国家自然科学基金(20625205)

作品数:8被引量:16H指数:3
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相关期刊:《Science China Chemistry》《Chemical Research in Chinese Universities》《Chinese Journal of Chemistry》《Chinese Chemical Letters》更多>>
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Histidine-catalyzed synthesis of cyclic carbonates in supercritical carbon dioxide被引量:3
《Science China Chemistry》2010年第7期1566-1570,共5页QI ChaoRong JIANG HuanFeng 
supported by the National Natural Science Foundation of China (20625205, 20772034 & 20932002);the National Basic Research Program of China (2010CB732206);Doctoral Fund of Ministry of Education of China (20090172110014);Guangdong Natural Science Foundation (8451064101000236)
The coupling reaction of carbon dioxide with epoxides was investigated using naturally occurring α-amino acids as the catalyst in supercritical carbon dioxide and it was found that L-histidine is the most active cata...
关键词:supercritical carbon dioxide amino acids EPOXIDES cyclic carbonates 
The heavy atom effect on photocleavage of DNA by mono-hydroxyl halogenated corroles被引量:4
《Chinese Chemical Letters》2010年第3期373-375,共3页Chi Kwong Chang 
supported by the National Natural Science Foundation of China(Nos.20771039,20625205, 20871122,20971046);National Key Foundation Research Development Project(973) Item of China(No. 2007CB815306)
DNA photocleavage properties of halogenated mono-hydroxyl corrole 1-5 were investigated.It was found that these corroles were able to photocleavage supercoiled pBR 322 DNA(SC) into nicked-circular DNA(NC).The acti...
关键词:CORROLE DNA PHOTOCLEAVAGE Heavy atom effect 
Reduction of Aldehydes by Fe-H_2O-CO_2 System in Supercritical Carbon Dioxide
《Chemical Research in Chinese Universities》2008年第5期658-660,共3页HUANG Xi-zhe JIANG Huan-feng 
the National Natural Science Foundation of China(Nos.20332030,20572027,20625205 and 20772034);Natural Science Foundation of Guangdong Province,China(No.07118070).
1 Introduction Nowadays, green chemistry has received increased attention. The use of water and scCO2 as a solvent or reagent is an important field for organic reactions and green chemistry both in laboratory and indu...
关键词:ALDEHYDES ALCOHOLS Fe-H2O-CO2 Supercritical carbon dioxide REDUCTION 
PdCl_2-catalyzed heterocyclotrimerization in MeOH/scCO_2:A versatile approach to dimethyl pyridine-3,5-dicarboxylate from methyl acrylate and urea
《Science China Chemistry》2008年第5期447-451,共5页ZOU Bo,JIANG HuanFeng College of Chemistry,South China University of Technology,Guangzhou 510640,China 
the National Natural Science Foundation of China (Grant Nos. 20332030, 20572027, 20625205 and 20772034);Guangdong Natural Science Foundation (Grant No. 07118070)
A novel and green method for the synthesis of dimethyl pyridine-3,5-dicarboxylate has been developed. It is PdCl2-catalyzed heterocyclotrimerization of methyl acrylate with urea in methanol/supercritical carbon dioxid...
关键词:PDCL2 heterocyclotrimerization DIMETHYL pyridine-3 5-dicarboxylate scCO2 
Carbon nanotubes-supported palladium nanoparticles for the Suzuki reaction in supercritical carbon dioxide: A facile method for the synthesis of tetrasubstituted olefins被引量:4
《Science China Chemistry》2008年第3期241-247,共7页ZHOU Lei ZHANG WeiDe JIANG HuanFeng 
Supported by the National Natural Science Foundation of China (Grant Nos. 20332030, 20572027, 20625205 and 20772034); Guangdong Natural Science Foundation (No. 07118070).
A facile and efficient method for the synthesis of tetrasubstituted olefins in supercritical carbon dioxide was developed by using carbon nanotubes-supported palladium nanoparticles (Pd/CNTs) as the catalyst. Compared...
关键词:Pd/CNTs Suzuki reaction tetrasubstituted olefins scCO2 
An Efficient and Practical Process for Pd/Cu Cocatalyzed Homocoupling Reaction of Terminal Alkynes Using Sodium Percarbonate as a Dual Reagent in Aqueous Media被引量:4
《Chinese Journal of Chemistry》2007年第10期1413-1416,共4页周磊 詹海莺 刘海灵 江焕峰 
Project supported by the National Natural Science Foundation of China (Nos. 20332030, 20572027, 20625205).
A new process for the Pd/Cu co-catalyzed homocoupling reaction of terminal alkynes was developed. The reaction was carried out in aqueous media with sodium percarbonate as both a clean oxidant and a base. Meanwhile, a...
关键词:HOMOCOUPLING sodium percarbonate aqueous media PALLADIUM 
PS-HQ:More convenient in situ polymeric cocatalyst for the PdC1_2-catalyzed acetalization in supercritical carbon dioxide被引量:1
《Chinese Chemical Letters》2007年第8期969-972,共4页Zhao Yang Wang Huan Feng Jiang Chao Rong Qi Yan Xia Shen Shao Rong Yang 
Polystyrene-supported hydroquinone (PS-HQ) is presented as an in situ polymeric cocatalyst to replace polystyrenesupported benzoquinone (PS-BQ) in the PdCl2-catalyzed acetalization of methyl acrylate with methanol...
关键词:Palladium chloride Polymeric supported catalyst HYDROQUINONE Oxidation Wacker reaction Molecular oxygen 
Polystyrene-supported Phenol/DMAP: an Efficient Binary Catalyst System for CO2 Fixation to Give Cyclic Carbonates被引量:1
《Chinese Journal of Chemistry》2007年第7期1051-1054,共4页戚朝荣 江焕峰 汪朝阳 邹波 
Project supported by the National Natural Science Foundation of China (Nos. 20332030, 20572027 and 20625205).
Polystyrene-supported phenol (PS-PhOH) was successfully synthesized by alkylation reaction of phenol with 2% DVB cross-linked chloromethylated polystyrene and characterized by IR spectra and elemental analysis. In c...
关键词:carbon dioxide EPOXIDE carbon dioxide fixation cyclic carbonate supported catalyst 
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