supported by the National Key R&D Program of China(grant no.2022YFA1504302);the National Natural Science Foundation of China(grant nos.22188101,91956000,and 92256301);the Fundamental Research Funds for the Central Universities,and the Haihe Laboratory of Sustainable Chemical Transformations.
Asymmetric hydrogenation of dialkyl imines to chiral amines is difficult because the two alkyls of imines are so similar in spatial and electronic structure that chiral catalysts are difficult to distinguish between t...
the financial support from the National Natural Science Foundation of China(nos.21788102,22020102006,21722603,and 21871083);project support by the Shanghai Municipal Science and Technology Major Project(grant no.2018SHZDZX03);Program of Shanghai Academic/Technology Research Leader(no.20XD1421300);“Shu Guang”project supported by Shanghai Municipal Education Commission and Shanghai Education Development Foundation(no.19SG26);the Innovation Program of Shanghai Municipal Education Commission(no.201701-07-00-02-E00010);the Fundamental Research Funds for the Central Universities.
For the first time,a series of photochromic dyes SP1-3 with dual-responsive thermally activated delayed fluorescence(TADF)characteristics were reported in this research.Benefitting from the reversible light-responsive...
the Free Exploration Fund from the Shenzhen Science and Technology Innovation Committee(JCYJ20170817105056467);the Youth Fund from National Natural Science Foundation of China(No.21901107);X.Zhang is indebted to Southern University of Science and Technology(start-up fund),Shenzhen Science and Technology Innovation Committee(nos.KQTD20150717103157174 and JSGG20170821140353405);Guangdong Provincial Key Laboratory of Catalysis(No.2020B121201002);National Natural Science Foundation of China(No.21991113);SZDRC Discipline Construction Program for financial support.
We herein present the design and synthesis of a structurally unique oxa-spirocyclic diphosphine ligand,termed as O-SDP.The diphosphine ligand O-SDP derived from oxa-spirocyclic diphenols(O-SPINOL)has a relatively larg...
The authors thank the National Natural Science Founda-tion of China(Grant#s.21790332 and 21532003);the“111”project(Grant#B06005)of the Ministry of Educa-tion of China for their financial support.
We report an enantioselective hydroarylation reaction of styrenes and 1,3-dienes with arylboronic acids catalyzed by nickel complexes bearing chiral spiro amino phosphine ligands.The reaction serves as an efficient,st...