寅龙兰凤英甘利华更多>>; 相关机构：中国科学院浙江大学湖南大学中国农业科学院兰州兽医研究所更多>>; 相关期刊：更多>>; 相关基金：国家自然科学基金国家重点基础研究发展计划中国博士后科学基金重庆市自然科学基金更多>>

Water-oxidation intermediates enabling electrochemical propylene epoxidation: 《Chinese Journal of Structural Chemistry》2024年第5期1-2,共2页Yang Yang Jing-Li Luo Xian-Zhu Fu; In the production of propylene oxide(PO),reliance on hazardous chemical oxidants,such as molecular chlorine(Cl_(2))or peroxides,is a common practice.A promising alternative to current epoxidation methods involves a se...; 关键词：PROPYLENE EPOXIDATION INTERMEDIATE

Recent Advances in the Analytical Techniques for PFASs and Corresponding Intermediates During Their Chemical Decomposition: 《Chemical Research in Chinese Universities》2023年第3期361-369,共9页LIU Fuyu KANG Tingshuo HAN Bin ZHANG Qingzhe YIN Yongguang CAI Yong; supported by the National Natural Science Foundation of China(No.22206113);the Fund of Qilu Youth Talent Program of Shandong University,China(No.61440082163171);the Outstanding Youth Science Fund(Overseas)of Shandong Provincial Natural Science Foundation,China(No.2022HWYQ-015);the Taishan Scholars Project Special Fund,China(No.tsqn202211039).; Per-and polyfluoroalkyl substances(PFASs)have been restricted from production and consumption in many countries due to their persistence and biological toxicity.With the development of removal technologies,the require...; 关键词：Per-and polyfluoroalkyl substance(PFAS) Analytical technique Decomposition intermediate

Monitoring the rapid nanocrystal transformation via trapped intermediates of silica encapsulation: 《Science China Materials》2022年第7期1963-1970,共8页Ruoxu Wang Qian Wang Huiying Guo Hongyu Chen; supported by the National Natural Science Foundation of China(21703104,21673117 and 91956109);Nanjing Tech University(39837102);the SICAM Fellowship from Jiangsu National Synergetic Innovation Center for Advanced Materials。; In transmission electron microscopy(TEM),encapsulation is an important tool to preserve the nanoparticles from aggregation,weathering,and destructive highenergy electron beam.Traditionally,encapsulation can only be us...; 关键词：ENCAPSULATION hollow nanostructures INTERMEDIATE salt nanocrystal nanoscale droplet kosmotrope

Spectroscopic characterization and photochemistry of the Criegee intermediate CF_(3)C(H)OO: 《Journal of Environmental Sciences》2022年第4期160-169,共10页Lina Wang Zhuang Wu Bo Lu Xiaoqing Zeng; supported by the National Natural Science Foundation of China(Nos.22003010 and 22025301); Criegee intermediates(CIs),also known as carbonyl oxide,are reactive intermediates that play an important role in the atmospheric chemistry.Investigation on the structures and reactivity of CIs is of fundamental impor...; 关键词：Criegee intermediates CF_(3)COOH(TFA) CF_(3)CHCl_(2)(HCFC-123) PHOTOCHEMISTRY Matrix-isolation spectroscopy

Structural insights of catalytic intermediates in dialumene based CO_(2) capture: Evidences from theoretical resonance Raman spectra: 《Chinese Chemical Letters》2021年第8期2469-2473,共5页Baoling Tian Shujuan Li Shulai Lei Liangxu Lin Wenyue Guo Hao Ren; financial support from the National Natural Science Foundation of China (NSFC,No.21773309);Highlevel Science Foundation of Qingdao Agricultural University (No.663/1114351);the Fundamental Research Funds for the Central Universities (No.19CX05001A);Hubei University of Arts and Science (No.2020kypytd002);Xiangyang Science and Technology Research and Development (No.2020YL09)。; CO_(2) capture is considered as one of the most ideal strategies for solving the environmental issues and against global warming.Recently,experimental evidence has suggested that aluminum double bond(dialumene) specie...; 关键词：Resonance Raman Ab initio Catalytic intermediate Dialumene CO_(2)capture Ultrafast spectroscopy

Reaction mechanism and kinetics of Criegee intermediate and hydroperoxymethyl formate: 《Journal of Environmental Sciences》2021年第7期128-137,共10页Meifang Chen Shengrui Tong Zhen Wang Weiran Li Yanyong Xu Sufan Wang Maofa Ge; supported by the National Key Research and Development Program of China(No.2016YFC0202200);the Na-tional Natural Science Foundation of China(No.42022039);Beijing National Laboratory for Molecular Sciences(No.BNLMS-CXXM-202011);Beijing Nova Program(No.2018113);the Youth Innovation Promotion Association CAS(No.2017042).; The reaction mechanism and kinetics of the simplest Criegee intermediate CH_(2)OO reaction with hydroperoxymethyl formate(HPMF)was investigated at high-level quantum chemistry calculations.HPMF has two reactive functi...; 关键词：Criegee intermediates Hydroperoxymethyl formate Mechanism KINETICS POLYMERIZATION

Intermediates transformation for efficient perovskite solar cells被引量：2: 《Journal of Energy Chemistry》2021年第1期102-114,I0004,共14页Zhizai Li Yi Sun Huanhuan Yao Jing Zhao Qian Wang Liming Ding Zhiwen Jin; funded by the National Natural Science Foundation of China (51902148, 61704099, 51801088 and 11664001);the Fundamental Research Funds for the Central Universities (lzujbky-2020-61, lzujbky-2019-88 and lzujbky-2020-kb06);the Special Funding for Open and Shared Large-Scale Instruments and Equipments of Lanzhou University (LZU-GXJJ-2019C023 and LZU-GXJJ-2019C019)。; Perovskite materials have made a great progress in terms of the power conversion efficiency(PCE), rising from 3.8% to 25.2%. To obtain pinhole-free, superior crystal, and high-quality perovskite films with less defect...; 关键词：INTERMEDIATE Formation energy Crystalline dynamics SOLUBILITY Nucleation sites

Ro-vibrational Spectra of the Simplest Deuterated Criegee Intermediate CD2OO: 《Chinese Journal of Chemical Physics》2020年第1期65-68,共4页Jun Li; the Chongqing Municipal Natural Science Foundation(No.cstc2019jcyjmsxmX0087);the National Natural Science Foundation of China(No.21573027 and No.21973009).; Criegee intermediates are of signi cance in the atmospheric chemistry.In this work,the rovibrational spectra of the simplest deuterated Criegee intermediate,CD2OO,were studied by a vibrational self-consistent eld/virt...; 关键词：Criegee intermediates Vibrational spectra Rotational constants Multimode calculations Potential energy surface

Rapid unimolecular reaction of stabilized Criegee intermediates and implications for atmospheric chemistry被引量：1: 《Science Foundation in China》2019年第4期21-21,共1页; Under the support by the National Natural Science Foundation of China,Prof.Long Bo(龙波)at the Guizhou Minzu University and his collaborators(led by Prof.Donald G,Truhlar)at the University of Minnesota have studied an...; 关键词：methods. STABILIZED INTERMEDIATE

Disassembly intermediates of RbsD protein remain oligomeric despite the loss of an intact secondary structure被引量：5: 《Science China(Life Sciences)》2009年第11期997-1002,共6页FENG YongJun1, ZHANG Meng2, HU MingXi1, ZHENG Jie1, JIAO WangWang2 & CHANG ZengYi2 1 School of Life Science, Beijing Institute of Technology, Beijing 100081, China 2 School of Life Sciences, National Laboratory of Protein Engineering and Plant Genetic Engineering, Center for Protein Science, Peking University, Beijing 100871, China; Supported by the National Natural Science Foundation of China (Grant Nos. 30570355, 30670022 and 30870055);the National Key Basic Research Foundation of China (Grant Nos 2006CB806508 and 2006CB910300); Many proteins exist as homo-oligomers in living organisms wherein the change of oligomeric status apparently serves as an effective means for modulating their biological activities. We have previously reported that th...; 关键词：RbsD oligomeric PROTEIN oligomeric INTERMEDIATE REFOLDING reassembly

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