supported by the National Natural Science Foundation of China(Grant No.29925101);the Special Founds for the Major State Basic Research Projects(Grant No.G19990-64800).
The reactions of [CptRhCl(m-Cl)]2 (1) (Cpt = tBu2C5H3) with Li2E2C2B10H10 (E = S, Se) lead to the green 16-electron dichalcogenolate complexes CptRh(E2C2B10H10) [E = S(2a), Se(2b)]. The 16-electron complexes 2a and 2b...
Supported by the National Natural Science Foundation of China( No.2 99740 2 9,2 992 5 10 1) and Special Funds forMajor State Basic Research Projects of China( G19990 64 80 0)
Halfsandwich iron dicarbonyl complex [η 5-C5H3(t-Bu)2]Fe(CO)2Cl(1) reacts with 1, 2-dilithium diseleno carborane Li2Se2C2B 10H 10(2) to give a binuclear iron carborane complex [η 5-C5H3(t-Bu)2]2Fe2(CO)3...
Financially Supported by the National Natural Science Foundation of China (29974029, 29925101) ;and Special Funds for Major State Basic Research Projects of China (G1999064800)
The crystal of complex [Li(THF)4][Fe(S2C2B10H10)2(THF)] 3 belongs to monoclinic, space group P21 with a = 11.964(2), b = 16.527(3), c = 12.554(3) ? = 108.70(3)? V = 2351.3(8) 3, Z = 2, Mr = 835.95, Dc = 1.181 g/cm3, ...
The reaction of \[Cp\+\%t\%RhCl\-2\]\-2(1) (Cp\+\%t\%=η\+5\|\{\}\+\%t\%Bu\-2C\-5\|H\-3) with 1,2\|dilithium dichalcogenolate carborane Li\-2E\-2C\-2B\-\{10\}H\-\{10\}(E=S, Se) afforded the 16\|electron rhodium(Ⅲ) ha...
This work was supported by the National Natural Science Foundation of China (Grant No. 29925101) ; also by the Special Founds for the State Major Basic Research Projects (Grant No. G1999064800).
Treatment of CptRh(PMe3)Cl2(1) (Cpt=5η-tBu2C5H3) with [Et4N]2Se6 in DMF solution leads to the for-mation of cyclo-tetraselenido half-sandwich rhodium com-plexes CptRh(PMe3)(Se4) (2). The elimination of 2 with ex-cess...