国家自然科学基金(20104005)

作品数:11被引量:10H指数:2
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相关作者:贺枫冯俊卓仁禧程峰梁芸更多>>
相关机构:武汉大学更多>>
相关期刊:《高等学校化学学报》《Science China Chemistry》《Chinese Journal of Polymer Science》《武汉大学学报(理学版)》更多>>
相关主题:RING-OPENING_POLYMERIZATIONPOLYCARBONATES侧链XY固定化酶更多>>
相关领域:理学化学工程更多>>
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Enzymatic Synthesis and Characterization of Novel Polycarbonates Derived from 5-Allyloxy-1, 3-dioxan-2-one and 5, 5-Dimethvl-1.3-dioxan-2-one
《Chinese Chemical Letters》2006年第10期1385-1387,共3页Yan Ping WANG Feng HE Gang LIU Ren Xi ZHUO 
The authors are grateful for the financial support of the National Natural Science Foundation of China (No. 20104005).
Novel polycarbonates from 5-allyloxy-1, 3-dioxan-2-one (ATMC) with 5, 5-dimethyl- 1, 3-dioxan-2-one (DTC) were successfully synthesized for the first time using immobilized porcine pancreas lipase (IPPL) as cata...
关键词:5-Allyloxy-1 3-dioxan-2-one 5 5-dimethyl-1 3-dioxan-2-one enzyme-catalyzed ring opening polymerization polycarbonates. 
Enzymatic Synthesis and Characterization of Novel Amphiphilic Triblock Copolymer Poly(p-dioxanone-co-5-benzyloxytrimethylene carbonate)-block-poly(ethylene glycol)
《Chinese Chemical Letters》2006年第8期1113-1116,共4页Hua Li JIA Feng HE Jun FENG Ren Xi ZHUO 
the financial support of the National Natural Science Foundation of China(No.20104005).
Novel amphiphilic triblock copolymer poly(p-dioxanone-co-5-benzyloxytrimethylene carbonate)-block-poly(ethylene glycol)-block-poly(p-dioxanone-co-5-benzyloxytrimethylene carbonate) (p(PDO-co-BTMC)-b-PEG-b-p(...
关键词:Amphiphilic copolymer poly(ethylene glycol) 5-benzyloxytrimethylene carbonate p-dioxanone enzymatic polymerization. 
聚ε-己内酯的微米硅球固定化猪胰脂肪酶促合成被引量:1
《高等学校化学学报》2006年第5期982-984,共3页王迎霞 贺枫 李峰 冯俊 卓仁禧 
国家自然科学基金(批准号:20104005)资助
Porcine pancreas lipase(PPL) immobilized on narrow distributed micron glass beads was employed successfully for ring-opening polymerization of ε-caprolactone(CL).Different polymerization conditions such as enzyme con...
关键词:猪胰脂肪酶 固定化 微米硅球 酶促开环聚合 聚Ε-己内酯 
Synthesis and Characterization of Amphiphific Block Copolymer Containing PVP and Poly(5-benzyloxytrimethylene carbonate)被引量:3
《Chinese Chemical Letters》2006年第2期239-242,共4页Ying Xia WANG Feng HE Ren Xi ZHUO 
the financial support of National Key Fundamental Research Program of China (Grant No. G1999064703) ;the National Natural Science Foundation of China (Grant No. 20104005).
Amphiphilic copolymer of 5-benzyloxytrimethylene carbonate (BTMC) with poly (vinyl pyrrolidone) (PVP) was successfully synthesized using immobilized porcine pancreas lipase (IPPL) or SnOct2 as catalyst. Hydrox...
关键词:Amphiphilic copolymer end-functionalized PVP 5-benzyloxytrimethylene carbonate immobilized enzyme ring-opening polymerization macroinitiator. 
Synthesis and Characterization of Novel Aliphatic Polycarbonates Bearing Pendant Allyl Ether Groups
《Chinese Chemical Letters》2006年第1期137-139,共3页Gang LIU Feng HE Yah Ping WANG Jun FENG Ren Xi ZHUO 
support of the National Natural Science Foundation of China(Grant No.20104005)
A new six-membered cyclic carbonate monomer, 5-allyloxytrimethylene carbonate (ATMC), was synthesized starting from glycerol, and the corresponding polycarbonates, poly(5-allyloxytrimethylene carbonate)(PATMC) w...
关键词:5-Allyloxytrmethylene carbonate poly(5-allyloxytrimethylene carbonate) ring-opening polymerization POLYCARBONATE allyl ether. 
侧链烯丙酯化的生物可降解聚碳酸酯的酶促合成与功能化被引量:1
《武汉大学学报(理学版)》2005年第6期704-708,共5页贺枫 刘钢 唐晓兰 史文 冯俊 卓仁禧 
国家自然科学基金资助项目(20104005);武汉市青年科技晨光计划资助项目(20015005041)
报道了多孔硅球固定化猪胰脂肪酶(IE)催化合成侧链含活性烯丙氧羰基的聚(5-甲基-5-烯丙氧羰基-三亚甲基碳酸酯)(PMAC)的新方法.所得聚合物经核磁共振氢谱(1H NMR),核磁共振碳谱(13C NMR)以及凝胶渗透色谱(GPC)表征.同时,研究了反应温度...
关键词:固定化酶 聚碳酸酯 酶促仆环聚合 烯丙酯 环氰化 
嵌段共聚物PDTC-PEG-PDTC的降解和释药性能
《武汉大学学报(理学版)》2004年第6期703-706,共4页贺枫 程峰 冯俊 李龙 卓仁禧 
国家自然科学基金资助项目(20104005);武汉市青年科技晨光计划资助项目(20015005041)
研究了5,5 二甲基 三亚甲基碳酸酯的均聚物(PDTC)及其与聚乙二醇(PEG)组成的嵌段共聚物(PDTC PEG PDTC)的亲水性、水解和酶解性能以及药物释放性能.结果表明:随着聚合物中PEG含量的增加,聚合物的亲水性显著增强;当PEG含量较高时,PEG从...
关键词:嵌段共聚物 聚乙二醇 聚碳酸酯 亲水性 降解性 药物释放 
一步合成侧链含活性羧基的聚(酯-碳酸酯)被引量:3
《武汉大学学报(理学版)》2004年第4期453-457,共5页贺枫 梁芸 冯俊 程峰 卓仁禧 
国家自然科学基金(20104005);武汉市青年科技晨光计划(20015005041)资助项目
报道了多孔硅球固定化猪胰脂肪酶(IE)催化一步合成侧链含活性羧基的聚(酯 碳酸酯)的方法.所得共聚物经红外光谱(IR)、核磁共振氢谱(1HNMR)和特性粘度表征.研究了反应温度、反应时间、IE用量及共聚单体5 甲基 5 羧基三亚甲基碳酸酯(MCC)...
关键词:固定化酶 聚乳酸 聚碳酸酯 活性羧基 酶促开环聚合 
Enzymatic ring-opening copolymerization of trimethylene carbonate and ethylene ethyl phosphate
《Science China Chemistry》2003年第2期160-167,共8页冯俊 卓仁禧 贺枫 
supported by the National Key Fundamental Research Program of China(Grant No.G1999064703);the National Natural Science Foundation of China(Grant No.20104005).
Enzymatic ring-opening copolymerization of trimethylene carbonate (TMC) and ethylene ethyl phosphate (EEP) are performed in bulk at 100°C using porcine pancreas lipase (PPL) or candida rugosa lipase (CL) as catalyst....
关键词:ENZYMATIC ring-opening copolymerization  poly(trimethylene carbonate-co ETHYLENE ETHYL phosphate)  polycarbonates  polyphosphates  lipase. 
SYNTHESIS OF POLY(5,5-DIMETHYL-1,3-DIOXAN-2-ONE)BY LIPASE-CATALYZED RING-OPENING POLYMERIZATION被引量:1
《Chinese Journal of Polymer Science》2003年第1期5-8,共4页贺枫 卓仁禧 
The authors are grateful for the financial support of the National Natural Science Foundation of China (No. 20104005) and Hubei Province Natural Science Foundation of China (No. 2001B053) and a grant from National Key Fundamental Research Program of Chin
Porcine pancreas lipase (PPL) and PPL immobilized on narrow distributed micron-sized glass beads wereemployed successfully for the ring-opening polymerization of 5, 5-dimethyl-1, 3-dioxan-2-one (DTC) for the first tim...
关键词:Enzymatic polymerization Immobilized enzyme Ring-opening polymerization POLYCARBONATES 
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