不同稀土离子对海藻酸钠凝胶特性的影响  

Effects of Different Rare Earth Ions on the Gel Properties of Sodium Alginate

作　　者：陈春梅 傅钰 庄晓雯 许加超[1] 高昕[1] 付晓婷[1] CHEN Chunmei;FU Yu;ZHUANG Xiaowen;XU Jiachao;GAO Xin;FU Xiaoting(Laboratory of Seaweed Chemistry and Applied Research,Ocean University of China,Qingdao 266003,China)

机构地区：[1]中国海洋大学,海藻化学及应用实验室,山东青岛266003

出　　处：《食品工业科技》2022年第14期52-58,共7页Science and Technology of Food Industry

基　　金：山东省重大科技创新工程项目(2019JZZY020613);青岛市科技惠民专项(20-3-4-31-nsh)。

摘　　要：本文主要研究了四种稀土离子Y^(3+)、Ce^(3+)、La^(3+)、Er^(3+)对海藻酸钠凝胶特性的影响,通过研究海藻酸钠-稀土凝胶的机械性质、平衡含水量、离子交换率及凝胶机理。结果发现:La^(3+)、Y^(3+)、Er^(3+)、Ce^(3+)可以与M/G≈1的海藻酸钠形成不可逆凝胶,其凝胶强度在32~41 N之间,杨氏模量在14~20 N之间,弹性在55%~59%之间,平衡含水量均大于93%,四种凝胶的强度为Ce^(3+)>Er^(3+)>Y^(3+)>La^(3+),弹性为Ce^(3+)<Er^(3+)<Y^(3+)<La^(3+),离子交换率大小为:Ce^(3+)为52.99%,Er^(3+)为50.81%,Y^(3+)为40.74%,La^(3+)为39.33%。在不同M/G比值条件下,四种海藻酸钠-稀土凝胶的强度有较大区别:当M/G=1.99>1时,大小依次为Er^(3+)>Ce^(3+)>Y^(3+)>La^(3+);当M/G=0.99≈1、M/G=0.19<1时,大小依次为Ce^(3+)>Er^(3+)>Y^(3+)>La^(3+),其中Ce^(3+)、Y^(3+)、La^(3+)对海藻酸钠中的G片段有一定的偏好性,Er^(3+)对M片段有一定的偏好性。本文研究为海藻酸钠的精深加工利用与稀土元素的新功能性材料的开发奠定理论基础。In this paper,the gel properties of sodium alginate with Y^(3+),Ce^(3+),La^(3+) and Er^(3+) were studied.By studying the mechanical properties,equilibrium water content,ion exchange rate and gel mechanism of seaweed rare earth gel,it was found that:The coordination form of rare earth ions and carboxyl group in sodium alginate was pseudo-bridged monodentate coordination and bridge coordination.At the same time,the special three-dimensional network structure of the rare earth gel was formed through the planar and non-planar geometry formed by intramolecular and intermolecular chelation,and the gel strength of the gel formed by La^(3+),Y^(3+),Er^(3+),Ce^(3+) and sodium alginate M/G≈1 was between 32 and 41 N,the Young’s modulus was between 14 and 20 N,the elasticity was between 55%and 59%,the equilibrium water content was greater than 93%,the strength of the four gel was Ce^(3+)>Er^(3+)>Y^(3+)>La^(3+),the elasticity was Ce^(3+)<Er^(3+)<Y^(3+)<La^(3+),and the ion exchange rate was:Ce^(3+)52.99%,Er^(3+)50.81%,Y^(3+)40.74%,La^(3+)39.33%.Under different M/G ratio,the affinity between rare earth ions and sodium alginate gel was quite different:When M/G=1.99>1,the affinity of seaweed rare earth gel was in this order:Er^(3+)>Ce^(3+)>Y^(3+)>La^(3+).When M/G=0.99≈1 and M/G=0.19<1,the affinity of seaweed rare earth gel was in this order:Ce^(3+)>Er^(3+)>Y^(3+)>La^(3+).Among them,Ce^(3+),Y^(3+) and La^(3+) had a certain preference for G fragment of sodium alginate,and Er^(3+)had a certain preference for M fragment.This study would lay a theoretical foundation for the intensive processing and utilization of sodium alginate and the development of new functional materials of rare earth elements.

关 键 词：海藻酸钠 稀土离子 M/G比值 凝胶特性 凝胶机理 

分 类 号：O648.17[理学—物理化学]