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国家自然科学基金(21202141): 作品数：16被引量：68H指数：6; 导出分析报告; 相关作者：俞磊徐清范以宁王芳丁克鸿更多>>; 相关机构：扬州大学江苏扬农化工股份有限公司南京大学扬州工业职业技术学院更多>>; 相关期刊：《化学试剂》《教育研究前沿（中英文版）》《有机化学》《Science Bulletin》更多>>; 相关主题：催化绿色化学CATALYST有机硒ADDITION更多>>; 相关领域：理学化学工程语言文字文化科学更多>>

硒催化绿色合成反应进展被引量：6: 《化学试剂》2019年第6期545-549,共5页俞磊; 国家自然科学基金资助项目(21202141);江苏省优势学科项目(2018);江苏省自然科学基金资助项目(BK20181449);江苏省“六大”人才高峰高层次人才项目(XCL-090); 由于硒催化剂具有价格低廉、对生态友好、可回收利用、催化过程清洁等优点,硒催化的绿色合成反应有着很好的工业应用前景。最近五年以来,硒催化的有机化学反应被广泛报道,着重研究了硒催化的绿色合成反应,利用该催化技术,开发了一系列...; 关键词：硒催化有机合成绿色化学

铜催化醛肟脱水/贝克曼重排选择性可切换反应（英文）被引量：7: 《有机化学》2018年第10期2736-2740,共5页范昕易容王芳张旭徐清俞磊; Project supported by the National Natural Science Foundation of China(No.21202141);the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD);the Natural Science Foundation of Guangling College(No.ZKZD17005)~~; 廉价金属铜,可催化醛肟的脱水反应,生成有机腈.该反应在腈类溶剂中发生,并且使用二氧化锰作助催化剂,三苯基膦作配体.如果使用水作溶剂,则会发生贝克曼重排,生成酰胺.这种选择性随溶剂切换的有趣反应,为合成相关有用的有机化合物提供了...; 关键词：醛肟脱水贝克曼重排腈酰胺

Calcium-catalyzed reactions of element-H bonds被引量：2: 《Science Bulletin》2018年第15期1010-1016,共7页Lei Yu Rongrong Qian Xin Deng Fang Wang Qing Xu; supported by the National Natural Science Foundation of China(21202141,21672163);Priority Academic Program Development(PAPD) of Jiangsu Higher Education Institutions;Top-notch Academic Programs Project of Jiangsu Higher Education Institutions(TAPP);the Open Project Program of Jiangsu Key Laboratory of Zoonosis(R1509);the Natural Science Foundation of Guangling College(ZKZD17005); Investigation on organocalcium catalysis is just unfolding during the past decade. Beside conventional Ca salts with strong electron-withdrawing counter anions that may serve as Lewis acid catalysts, many Ca complexes...; 关键词：CALCIUM Organic reaction Green chemistry ADDITION Hydrofunctionalization

Recent advances on controllable and selective catalytic oxidation of cyclohexene被引量：4: 《Chinese Journal of Catalysis》2018年第5期899-907,共9页Hongen Cao Boran Zhu Yufan Yang Lin Xu Lei Yu Qing Xu; 国家自然科学基金(21202141,21672163);江苏省高校优势学科项目.; Because of multiple potential reaction sites and variable oxidation depths,oxidation of cyclohexene can lead to a mixture of products with different oxidation states and functional groups,such as 7-oxabicyclo[4.1.0]he...; 关键词：CYCLOHEXENE Selective oxidation Green chemistry 7-Oxabicyclo[4.1.0]heptane Cyclohexane-1 2-diol Adipic acid Cyclohex-2-en-1-ol Cyclohex-2-en-1-one

Catalytic dehydrogenation of propane to propylene over highly active PtSnNa/γ-Al2O3 catalyst被引量：5: 《Chinese Chemical Letters》2018年第3期475-478,共4页Shiyong Zhao Bolian Xu Lei YU Yining Fan; the Doctoral Program of Higher Education(No. SRFDP-2012009111001);NNSFC(No. 21202141);Priority Academic Program Development(PAPD) of Jiangsu Higher Education Institutions, Key Science & Technology Specific Projects of Yangzhou(No. YZ20122029);Yangzhou Nature Science Foundation(No. YZ2014040) for financial support; PtSnNa/γ-Al2O3 catalyst is widely used in the dehydrogenation of light alkane. This paper reports a new fabrication method of the catalyst. In the work, γ-Al2O3, SnCl4 and NaCl were ball milled to upload Sn and Na＋...; 关键词：Propane Propylene Dehydrogenation Platinum Aluminum oxide

Visible light-promoted, iodine-catalyzed selenoalkoxylation of olefins with diselenides and alcohols in the presence of hydrogen peroxide/air oxidant: an efficient access to α-alkoxyl selenides被引量：3: 《Science China Chemistry》2018年第3期294-299,共6页Mingxuan Liu Yiming Li Lei Yu Qing Xu Xuefeng Jiang; supported by the National Natural Science Foundation of China(21202141,21672069);Priority Academic Program Development of Jiangsu Higher Education Institutions;the Open Project Program of Jiangsu Key Laboratory of Zoonosis(R1509);the High Level Talent Support Project of Yangzhou University; Under iodine-catalyzed and visible light-irradiated aerobic conditions, selenoalkoxylation of olefins with diselenides and alcohols can be efficiently achieved to afford the useful α-alkoxyl selenides in the presence...; 关键词：selenium alkoxyl selenide aerobic oxidation visible light iodine catalysis

Easily fabricated and recyclable Pd&Cu@Al catalyst for gram-scale phosphine-free Heck reactions with high TON被引量：3: 《Science Bulletin》2017年第19期1325-1330,共6页Dongliang Zhang Zheng Wei Lei Yu; supported by the National Natural Science Foundation of China (21202141);Priority Academic Program Development (PAPD) of Jiangsu Higher Education Institutions;the Young Science and Technology Talent Support Project of Jiangsu Province (Lei Yu);the High Level Talent Support Project of Yangzhou University (Topnotch Talent, Lei Yu);the Open Project Program of Jiangsu Key Laboratory of Zoonosis (R1509);the Testing Centre of Yangzhou University; A unique Pd＆Cu@Al catalyst was easily fabricated just by immersing commercial aluminum foil in a mixed xylene solution of PdC12 and CuCl2. The catalyst fabrication process led to aluminum oxide coatings in situ, whic...; 关键词：Catalyst recoveryPalladiumnanoparticlesAluminum oxidePhosphine-freeSustainable chemistryHeck reaction

有机硒催化苯酚选择性氧化制对苯醌的研究被引量：11: 《有机化学》2017年第8期2115-2118,共4页王芳徐林孙诚徐清黄杰军俞磊; 国家自然科学基金(No.21202141);浙江省自然科学基金杰出青年基金(LR14B020002);江苏省高校优势学科项目;扬州大学高端人才支持计划资助项目~~; 苯酚选择性氧化制备对苯醌是一个有重要工业应用价值的反应.在有机硒催化下,以过氧化氢为氧化剂氧化苯酚,高选择性地生成了对苯醌.与已有技术相比,有机硒催化氧化反应可避免使用金属催化剂,从而避免产物中的金属残留.该反应过程清洁,不...; 关键词：有机硒催化苯酚氧化对苯醌对苯二酚

Pt/WO_3/ZrO_2催化甘油选择性氢解制备1,3-丙二醇被引量：9: 《有机化学》2017年第3期753-758,共6页仝庆高强许波连俞磊范以宁; 国家自然科学基金(No.21202141);江苏省高校优势学科和扬州市自然科学基金重大科技专项(No.YZ20122029)资助项目~~; 甘油是产量巨大的生物质.将之转化为有用化合物的研究,有重要的工业应用价值.甘油的氢解可生成一系列的C-3醇,如正丙醇、异丙醇、1,2-丙二醇以及1,3-丙二醇等.其中,1,3-丙二醇是合成聚对苯二甲酸丙二醇酯(PPT)的重要有机中间体.因此,选...; 关键词：甘油氢化催化生物质 1 3-丙二醇

PtSnNa/SUZ-4:An efficient catalyst for propane dehydrogenation被引量：9: 《Chinese Journal of Catalysis》2017年第3期529-536,共8页周华兰龚静静许波连邓生财丁元华俞磊范以宁; supported by the Jiangsu Planned Projects for Postdoctoral Research Funds(1301080C);NNSFC(21202141,21173182);Key Science&Technology Specific Projects of Yangzhou(YZ20122029);the Innovation Foundation of Yangzhou University(2015CXJ009)~~; The structure and catalytic properties of PtSn catalysts supported on SUZ-4 and ZSM-5 zeolite have been studied by using various experimental techniques including XRD,nitrogen adsorption,NH3-TPD,TG,H2-TPR and TPO tech...; 关键词：SUZ-4 zeolite PtSnNa catalyst Propane dehydrogenation Catalyst stability Pt distribution

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