DIPHOSPHINE

作品数：16被引量：12H指数：2
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相关领域：理学更多>>
相关作者：唐元友李贤均李瑞祥周向葛余长斌更多>>
相关机构：四川大学中国科学院更多>>
相关期刊：《Chinese Journal of Chemistry》《Science China Chemistry》《Chemical Research in Chinese Universities》《Chinese Journal of Structural Chemistry》更多>>
相关基金：国家自然科学基金广东省自然科学基金高等学校学科创新引智计划国家重点基础研究发展计划更多>>
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Design and synthesis of novel 1,3-diene bridged chiral atropoisomeric diphosphine ligands for asymmetric hydrogenation ofα-dehydro amino ketones
《Science China Chemistry》2023年第10期2847-2851,共5页Xuefeng Tan Shuang Gao Chunyan Yang Qiwei Lang Xiaobing Ding Gen-Qiang Chen Xumu Zhang 
the National Key R&D Program of China(2021YFA1500201);the Stable Support Plan Program of Shenzhen Natural Science Fund(20200925161222002);the Key-Area Research and Development Program of Guangdong Province(2020B010188001);the Innovative Team of Universities in Guangdong Province(2020KCXTD016);the National Natural Science Foundation of China(21991113);the Guangdong Basic and Applied Basic Research Foundation(2022B1515020055);the National Natural Science Foundation of China(22171129);Shenzhen Science and Technology Innovation Committee(JCYJ20210324104202007)for financial support。
A series of novel atropisomeric diphosphine ligands termed Tan Phos were designed and synthesized,which has a smaller bite angle compared with that of other ligands such as BINAP.Tan Phos showed high reactivity and en...
关键词：DIPHOSPHINE asymmetric hydrogenation chiral ligand 
Semi-Hydrogenation of Alkynes by a Tandem Photoredox System Free of Noble Metal被引量：1
《CCS Chemistry》2022年第8期2597-2603,共7页Tao Yuan Shuwen Huan Bingqing Ge Sen Lin Meifang Zheng Xinchen Wang 
supported by the National Natural Science Foundation of China(grant nos.22071026,21673040,21961142019,22032002,and U1905214);the National Key R&D Program of China(no.2018YFA0209301);the Chang Jiang Scholars Program of China(no.T2016147),and the 111 Project(no.D16008).
The selective hydrogenation reactions play a key role in industrial manufacture of fine chemicals,which mainly rely on noble metal catalysts.Herein,a noble-metal-free hybrid photosystem is established,in which boron c...
关键词：boron carbonitride nickel bis-diphosphine complex photocatalysis selective hydrogenation ALKYNE 
Synthesis, Structure and Photophysical Properties of a Dinuclear Copper (Ⅰ) Complex Based on Phosphinopyridine and Diphosphine Mixed-ligands
《Chinese Journal of Structural Chemistry》2021年第2期175-181,145,共8页YU Wen-Si HUANG Chun-Hua HUANG Xi-He 
supported by the Natural Science Foundation of Fujian Province(2017J01576)。
Treatment of bis(diphenylphosphino)methane(dppm)and 2-(diphenylphosphanyl)pyridine(dpppy)with Cu(CH_(3)CN)_(4)BF_(4)afforded a dinuclear Cu(I)complex[Cu_(2)(dpppy)_(2)(dppm)(CH_(3)CN)](BF_(4))_(2)·3CH_(2)Cl_(2)(1).Co...
关键词：copper(I)complex thermally activated delayed fluorescence crystalline structure 
Highly Enantioselective Hydrogenation of tetra-and tri-Substitutedα,β-Unsaturated Carboxylic Acids with oxa-Spiro Diphosphine Ligands被引量：4
《CCS Chemistry》2020年第6期468-477,共10页Gen-Qiang Chen Jia-Ming Huang Bi-Jin Lin Chuan Shi Ling-Yu Zhao Bao-De Ma Xiao-Bing Ding Qin Yin Xumu Zhang 
the Free Exploration Fund from the Shenzhen Science and Technology Innovation Committee(JCYJ20170817105056467);the Youth Fund from National Natural Science Foundation of China(No.21901107);X.Zhang is indebted to Southern University of Science and Technology(start-up fund),Shenzhen Science and Technology Innovation Committee(nos.KQTD20150717103157174 and JSGG20170821140353405);Guangdong Provincial Key Laboratory of Catalysis(No.2020B121201002);National Natural Science Foundation of China(No.21991113);SZDRC Discipline Construction Program for financial support.
We herein present the design and synthesis of a structurally unique oxa-spirocyclic diphosphine ligand,termed as O-SDP.The diphosphine ligand O-SDP derived from oxa-spirocyclic diphenols(O-SPINOL)has a relatively larg...
关键词：asymmetric hydrogenation DIPHOSPHINE O-SDP O-SPINOL 
Diphosphine-induced chiral propeller arrangement ofgold nanoclusters for singlet oxygen photogeneration被引量：2
《Nano Research》2018年第11期5787-5798,共12页Jiangwei Zhang Yang Zhou KaiZheng Hadi Abroshan Douglas R. Kauffman Junliang Sun Gao Li 
G. L. acknowledges financial supports by the fund of the National Natural Science Foundation of China （No. 21701168） and the Liaoning Natural Science Foundation （No. 20170540897）, and beamline BL14B （Shanghai Synchrotron Radiation Facility） for providing the beam time. A portion of this report was prepared as an account of work sponsored by an agency of the United States Government （D. R. K.）. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accurac~ completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights.
Making Spiroketal-based Diphosphine （SKP） Ligands via a Catalytic Asymmetric Approach被引量：1
《Chinese Journal of Chemistry》2018年第10期899-903,共5页Xiaoming Wang Kuiling Ding 
The spiro concept for chiral ligand design represents an important contribution to the area of asymmetric catalysis. Due to the considerable difficulties in the construction of enantiopure all-carbon spiro backbones, ...
关键词：chiral ligand spiro compounds SPIROKETAL asymmetric catalysis HYDROGENATION 
Asymmetric Hydrosilylation of Aromatic Ketones Catalyzed by an Economical and Effective Copper-Diphosphine Catalytic System in Air
《Chinese Journal of Chemistry》2015年第5期578-582,共5页Minting Liang Xiaofeng Xia Xiang Liu Hexing Li 
the National Natural Science Foundation of China(No.21402066);the Open Project of the Key Laboratory of the Chinese Ministry of Education in Resource Chemistry.
In the presence of the inexpensive and non-toxic polymethylhydrosiloxane, the combination of copper(II) acetateand a chiral diphosphine displayed high catalytic efficiency in the asymmetric hydrosilylation of a series...
关键词：asymmetric catalysis HYDROSILYLATION KETONES copper salt POLYMETHYLHYDROSILOXANE 
Asymmetric hydrogenation of aromatic ketones using new chiral-bridged diphosphine/diamine-Ru(Ⅱ) complexes
《Chinese Chemical Letters》2010年第12期1403-1406,共4页Yu Ming Cui Lai Lai Wang Fuk Yee Kwong Wei Sun 
the National Natural Science Foundation of China(Nos.20343005,20473107,20673130,and 20773147);the Hong Kong PolyU Joint Supervision Scheme(A-PH78) for financial support.
A series of chiral secondary alcohols were easily prepared by means of asymmetric hydrogenation of prochiral aromatic ketones using a new（（Rax）-BuP）/（R,R）-DPEN-Ru（Ⅱ） complex catalyst system.The hydrogenation ...
关键词：Asymmetric hydrogenation Chiral alcohols Diphosphine ligand Ruthenium complexes DIAMINE 
Alkoxy substituted MeO-BIPHEP-type diphosphines ligands for asymmetric hydrogenation of aryl ketones被引量：2
《Chinese Chemical Letters》2010年第5期576-579,共4页Meng Lin Ma Zong Hai Peng Yu Guo Li Chen Hua Chen Xian Jun Li 
the NSFC(No.20272037),the Doctor's Foundation of Education Ministry of China(No.20030610022);Foundation of Xihua University(No.R0723315) and(No.07ZA109) for the financial support of this work.
In this paper,a series of optically active MeO-BIPHEP-type ligands,（S）-6,6′-dimethoxy-2,2’-bis（di-p-alkoxyphenylphosphine）- 1,1′-biphenyl were synthesized and used to prepare the ruthenium complex.The effects o...
关键词：Aryl ketone Asymmetric hydrogenation Biaryl phosphines ligands Ruthenium complex 
Rhodium catalyzed asymmetric Pauson-Khand reaction using SDP ligands
《Science China Chemistry》2006年第1期81-87,共7页FAN Baomin1, LI Shen2, XIE Jianhua2, WANG, Lixin2, TU Yongqiang1 & ZHOU Qilin2 1. State Key Laboratory of Applied Organic Chemistry,Lanzhou University,Lanzhou 730000,China 2. State Key Laboratory of Elemento-organic Chemistry,Nankai University,Tianjin 300071, China 
This work was supported by the National Natural Science Foundation of China (Grant Nos. 20132010 and 20272026); the Major State Basic Research Development Program (Grant No. G2000077506); the Ministry of Education of China and the Committee of Science and Technology of Tianjin City for financial support.
The activity and enantiocontrol ability of the chiral catalysts prepared from spiro di-phosphine ligands, SDP, and rhodium precursor were investigated in the asymmetric catalytic Pau-son-Khand reaction. The results sh...
关键词：Pauson-Khand reaction  ASYMMETRIC catalysis  DIPHOSPHINE ligand  rhodium. 
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