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supported by the National Key Research and Development Program Nanotechnology Specific Project (2020YFA0210900);the Guangdong Natural Science Funds for Distinguished Young Scholar (2022B1515020035);the National Natural Science Foundation of China (22078371, U22A20428, 21961160741);the Special Fund for Science and Technology Innovation Teams of Shanxi Province (202304051001007)。
Tandem hydroformylation/hydrogenation of olefins to alcohols is an appealing and challenging route that has received continuous interest. Herein, we report a bifunctional atomically dispersed Rh and Co catalyst(Rh Co/...
supported by the National Key Research and Development Program Nanotechnology Specific Project(2020YFA0210900);the Science and Technology Key Project of Guangdong Province,China(2020B010188002);Guangdong Natural Science Funds for Distinguished Young Scholar(2022B1515020035);Guangdong Provincial Key R&D Program(2019B110206002);the National Natural Science Foundation of China(22078371,21938001,21961160741);the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program(2017BT01C102);the Natural Science Foundation of Guangdong Province(2020A1515011141);the Science and Technology Project of Guangzhou City,China(202102020461)。
Single-atom catalysts(SACs)are considered the best candidates for olefin hydroformylation due to their combined advantages of homogeneous and heterogeneous catalysts.Unlike conventional organo-phosphine modification,R...
supported by the National Natural Science Foundation of China(92061109 and 22273053);the Natural Science Basic Research Program of Shaanxi(2021JCW-20 and 2022KJXX-18).
Atomic dispersion of Rh on phosphotungstic acid(PTA)salts was achieved by a self-assembled precipitation method using alkali metal ions as coprecipitation reagents.During styrene hydroformylation,the supported Rh sing...
financial support from the National Natural Science Foundation of China (No.21902032)。
This work detailed the preparation of a class of water-soluble PNP ligands that differed by the nature of the substitute on phenyl ring of ligands. These ligands were incorporated into water-soluble rhodium-PNP comple...
support from the European Commission within the H2020 projects ROMEO(grant agreement number 680395);MACBETH(grant agreement number 869896).
Homogeneous catalysts,usually being active in liquid environment,offer several benefits for highly selective processes.However,the often tedious product separation and catalyst recycling,requiring energy and chemical ...
supported by the National Key Research and Development Program of China(2018YFA0704501).
Hydroformylation of formaldehyde to glycolaldehyde(GA),as a vital reaction in both direct and indirect process of syngas to ethylene glycol(EG),shows great advantages in the aspects of the process complexity and clean...
Recently,the project“Development and application of low-temperature and high-selectivity catalytic system for hydroformylation of low-carbon olefins”jointly undertaken by the China National Offshore Oil Company(CNOO...
Based on industrial production with an annual capacity of million tons of methanol,ammonia/urea,etc.,a platform technology is developed for direct,green,efficient,and high-value mega-size utilization of the CO2-rich n...
Novel catalytic systems for the Rh‐catalyzed hydroformylation of dicyclopentadiene have been developed using tris‐H8‐binaphthyl monophosphite as ligands containing different ester substituents at the 2’‐binaphthy...
Supported by the National Natural Science Foundation of China(Nos.21373120, 21301098, 21071086, 21271110), the National "111" Project of China's Higher Education(No.B 12015), the Applied Basic Research Programs of Science and Technology Commission Foundation ofTianjin, China(Nos.13JCQNJC02000, 12JCYBJC13100).
TiO2 nanotubes supported amorphous Co-B(Co-B/TNTs) catalyst was prepared via impregnation- chemical reduction procedure. The catalyst was characterized with transmission electron microscopy(TEM), ammonia temperatu...