相关期刊:《Chinese Journal of Structural Chemistry》《Chemical Research in Chinese Universities》《Chinese Journal of Chemistry》《Journal of Environmental Sciences》更多>>
This work was supported by the National Key R&D Program of China(Grant No.2021YFC2103704);the National Natural Science Foundation of China(Grant Nos.21878266 and 22078288);the Science and Technology Research Project of Henan Province(Grant No.222300420527);Program of Processing and Efficient Utilization of Biomass Resources of Henan Center for Outstanding Overseas Scientists(Grant No.GZS2022007).
Ultra-dispersed Ni nanoparticles(7.5 nm)on nitrogen-doped carbon nanoneedles(Ni@NCNs)were prepared by simple pyrolysis of Ni-based metal–organic-framework for selective hydrogenation of halogenated nitrobenzenes to c...
This work was supported by the National Natural Science Foundation of China(Nos.21871226,21502160,21572194);the Scientific Research Fund of Hunan Provincial Education Department(No.19B564).
The electrochemical reduction strategy of nitrobenzenes is developed.The chemistry occurs under ambient conditions.The protocol uses inert electrodes and the solvent,DMSO,plays a dual role as a reducing agent.Its synt...
the National Natural Science Foundation of China (Nos. 21262020 and 51464021);the Science and Technology Planning Project of Yunnan Province (No. KKSY201207140) for the financial support
A facile synthesis of 1,4-disubstituted 1,2,3-triazoles was achieved from nitrobenzenes and terminal alkynes under mild conditions. The reactions were successful for nitrobenzenes and terminal alkynes bearing various ...
supported by the National Natural Science Foundation of China(Nos.20976164,21176221 and 21136001);National Basic Research Program of China(973 Program)(Nos. 2011CB710803,2013CB733500);Zhejiang Provincial Natural Science Foundation of China(No.LY12B03005)
This study shows that minor amount of water plays a very important role in solvent-free hydrogenation of halogenated nitrobenzenes. For dried sponge Pd, the reaction cannot occur in the absence of water. For Pd/C cata...
Commercial MoS2 was found to be a highly selective catalyst for the reduction of nitrobenzenes to the corre- sponding anilines with hydrazine under mild conditions. MoS2 is not only much cheaper, but also more selecti...
supported by the Natural Science Foundation of Yancheng Teachers University (08YCKL077);the Jiangsu Provincial Key Laboratory of Coastal Wetland Bioresources & Environmental Protection (JLCBE 07025);the Educational Bureau of Jiangsu Province (08KJD150021)
In this study,DFT-B3LYP level of theory with the 6-311G basis set was used to calculate a set of molecular descriptors of 36 nitrobenzenes.Quantitative structure-activity relationship(QSAR) models of the toxicity(p...
This work was supported by the National Natural Science Foundation of China (No.10576030)
The molecular geometries and electronic structures of 30 nitrobenzenes have been calculated by using semi-empirical MO AM1 and PM3 methods. EHOMO, ELUMO, ENHOMO, ENLUMO, AE, QNO2, Qc and V were selected as the structu...
The single cell gel electrophoresis (SCGE) technique was used to detect DNA damage in germ cells of rats, which was induced by five tested nitroaromatic compounds. Mixed cultures of Sertoli and germ cells were prepa...
Supported by the Educational Ministry Foundation of China(No. 0 10 6 3) .Tetrahymena pyriformis B was kindlysupplied by Dr.Tiedke;Münster
The IGC 50 (50% inhibitory growth concentration) values of 27 nitrobenzenes were determined for the population growth endpoint of Tetrahymena pyriformis . The toxicity order of the observed compounds was found to be a...
It is experimentally found that different renction courses exist when mtrite ion reacts with nitrobenzenes with different electron withdrawing groups. when it is substituted with strong electron withdrawing groups. se...