国家自然科学基金(20972025)

作品数:10被引量:14H指数:3
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相关作者:毛国梁宁英男姜涛薛秋梅徐韬更多>>
相关机构:东北石油大学天津科技大学更多>>
相关期刊:《化工进展》《Chinese Journal of Polymer Science》《Science Bulletin》《化学工程师》更多>>
相关主题:配体乙烯烯烃聚合LIGANDS1-辛烯更多>>
相关领域:理学化学工程更多>>
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FI催化剂配体的研究进展被引量:3
《化学通报》2015年第4期305-311,共7页吴韦 徐韬 宁英男 毛国梁 姜涛 
国家自然科学基金项目(20972025和U1362110);中国石油科技创新基金项目(2013D-5006-0503);教育部新世纪优秀人才支持计划(NCET-07-0142)资助
FI催化剂作为一类新型聚烯烃催化剂,具有高活性、耐高温等特性,在催化聚合方面表现出良好的性能,不但可以催化乙烯与极性及非极性单体共聚,而且可以通过改变主催化剂苯氧基亚胺配体的结构,得到具有不同结构的聚合物。本文介绍了FI主催...
关键词:FI催化剂 配体 苯氧基亚胺 聚乙烯 烯烃聚合 
Progress in the research of radical anion ligands and their complexes
《Chinese Science Bulletin》2014年第24期2936-2944,共9页Guoliang Mao Yuanmeng Song Tianjun Hao Ying Li Tao Xu Haiyan Zhang Tao Jiang 
supported by the National Natural Science Foundation of China(20972025,U1362110);PetroChina Innovation Foundation(2013D-5006-0503);Scientific Research Foundation for the Returned Overseas Chinese Scholars,Program for New Century Excellent Talents in University(NCET-07-0142);Heilongjiang Province(41417837-8-08016);Department of Education of Heilongjiang Province(1154H14,1154G53)
Recent progress in the research of radical anion ligands and their complexes with metals were summarized in this review.Radical anions were sorted into several types including iminosemiquinonate and iminoquinonate rad...
关键词:阴离子自由基 复合物 配体 过渡金属催化 有机磁性材料 氮氧自由基 配合物 杂环 
Recent progresses of late-transition metal complexes with nonsymmetric diimine ligands in ethylene polymerization and oligomerization
《Chinese Science Bulletin》2014年第21期2505-2512,共8页Guoliang Mao Yue Jiang Ning Li Qin Wang Dejin Zheng Meijiao Li Yingnan Ning 
supported by the National Natural Science Foundation of China (20972025,U1362110);the China National Petroleum Corporation (CNPC) Innovation Foundation (2013D-5006-0503);the Scientific Research Foundation for the Returned Overseas Chinese Scholars,Heilongjiang Province (41417837-8-08016);the Scientific Research Foundation for Overseas Chinese Scholars,Department of Education of Heilongjiang Province (1154H14)
Researches of late-transition metal complexes for ethylene polymerization and oligomerization have attracted a lot of attention in the last two decades.A large number of late-transition metal complexes with symmetric ...
关键词:过渡金属配合物 乙烯聚合 二亚胺 非对称 后期 齐聚 配体 聚合反应速率 
乙烯与极性单体共聚的研究进展
《化学工程师》2013年第12期34-37,44,共5页王钦 宁英男 毛国梁 
国家自然科学基金(20972025);黑龙江省留学归国人员科学基金(41417837-8-08016);黑龙江省教育厅海外学人科研资助(1154H14);中国石油科技创新基金(No.2010D-5006-0504)资助项目
聚烯烃属于非极性聚合物,通过在其分子链上引入极性基团可以将其功能化,从而可以有效地改善聚烯烃的性质,拓宽聚烯烃的商业用途。本文主要从极性单体的种类、乙烯与极性单体共聚的催化剂体系两个方面介绍了乙烯与极性单体共聚合研究的...
关键词:乙烯 极性单体 后过渡金属催化剂 共聚 
Recent progress in immobilization of late-transition-metal complexes with diimine ligands for olefin polymerization被引量:1
《Chinese Science Bulletin》2013年第15期1741-1750,共10页WU Wei JIANG Yan WU Hao LV ChunSheng LUO MingJian NING YingNan MAO GuoLiang 
supported by the National Natural Science Foundation of China (20972025);the China National Petroleum Corporation (CNPC)Innovation Foundation (2010D-5006-0504);Scientific Research Foundation for the Returned Overseas Chinese Scholars,Heilongjiang Province(41417837-8-08016);Scientific Research Foundation for Overseas Chinese Scholars,Department of education of Heilongjiang Province(1154H14)
Late-transition-metal(LTM) catalysts are a family of very flexible ethylene polymerization catalysts because their catalytic performance can be easily adjusted by modifying the ligand structure.Their less oxyphilicity...
关键词:后过渡金属配合物 烯烃聚合 配体 亚胺 催化剂 聚合反应 催化性能 共聚单体 
HIGH ACTIVITY AND GOOD HYDROGEN RESPONSE SILICA-SUPPORTED ZIEGLER-NATTA CATALYST FOR ETHYLENE POLYMERIZATION被引量:3
《Chinese Journal of Polymer Science》2012年第4期561-567,共7页姜涛 
supported by the Program for New Century Excellent Talents in Universities(NCET-07-0142);the Program for New Century Excellent Talents in Heilongjiang Provincial Universities(NCET-06-010);the National Natural Science Foundation of China(No.20972025);the Science Foundation of Tianjin University of Science & Technology(No.20090420).
A silica-supported Ziegler-Natta catalyst with dimethyldichlorosilane (DMDS) as modifier and small silica as support was successfully prepared and characterized. Results from pilot screen showed that the new catalys...
关键词:Ziegler-Natta catalyst Ethylene polymerization SILICA Dimethyldichlorosilane.[ TI-~TI^IN T 
Recent developments in homobimetallic reagents and catalysts for organic synthesis
《Chinese Science Bulletin》2011年第17期1753-1769,共17页WU Wei GU DeLiang WANG ShiMeng NING YingNan MAO GuoLiang 
supported by the National Natural Science Foundation of China (20972025);the China National Petroleum Corporation (CNPC) Innovation Foundation (2010D-5006-0504)
Organometallics are a family of useful organic chemicals because they play important roles in organic synthesis as reagents and as catalysts.They can be classified according to the number of metals they contain.Bimeta...
关键词:有机合成试剂 催化剂 有机金属化合物 有机化工原料 双金属化合物 有机反应 不对称反应 数量分类 
乙烯四聚催化体系双膦胺配体的结构与性能被引量:5
《化工进展》2011年第5期1003-1007,共5页宁英男 薛秋梅 毛国梁 姜涛 
国家自然科学基金(20972025);教育部"高校新世纪优秀人才支持项目"(NCET-07-0142);黑龙江省高校"新世纪优秀人才培养计划"(NCET-06-010)项目
简述了乙烯四聚反应制备1-辛烯催化体系的最新研究进展。指出乙烯四聚制1-辛烯催化体系中配体的结构和电子性是影响催化体系的活性和目的产物1-辛烯的选择性的主要因素。PNP配体中N取代基和P取代基的空间位阻和给电子效应都会对催化体...
关键词:乙烯四聚 1-辛烯 双膦胺配体 结构与性能 
COPOLYMERIZATION OF ETHYLENE AND PROPYLENE CATALYZED BY MAGNESIUM CHLORIDE SUPPORTED VANADIUM/TITANIUM BIMETALLIC ZIEGLER-NATTA CATALYSTS
《Chinese Journal of Polymer Science》2011年第4期475-482,共8页姜涛 
supported by the Program for New Century Excellent Talents in Universities(NCET-07-0142);the Program for New Century Excellent Talents in Heilongjiang Provincial Universities(NCET-06-010);the National Natural Science Foundation of China(No.20972025);the Science Foundation of Tianjin University of Science & Technology(No.20090420)
Magnesium chloride supported vanadium/titanium bimetallic Ziegler-Natta catalysts with di-i-butyl phthalate as internal donor for copolymerization of ethylene and propylene were prepared. The effects of reaction tempe...
关键词:Ziegler-Natta polymerization Vanadium/titanium catalyst Ethylene-propylene copolymer. 
A series of novel bisphosphinoamine ligands:Synthesis,characterization and application in ethylene tetramerization被引量:2
《Chinese Science Bulletin》2010年第33期3750-3754,共5页JIANG Tao CHEN HongXia CAO ChenGang MAO GuoLiang NING YingNan 
supported the Program for New Century Excellent Talents in University(NCET-07-0142);the Program for New Century Excellent Talents in Heilongjiang Provincial University(NCET-06-010);the National Natural Science Foundation of China(20972025);the Science Foundation of Tianjin University of Science & Technology(20090420)
A series of novel N-halogen-substituted-aryl bisphosphinoamine ligands were synthesized and characterized by elemental analysis,1H NMR and mass spectrometry.The combination of these ligands with Cr(Ⅲ) and activation ...
关键词:催化体系 配体 合成 乙烯 表征 甲基铝氧烷 元素分析 核磁共振 
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