半夹芯16e化合物Cp Co S2C2B10H10(Cp:cyclopentadienyl)(1)与HC≡CCO2Me在2-甲基二硫代丙酸存在下反应生成化合物{(C5H4Co S2C2B9H9)(CH=CHCO2Me)(Me2C=CS2H)}(2)和(Me2C=CS2H)3Co(3)。在化合物2中,原料化合物1中的一个S-Co键断裂,该S...
Project supported by the Science and Technology Research Project of Key Laboratory of Higher Institutions of Jiangxi Province(No.GJJl 1710);the Science and Technology Research Projects of the Education Department of Jiangxi Province(Nos.GJJ09376 and GJJ10613);the National Natural Science Foundation of China(21361022 and 21261020);the Scientific and Technological Landing Project of Higher Education of Jiangxi Province(No.KJLD12094);the Fourth Point of Specialty Construction College of Education Ministry(No.TS11524)
A new compound [CpCo(Se2C2BIoH9)CH2C(O)C4H30] has been synthesized and characterized by elemental analysis, IR spectroscopy, NMR, MS and single-crystal X-ray diffraction. The complex crystallizes in the monoclinic...