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financial support from the National Natural Science Foundation of China(21922810,21908153,21908155);program of Innovative Talents of Higher Education Institutions of Shanxi;the supported by Cultivate Scientific Research Excellence Programs of Higher Education Institutions in Shanxi(CSREP)。
The removal of trace propyne(C_(3)H_(4))from propyne/propylene(C_(3)H_(4)/C_(3)H_(6))mixtures is a technical and challenging task during the production of polymer-grade propylene in view of their very similar size and...
This work was supported by the National Natural Science Foundation of China (Nos. 21703146 and 51802206);Natural Science Foundation of Jiangsu Province (No. BK20180846);We also acknowledge the financial support from the 111 Project, Joint International Research Laboratory of Carbon-Based Functional Materials and Devices, Collaborative Innovation Center of Suzhou Nano Science and Technology (NANO-CIC);the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD),SWC for Synchrotron Radiation. Yong Xu acknowledges the financial support from Guangdong University of Technology.
The selective hydrogenation of propyne to propylene has attracted great attention in chemical industry for removing trace amount of propyne for producing polymer-grade propylene. As the state-of-the-art catalyst, Pd s...
Several aromatic homopropargyl alcohols, and derivatives were prepared by one-pot reaction of 1,3-dilithiopropyne (or its equivalent) with aldehydes and ketones. The antibacterial activity, of alcohols thus prepared, ...
This work is supported by the National Natural Science Foundation of China (No.51476155, No.51622605, No.91541201), the National Key Sci- entific Instruments and Equipment Development Program of China (No.2012YQ22011305), the National Postdoctoral Program for Innovative Talents (No.BX201600100), and China Postdoctoral Science Foundation (No.2016M600312).
A numerical investigation on the co-pyrolysis of 1,3-butadiene and propyne is performed to explore the synergistic effect between fuel components on aromatic hydrocarbon formation. A detailed kinetic model of 1,3-buta...
A practical and efficient liquid-phase synthesis of 1,2,3-triazoles using poly(ethylene glycol) as support in aqueous solution was described. The title compounds, 1,2,3-triazoles 5 were obtained by a one-pot three-c...
This work was in part supported by the Hong Kong Research Grants Council(HKUST6062/98P and DAG96/97 SC11).
While WCl_6-Ph_4Sn fails to polymerize 1-phenyl-1-propyne (PP) at room temperature, highmolecular weight (M_w up to 410× 10~3) polymers are obtained in high yields (up to 80%) when thepolymerizations of PP are carrie...
An investigation into the organic permselective separation through poly [1-trimethylsilyl-1-propyne] (PTMSP) and (1-trimethylsily 1)-1-(1-penta-methyl-disily 1)-1-propyne copolymer (TMSP-PMDSP) dense membranes was mad...
The project is supported by the National Natural Science Foundation of China
Surface modification of poly [1-(trimethylsilyl)-1-propyne] (PTMSP) membranes bybromine vapor has been studied. It is shown that Br/C atomic ratio at the surfaces increased withthe time of bromination until about 60 m...
The permeability of copoly (1-trimethylsilyl-1-propyne-pentamethyldisilyl-1-propyne) membrane for twelve gases (0_2, N_2, CO_2, H_2, D_2, He, At, CH_4, C_2H_4, C_2H_6, C_3H_6 and C_3H_8) was examined. The basic laws o...