绿衣观音土曲中添加中药材对清香型白酒风味物质的影响  

Effects of adding Chinese medicinal materials to the Green-covering Guanyin Tuqu on flavor components of light-flavor Baijiu

作　　者：江威 李锐 江丹 唐洁 林斌 李群 张晶晶 柯晗冰 杨强 陈申习 JIANG Wei;LI Rui;JIANG Dan;TANG Jie;LIN Bin;LI Qun;ZHANG Jingjing;KE Hanbing;YANG Qiang;CHEN Shenxi(Hubei Provincial Key Lab for Quality and Safety of Traditional Chinese Medicine Health Food,Jing Brand Research Institute,Jing Brand Co.,Ltd.,Huangshi 435000,China)

机构地区：[1]劲牌有限公司劲牌研究院中药保健食品质量与安全湖北省重点实验室,湖北黄石435000

出　　处：《中国酿造》2025年第3期48-52,共5页China Brewing

基　　金：湖北省重点研发计划项目(2020BBA050);湖北省自然科学基金(2022CFB137)。

摘　　要：为探究在绿衣观音土曲生产中加入10种中药材(肉桂、丁香、丹参、人参、黄芪、陈皮、当归、川芎、辣蓼、甘草)对清香型白酒品质的影响,该研究将10种中药材按5%的添加量添加至绿衣观音土曲(药曲),以不添加中药材绿衣观音土曲(土曲)为对照,分别酿造药曲白酒及土曲白酒。利用气相色谱(GC)、气质联用(GC-MS)和顶空固相微萃取-气相色谱-质谱(HS-SPME-GC-MS)等方法,检测其出酒率、酒质指标(乙酸乙酯、正丙醇、杂醇油)、挥发性风味物质及活性成分。结果表明,与土曲白酒相比,药曲白酒出酒率提升2.93个百分点,正丙醇和杂醇油分别降低0.08 g/L、0.12 g/L,乙酸乙酯下降0.18 g/L。土曲酒样、药曲酒样中分别检出99种、101种挥发性风味物质,药曲白酒中存在异丁香烯、古巴烯、卡拉烯、丁香酚和α-白菖考烯,其中,异丁香烯相对含量最高(1.36%)。与土曲酒样相比,药曲白酒中四甲基吡嗪、愈创木酚含量分别增加12.62%、23.36%。In order to investigate the effects of 10 Chinese medicinal materials(cinnamon,clove,Salviae miltiorrhizae,ginseng,Astragalus Membranaceus,Pericarpium Citri Reticulatae(Chenpi),Angelica sinensis(Danggui),Ligusticum Chuanxiong(Chuanxiong),Polygonum hydropiper(Laliao),Licorice)added in Green-covering Guanyin Tuqu on the quality of light-flavor(Qingxiangxing)Baijiu,10 Chinese medicinal materials were added at 5%addition in the Green-covering Guanyin Tuqu(Yaoqu),and pure Green-covering Guanyin Tuqu(Tuqu)as a control,Yaoqu Baiju and Tuqu Baijiu were brewed,respectively.The liquor yield,liquor quality indexes(ethyl acetate,n-propanol,fusel oil),volatile flavor substances and active ingredient were determined by gas chromatography(GC),gas chromatography mass spectrometry(GC-MS)and headspace solid phase microextraction gas chromatography mass spectrometry(HS-SPME-GC-MS).The results showed that compared with Tuqu Baijiu,the liquor yield of Yaoqu Baijiu increased by 2.93 percentage points,n-propanol and fusel oil decreased by 0.08 g/L and 0.12 g/L,respectively,and ethyl acetate decreased by 0.18 g/L.99 and 101 kinds of volatile flavor substances were detected in the samples of Tuqu Baijiu and Yaoqu Baijiu,respectively.Isocaryophyllene,copaene,calamene,eugenol andα-calacorene were found in Yaoqu Baijiu,among which the relative content of isocaryophyllene was the highest(1.36%).Compared with Tuqu Baijiu samples,the contents of tetramethylpyrazine and guaiacol in Yaogu Baijiu increased by 12.62%and 23.36%,respectively.

关 键 词：绿衣观音土曲 中药材 清香型白酒 风味物质 活性成分 

分 类 号：TS262.3[轻工技术与工程—发酵工程]