HYDROFORMYLATION

作品数:63被引量:60H指数:4
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相关作者:丁云杰李存耀姜淼刘佳严丽更多>>
相关机构:中国科学院中国科学院大学更多>>
相关期刊:《Science China Chemistry》《China Petroleum Processing & Petrochemical Technology》《Progress in Natural Science:Materials International》《Chinese Journal of Catalysis》更多>>
相关基金:国家自然科学基金国家重点基础研究发展计划中国科学院战略性先导科技专项霍英东教育基金更多>>
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  • 期刊=Chinese Chemical Lettersx
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Synthesis of rac-α-aryl propionaldehydes via branched-selective hydroformylation of terminal arylalkenes using water-soluble Rh-PNP catalyst被引量:1
《Chinese Chemical Letters》2022年第2期830-834,共5页Peng Gao Miaolin Ke Tong Ru Guanfeng Liang Fen-Er Chen 
financial support from the National Natural Science Foundation of China (No.21902032)。
This work detailed the preparation of a class of water-soluble PNP ligands that differed by the nature of the substitute on phenyl ring of ligands. These ligands were incorporated into water-soluble rhodium-PNP comple...
关键词:Aryl propionaldehydes HYDROFORMYLATION Water-soluble PNP ligands Regioselectivity RHODIUM 
Highly active rhodium]phosphorus catalytic system for the hydroformylation of α-methylstyrene
《Chinese Chemical Letters》2016年第5期678-680,共3页Xue-Li Zheng Cong-Ye Zheng Fan-Ding Zhou Hai-Yan Fu Mao-Lin Yuan Rui-Xiang Li Bin Xu Hua Chen 
financial support from the National Natural Science Foundation of China (No. 201202108);from the Opening Project of Key Laboratory of Green Chemistry of Sichuan Institutes of Higher Education (No. LZJ1402);from the Sichuan university outstanding scholar research fund (No. 2015SCU04A05)
Rhodium catalyzed hydroformylation of α-methylstyrene was investigated in the presence of monodentate phosphine ligands L1-L6. We found that the phosphine with good n-acceptability could efficiently improve the activ...
关键词:α-Methytstyrene Hydroformylation Rh complex Phosphine Pyrrole 
A theoretical study on the alkene insertion step in Rh-Yanphos catalyzed hydroformylation被引量:2
《Chinese Chemical Letters》2013年第12期1083-1086,共4页Xiao-Jie Du Yan-Hui Tang Xin Zhang Ming Lei 
in part supported by the National Natural Science Foundation of China (Nos. 21072018 and 21203006)
This paper studied the mechanism of the alkene insertion elementary step in the asymmetric hydroformylation (AHF) catalyzed by RhH(CO)2[(R,S)-Yanphos] using four alkene substrates (CH2=CH- Ph, CH2=CH-Ph-(p)-M...
关键词:DFT Hydroformylation Mechanism Alkene insertion Coordination mode 
A novel thermoregulated phosphine ligand used for the Rh-catalyzed hydroformylation of mixed C_(11-12) olefins in aqueous/organic biphasic system被引量:2
《Chinese Chemical Letters》2010年第5期515-518,共4页Zhi Jiang Ji,Jing Yang Jiang,Yan Hua Wang State Key Laboratory of Fine Chemicals,Dalian University of Technology,Dalian 116012,China 
the financial support from the Program for New Century Excellent Talents in University (No.NCET-07-0138);the Science and Technology Project in Universities from the Education Department of Liaoning Province(No.2008T233).
A novel thermoregulated phosphine ligand PhP(CHCHO)CH(n=22) was synthesized and used for the Rh-catalyzed hydroformylation of mixed Colefins in aqueous/organic biphasic system.Under the optimized conditions,pressure =...
关键词:Thermoregulated phosphine ligand Mixed C11-12 olefins HYDROFORMYLATION RHODIUM 
A novel phosphate ligand used for the Rh-catalyzed hydroformylation of cyclohexene in a thermoregulated PEG biphase system被引量:1
《Chinese Chemical Letters》2007年第8期933-935,共3页Wei Wei Yan Hua Wang Jing Yang Jiang Zi Lin Jin 
Financial support from Fok Ying Tung Education Foundation(No.91071);the National Natural Science Foundation of China(No.20376013)are gratefully acknowledged.
A novel phosphate ligand, tri-(methoxyl polyethylene glycol)-phosphate (TMPGPA), has been synthesized and used in the Rhcatalyzed hydroformylation of cyclohexene in a thermoregulated PEG biphase system. Under the ...
关键词:Thermoregulated PEG biphase system HYDROFORMYLATION Phosphate ligand RHODIUM CYCLOHEXENE 
Biphasic Catalytic Hydroformylation of 1-Dodecene in Micellar System with Cationic Gemini Surfactants被引量:1
《Chinese Chemical Letters》2004年第9期1022-1024,共3页MinLI BinXU HuaCHEN HongJieZHENG XueYuanHUANG YaoZhongLI XianJunLI 
The promotion effect of cationic gemini surfactants for the hydroformylation of 1-dodecene in the organic/aqueous biphasic catalytic system is reported. The hydroformylation reaction in the presence of gemini surfacta...
关键词:HYDROFORMYLATION gemini surfactant 1-DODECENE rhodium catalyst. 
Aqueous Biphasic Hydroformylation of Oleyl Alcohol Catalyzed by Thermoregulated Rhodium Complex
《Chinese Chemical Letters》2003年第9期917-919,共3页Fan Zhi KONG, Xiao Lai ZHENG, Zi Lin JIN State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012 
support from the National Natural Science Foundation of China.(Grant no.29906001).
The aqueous biphasic hydroformylation of oleyl alcohol was achieved under thermo-regulated phase transfer catalysis (TRPTC) conditions with Rh(acac)(CO)2 Ph2P[p-C6H4 (OCH2CH2)25OH] (PETPP) complex catalyst formed in s...
关键词:RHODIUM HYDROFORMYLATION oleyl alcohol TRPTC. 
The Performance of Rhodium Complex-diphosphine Systems in the Hydroformylation of 1-Dodecene
《Chinese Chemical Letters》2003年第6期623-626,共4页Xue Yuan HUANG Rui Xiang LI Hua CHEN Xian Jun LI 
We thank the National Basic Research Project of China(G2000048008)for the financial support.
The catalytic performances of four HRh(CO)(PPh3)3-diphosphine (BISBI,BDPX, BDNA and BINAP) systems in 1-dodecene hydroformylation were investigated and compared with HRh(CO)(PPh3)3-PPh3 system. The catalyst system HR...
关键词:HYDROFORMYLATION 1-DODECENE DIPHOSPHINE rhodium complex. 
Studies on the Recycling Efficiency of Thermoregulated Phase-separable Rh/PETPP Complex Catalyst被引量:1
《Chinese Chemical Letters》2003年第1期91-93,共3页Yan Hua WANG Fang CHENG Xiao Wei WU Zi Lin JIN 
The financial support of the National Natural Science Foundation of China (grant no. 29906001) and the Research Institute of Petroleum Processing; China Petroleum & Chemical Corporation is gratefully acknowledged.
Effects on the recycling efficiency of thermoregulated phase-separable Rh/PETPP (P-[p-C6H4O(CH2CH2O)nH]3, N=3n) complex catalyst involved in hydroformylation of 1-decene are for the first time presented. It was found...
关键词:Thermoregulated phase-separable catalysis (TPSC) HYDROFORMYLATION nonionic phosphine ligand rhodium. 
Hydroformylation of Oleyl Alcohol Catalyzed by Rh-OPGPP Complex
《Chinese Chemical Letters》2002年第6期497-498,共2页Fan Zhi KONG Yan Hua WANG Zi Lin JIN 
The authors are grateful to the financial support from the National Natural Science Foundation of China(Grant No.29906001)
Polyether-tailored phosphite modified rhodium complex formed in situ was highly active in the hydroformylation of oleyl alcohol in nonaqueous phosphite/heptane system where the phosphite acted both as the ligand and t...
关键词:PHOSPHITE HYDROFORMYLATION oleyl alcohol nonaqueous biphasic catalysis. 
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