NITROBENZENES

作品数:11被引量:48H指数:4
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相关期刊:《Chinese Journal of Structural Chemistry》《Chemical Research in Chinese Universities》《Chinese Journal of Chemistry》《Journal of Environmental Sciences》更多>>
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Room-temperature hydrogenation of halogenated nitrobenzenes over metal-organic-framework-derived ultra-dispersed Ni stabilized by N-doped carbon nanoneedles被引量:3
《Frontiers of Chemical Science and Engineering》2022年第12期1782-1792,共11页Yuemin Lin Yuanyuan Zhang Renfeng Nie Kai Zhou Yao Ma Mingjie Liu Dan Lu Zongbi Bao Qiwei Yang Yiwen Yang Qilong Ren Zhiguo Zhang 
This work was supported by the National Key R&D Program of China(Grant No.2021YFC2103704);the National Natural Science Foundation of China(Grant Nos.21878266 and 22078288);the Science and Technology Research Project of Henan Province(Grant No.222300420527);Program of Processing and Efficient Utilization of Biomass Resources of Henan Center for Outstanding Overseas Scientists(Grant No.GZS2022007).
Ultra-dispersed Ni nanoparticles(7.5 nm)on nitrogen-doped carbon nanoneedles(Ni@NCNs)were prepared by simple pyrolysis of Ni-based metal–organic-framework for selective hydrogenation of halogenated nitrobenzenes to c...
关键词:halogenated nitrobenzenes room-temperature hydrogenation Ni nanoparticles nitrogen-doped carbon nanoneedles metal–organic-framework 
Electrosynthesis of Azobenzenes Directly from Nitrobenzenes被引量:3
《Chinese Journal of Chemistry》2021年第12期3334-3338,共5页Yanfeng Ma Shanghui Wu Shuxin Jiang Fuhong Xiao Guo-Jun Deng 
This work was supported by the National Natural Science Foundation of China(Nos.21871226,21502160,21572194);the Scientific Research Fund of Hunan Provincial Education Department(No.19B564).
The electrochemical reduction strategy of nitrobenzenes is developed.The chemistry occurs under ambient conditions.The protocol uses inert electrodes and the solvent,DMSO,plays a dual role as a reducing agent.Its synt...
关键词:Azo compounds Nitro reduction ELECTROCHEMISTRY NITROBENZENES Green chemistry 
One-pot synthesis of 1,4-disubstituted 1,2,3-triazoles from nitrobenzenes
《Chinese Chemical Letters》2016年第1期109-113,共5页Fen Zhao Zhen Chen Kai Xie Rui Yang Yu-Bo Jiang 
the National Natural Science Foundation of China (Nos. 21262020 and 51464021);the Science and Technology Planning Project of Yunnan Province (No. KKSY201207140) for the financial support
A facile synthesis of 1,4-disubstituted 1,2,3-triazoles was achieved from nitrobenzenes and terminal alkynes under mild conditions. The reactions were successful for nitrobenzenes and terminal alkynes bearing various ...
关键词:ONE-POT Four-step 1 4-Disubstituted 1 2 3-triazoles NITROBENZENES Terminal alkynes 
The promoting role of minor amount of water in solvent-free hydrogenation of halogenated nitrobenzenes被引量:3
《Chinese Chemical Letters》2014年第2期205-208,共4页Jing-Hui Lyu Xiao-Bo He Chun-Shan Lu Lei Ma Qun-Feng Zhang Feng Feng Xiao-Nian Li Jian-Guo Wang 
supported by the National Natural Science Foundation of China(Nos.20976164,21176221 and 21136001);National Basic Research Program of China(973 Program)(Nos. 2011CB710803,2013CB733500);Zhejiang Provincial Natural Science Foundation of China(No.LY12B03005)
This study shows that minor amount of water plays a very important role in solvent-free hydrogenation of halogenated nitrobenzenes. For dried sponge Pd, the reaction cannot occur in the absence of water. For Pd/C cata...
关键词:Halogenated nitrobenzenes Solvent Free WATER HYDROGENATION 
Selective Reduction of Nitroarenes with Molybdenum Disulfide被引量:1
《Chinese Journal of Chemistry》2013年第8期987-991,共5页Lei Huang Pingfei Luo Man Xiong Rizhi Chen Yong Wang Weihong Xing Jun Huang 
Commercial MoS2 was found to be a highly selective catalyst for the reduction of nitrobenzenes to the corre- sponding anilines with hydrazine under mild conditions. MoS2 is not only much cheaper, but also more selecti...
关键词:ANILINES REDUCTION molybdenum disulfide NITROBENZENES 
A DFT-based Quantum Theoretic QSAR Study of Nitrobenzenes' Toxicity to Tetrahymena Pyriformis被引量:5
《Chinese Journal of Structural Chemistry》2010年第1期86-92,共7页顾云兰 陶建清 费正皓 张根成 
supported by the Natural Science Foundation of Yancheng Teachers University (08YCKL077);the Jiangsu Provincial Key Laboratory of Coastal Wetland Bioresources & Environmental Protection (JLCBE 07025);the Educational Bureau of Jiangsu Province (08KJD150021)
In this study,DFT-B3LYP level of theory with the 6-311G basis set was used to calculate a set of molecular descriptors of 36 nitrobenzenes.Quantitative structure-activity relationship(QSAR) models of the toxicity(p...
关键词:NITROBENZENES TOXICITY DFT QSAR 
QSAR Study of Nitrobenzenes’ Toxicity to Tetrahymena Pyriformis Using Semi-empirical Quantum Chemical Methods被引量:16
《Chinese Journal of Structural Chemistry》2007年第1期7-14,共8页闫秀芬 肖鹤鸣 
This work was supported by the National Natural Science Foundation of China (No.10576030)
The molecular geometries and electronic structures of 30 nitrobenzenes have been calculated by using semi-empirical MO AM1 and PM3 methods. EHOMO, ELUMO, ENHOMO, ENLUMO, AE, QNO2, Qc and V were selected as the structu...
关键词:NITROBENZENES TOXICITY QSAR semi-empirical MO orbital methods 
Effects of Nitrobenzenes on DNA Damage in Germ Cells of Rats被引量:7
《Chemical Research in Chinese Universities》2006年第1期29-32,共4页XU Jing-bo JING Ti-song YANG Li SUN Zhi-wei SHI Long 
SupportedbyNationalNaturalScienceFoundationofChina(No.30370262),NaturalScienceFoundationofJilinProvince(No.20020633-2),NationalBasicResearchProgram(973Project)ofChina(No.2004CB418505)andSubjectConstructionofDoctoralDe-greebytheMinistryofEducationofChina(No.20040200002).
The single cell gel electrophoresis (SCGE) technique was used to detect DNA damage in germ cells of rats, which was induced by five tested nitroaromatic compounds. Mixed cultures of Sertoli and germ cells were prepa...
关键词:Nitroaromatic compound Sertoli-germ cell coculture SCGE DNA damage 
QSAR Studies on the Toxicity of Nitrobenzenes to Population Growth of Tetrahymena Pyriformis被引量:9
《Chemical Research in Chinese Universities》2002年第3期258-261,共4页XU Jing-bo JING Ti-song Pauli W. Berger S. 
Supported by the Educational Ministry Foundation of China(No. 0 10 6 3) .Tetrahymena pyriformis B was kindlysupplied by Dr.Tiedke;Münster
The IGC 50 (50% inhibitory growth concentration) values of 27 nitrobenzenes were determined for the population growth endpoint of Tetrahymena pyriformis . The toxicity order of the observed compounds was found to be a...
关键词:Tetrahymena pyriformis NITROBENZENE QSAR 
Nucleophilic Aromatic Substitution of Nitrobenzenes with Nitrite Ion
《Chinese Chemical Letters》1997年第3期193-194,共2页Zhi Qiang ZHANG Zheng Hua TIAN (Anshan Institute of Iron & Steel Technology, Anshan 114002) 
It is experimentally found that different renction courses exist when mtrite ion reacts with nitrobenzenes with different electron withdrawing groups. when it is substituted with strong electron withdrawing groups. se...
关键词:Nucleophilic Aromatic Substitution of Nitrobenzenes with Nitrite Ion 
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