nm pulsed laser\|ablated Ta atoms react with carbon dioxide to form products TaCO, OTaCO and O\-2Ta(CO)\-2, which have been isolated in argon matrices and identified by their FTIR spectra and a comparison of the spect...
The mass spectra of both positive and negative charged Ta-containing ions from laser ablatiou of Ta2O5 were measured using a time-of-flight mass spectrometer. Formation of iomc Ta-containing oxides such as TaO and TaO...
The geometries and fundamental vibrational frequencies of trans-and C2v- nitrous acid have been determined by ab initio calculations at the MP2 level with 6-31G** and 6-311+G** basis sets. The calculation results sati...
The photodissociation of cis-(NO)2 in N2 and Ar matrices under 266 nm pulsed laser irradiation is reported- Results show the electronically excited o(1D) atom may be formed in the primary photolysis step. In the N2 ma...