HYDROFORMYLATION

作品数:63被引量:60H指数:4
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相关作者:丁云杰李存耀姜淼刘佳严丽更多>>
相关机构:中国科学院中国科学院大学更多>>
相关期刊:《Science China Chemistry》《China Petroleum Processing & Petrochemical Technology》《Progress in Natural Science:Materials International》《Chinese Journal of Catalysis》更多>>
相关基金:国家自然科学基金国家重点基础研究发展计划中国科学院战略性先导科技专项霍英东教育基金更多>>
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Tandem hydroformylation/hydrogenation of olefins to alcohols using atomically dispersed bifunctional catalysts
《Science China Chemistry》2024年第11期3706-3711,共6页Ying Zhang Liyang Liu Ziyue Wang Xingcong Zhang Xiaohui He Hongbing Ji 
supported by the National Key Research and Development Program Nanotechnology Specific Project (2020YFA0210900);the Guangdong Natural Science Funds for Distinguished Young Scholar (2022B1515020035);the National Natural Science Foundation of China (22078371, U22A20428, 21961160741);the Special Fund for Science and Technology Innovation Teams of Shanxi Province (202304051001007)。
Tandem hydroformylation/hydrogenation of olefins to alcohols is an appealing and challenging route that has received continuous interest. Herein, we report a bifunctional atomically dispersed Rh and Co catalyst(Rh Co/...
关键词:TANDEM hydroformylation/hydrogenation ALCOHOLS BIFUNCTIONAL single atom catalysts 
Activity promotion of Rh_(1)Ca_(x)/Al_(2)O_(3) single-atom catalyst in 1-octene hydroformylation:a volcano curve exists between Ca adding ratio and catalytic activity被引量:2
《Science China Chemistry》2024年第4期1187-1192,共6页Hao Zhang Xingcong Zhang Xilun Wang Qingdi Sun Hao Liu Hongbing Ji Xiaohui He 
supported by the National Key Research and Development Program Nanotechnology Specific Project(2020YFA0210900);the Science and Technology Key Project of Guangdong Province,China(2020B010188002);Guangdong Natural Science Funds for Distinguished Young Scholar(2022B1515020035);Guangdong Provincial Key R&D Program(2019B110206002);the National Natural Science Foundation of China(22078371,21938001,21961160741);the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program(2017BT01C102);the Natural Science Foundation of Guangdong Province(2020A1515011141);the Science and Technology Project of Guangzhou City,China(202102020461)。
Single-atom catalysts(SACs)are considered the best candidates for olefin hydroformylation due to their combined advantages of homogeneous and heterogeneous catalysts.Unlike conventional organo-phosphine modification,R...
关键词:HYDROFORMYLATION bimetallic single-atom catalysts RHODIUM heterogeneous catalyst 
Hydroformylation over polyoxometalates supported single-atom Rh catalysts
《National Science Open》2023年第2期161-174,共14页Shixiang Feng Qi Yu Xinbin Ma Xiaohu Yu Ning Yan 
supported by the National Natural Science Foundation of China(92061109 and 22273053);the Natural Science Basic Research Program of Shaanxi(2021JCW-20 and 2022KJXX-18).
Atomic dispersion of Rh on phosphotungstic acid(PTA)salts was achieved by a self-assembled precipitation method using alkali metal ions as coprecipitation reagents.During styrene hydroformylation,the supported Rh sing...
关键词:POLYOXOMETALATES Rh single-atom HYDROFORMYLATION SELF-ASSEMBLY STYRENE 
Synthesis of rac-α-aryl propionaldehydes via branched-selective hydroformylation of terminal arylalkenes using water-soluble Rh-PNP catalyst被引量:1
《Chinese Chemical Letters》2022年第2期830-834,共5页Peng Gao Miaolin Ke Tong Ru Guanfeng Liang Fen-Er Chen 
financial support from the National Natural Science Foundation of China (No.21902032)。
This work detailed the preparation of a class of water-soluble PNP ligands that differed by the nature of the substitute on phenyl ring of ligands. These ligands were incorporated into water-soluble rhodium-PNP comple...
关键词:Aryl propionaldehydes HYDROFORMYLATION Water-soluble PNP ligands Regioselectivity RHODIUM 
Monolithic membrane reactors based on supported ionic liquid phase(SILP)materials–hydroformylation and water-gas shift case studies
《Green Chemical Engineering》2021年第4期339-341,共3页Markus Schorner Patrick Wolf Marco Haumann 
support from the European Commission within the H2020 projects ROMEO(grant agreement number 680395);MACBETH(grant agreement number 869896).
Homogeneous catalysts,usually being active in liquid environment,offer several benefits for highly selective processes.However,the often tedious product separation and catalyst recycling,requiring energy and chemical ...
关键词:IONIC CATALYST LIQUID 
Hydroformylation of formaldehyde to glycolaldehyde:An alternative synthetic route for ethylene glycol被引量:2
《Chinese Journal of Chemical Engineering》2021年第7期3-16,共14页Jie Wei Maoshuai Li Meiyan Wang Shixiang Feng Weikang Dai Qi Yang Yi Feng Wanxin Yang Cheng Yang Xinbin Ma 
supported by the National Key Research and Development Program of China(2018YFA0704501).
Hydroformylation of formaldehyde to glycolaldehyde(GA),as a vital reaction in both direct and indirect process of syngas to ethylene glycol(EG),shows great advantages in the aspects of the process complexity and clean...
关键词:FORMALDEHYDE SYNGAS HYDROFORMYLATION GLYCOLALDEHYDE Ethylene glycol Mechanism 
Catalytic System for Manufacturing Butanol via Hydroformylation of Low-Carbon Olefins Developed Jointly by CNOOC and Others
《China Petroleum Processing & Petrochemical Technology》2021年第2期83-83,共1页
Recently,the project“Development and application of low-temperature and high-selectivity catalytic system for hydroformylation of low-carbon olefins”jointly undertaken by the China National Offshore Oil Company(CNOO...
关键词:jointly CATALYTIC Tianjin 
Study on Technology Clusters for Direct Utilization of CO2-Rich Natural Gas and Construction of Hybrid System for Energy and Chemicals Production被引量:3
《China Petroleum Processing & Petrochemical Technology》2020年第2期1-9,共9页Wu Qing 
Based on industrial production with an annual capacity of million tons of methanol,ammonia/urea,etc.,a platform technology is developed for direct,green,efficient,and high-value mega-size utilization of the CO2-rich n...
关键词:CO2-riched natural gas dry reforming Fischer-Tropsch to olefins Fischer-Tropsch to aromatics linear hydroformylation techno-economic evaluation 
Highly efficient Rh(Ⅰ)/tris-H_8-binaphthyl monophosphite catalysts for hydroformylation of dicyclopentadiene to dialdehydes被引量:4
《Chinese Journal of Catalysis》2018年第10期1646-1652,共7页Mi Tian Haifeng Li Lailai Wang 
国家自然科学基金(21633013,21073211,21174155);2016年南沙技术攻关项目(2016GG007).
Novel catalytic systems for the Rh‐catalyzed hydroformylation of dicyclopentadiene have been developed using tris‐H8‐binaphthyl monophosphite as ligands containing different ester substituents at the 2’‐binaphthy...
关键词:HYDROFORMYLATION DICYCLOPENTADIENE Monophosphite DIALDEHYDE Homogeneous catalysis 
Hydroformylation of 1-Octene over Nanotubular TiO2-supported Amorphous Co-B Catalysts被引量:4
《Chemical Research in Chinese Universities》2015年第5期851-857,共7页SHI Yukun HU Xiaojing ZHU Baolin ZHANG Shoumin HUANG Weiping 
Supported by the National Natural Science Foundation of China(Nos.21373120, 21301098, 21071086, 21271110), the National "111" Project of China's Higher Education(No.B 12015), the Applied Basic Research Programs of Science and Technology Commission Foundation ofTianjin, China(Nos.13JCQNJC02000, 12JCYBJC13100).
TiO2 nanotubes supported amorphous Co-B(Co-B/TNTs) catalyst was prepared via impregnation- chemical reduction procedure. The catalyst was characterized with transmission electron microscopy(TEM), ammonia temperatu...
关键词:HYDROFORMYLATION TiO2 nanotubes Amorphous Co-B 1-OCTENE 
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