HYDROFORMYLATION

作品数：63被引量：60H指数：4
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相关机构：中国科学院中国科学院大学更多>>
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Hydroformylation of olefins catalyzed by chiral phosphite-Rh(I)complexes
《Chinese Science Bulletin》2003年第20期2188-2192,共5页YANMing LIXingshu CHANAlbertSunchi 
supported by the Research Starting Funds of Suzhou University(Grant No.Q4109308);ASD Funds of Hong Kong Polytechnic University.
A series of chiral phosphite ligands based on chiral binaphthol have been designed and synthesized. Their Rhodium(I) complexes were found to be efficient catalysts for the asymmetric hydroformylation of styrene and vi...
关键词：亚磷酸铑 手性化合物 合成 不对称加氢甲酰化作用 催化反应 石蜡 
Aqueous Biphasic Hydroformylation of Oleyl Alcohol Catalyzed by Thermoregulated Rhodium Complex
《Chinese Chemical Letters》2003年第9期917-919,共3页Fan Zhi KONG, Xiao Lai ZHENG, Zi Lin JIN State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012 
support from the National Natural Science Foundation of China.(Grant no.29906001).
The aqueous biphasic hydroformylation of oleyl alcohol was achieved under thermo-regulated phase transfer catalysis (TRPTC) conditions with Rh(acac)(CO)2 Ph2P[p-C6H4 (OCH2CH2)25OH] (PETPP) complex catalyst formed in s...
关键词：RHODIUM HYDROFORMYLATION oleyl alcohol TRPTC. 
Hydroformylation of Oleyl Alcohol Catalyzed by Rh-OPGPP Complex
《Chinese Chemical Letters》2002年第6期497-498,共2页Fan Zhi KONG Yan Hua WANG Zi Lin JIN 
The authors are grateful to the financial support from the National Natural Science Foundation of China(Grant No.29906001)
Polyether-tailored phosphite modified rhodium complex formed in situ was highly active in the hydroformylation of oleyl alcohol in nonaqueous phosphite/heptane system where the phosphite acted both as the ligand and t...
关键词：PHOSPHITE HYDROFORMYLATION oleyl alcohol nonaqueous biphasic catalysis. 
Preliminary Exploration of the Reactor Configuration for Hydroformylation of 1-Dodecene Catalyzed by Water Soluble Rhodium Complex
《Chinese Journal of Chemical Engineering》2002年第1期45-51,共7页毛在砂 毕新艳 禹耕之 张永强 杨超 王蓉 
the National Natural Science Foundation of China (No. 29792074) and SINOPEC.
Hydroformylation of 1-dodecene was studied in a biphasic systemusing water-soluble rhodium complex [RhCl(CO)(TPPTS)_2] as catalystin the presence of cetyl trimethyl ammonium bromide as surfactant toenhance the reactio...
关键词：1-DODECENE biphasic hydroformylation gas-liquid-liquid reactor reaction engineering 
Ab Initio MO Studies on the Reaction Mechanism for Carbonyl Insertion Catalyzed by Carbonyl Cobalt Complex被引量：1
《Chemical Research in Chinese Universities》2000年第1期31-35,共5页LEI Ming FENG Wen-lin and XU Zhen-feng (Department of Applied Chemistry, Beijing University of Chemical Technology,Beijing 100029, P. R. China Department of Chemistry, Beijing Normal University, Beijing 100875, P. R. China) 
Ab initio method, under the effective core potential(ECP) approximation at HF/LANL2DZ level, has been employed to study the reaction mechanism of the carbonyl insertion of olefin hydroformylation catalyzed by a carbo...
关键词：Carbonyl Cobalt HYDROFORMYLATION Ab initio method Effective core potential 
HYDROFORMYLATION OF OLEFINS CATALYZED BY HOMOGENEOUS HETERONUCLEAR METAL CLUSTER [PhCH_2Me_3N][FeCo_3(CO)_(12)]
《分子催化》1990年第S1期10-17,共8页Luo Yuzhong, Fu Hongxiang, Zhang Shuwei(Lanzhou Institute of Chemical Physics, Chinese Academy of Science, Lanzhou, China) Wang Yunpu, Wu Nan, Zhang Aimi(Northwestern Teachers College, Lanzhou, China) 
This work was supported by National Natural Science Foundation of China.
Hydroformylation of olefins catalyzed by heteronuclear metal cluster [PhCH2Me3N]-[FeCo3（CO）12] was studied. The effect of temperature, pressure, and solvent ect. on olefin...
关键词：selectivity FECO CATALYZED olefin styrene hydrogenation ALDEHYDE MONOXIDE carbonyl alcohols 
HYDROFORMYLATION OF ETHYLENE CATALYZED BY HOMOGENEOUS METAL CLUSTERS
《分子催化》1989年第S1期88-93,共6页Fu Hongxiang, Luo Yuzong , Zhang Shuwei, Ren Xu (Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, China) 
This work was supported by Science Foundation of Chinese Academy of Sciences
This paper deals with a study of hydroformylation of ethylene catalyzed by homoge-neous metal clusters.〔PhCH2Me3N〕〔FeCo3（CO）12〕and〔PhCH2Me3N〕〔...
关键词：FECO faster SELECTIVITY tempera spectroscopic CRYSTALLINE CATALYZED silica deals CARBONYL 
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