By allowing H_(2)SeO_(4),Cy_(2)NH,CyNH_(2) or Bz2NH to react respectively with SnPh_(3)Cl(in methanol),SnPh_(2)Cl_(2)(in water+methanol)and MgCl_(2)·6H_(2)O(in methanol)in specific ratios,the studied complexes are ob...
financially National Natural Science Foundation of China (Grant No. 22209134);Fundamental Research Funds for the Central Universities, Southwest Minzu University (Grant No. ZYN2023003);Sichuan Science and Technology Program (Grant No. 2024NSFSC1155);Fundamental Research Funds for the Central Universities, Southwest Jiaotong University (Grant No. 2682023CX005)。
The poor compatibility of ester electrolytes with lithium metal anode severely limits its use in high voltage lithium metal batteries(LMBs).In this work,a bidentate solvent 1,2-diethoxyethane(DEE) is introduced into e...
DFT calculations have been performed to discover the mechanism for the synthesis of dimethyl adipate(DMA)by 1,3-butadiene(BD)dicarbonylation catalyzed by a complex consisting of palladium and a bidentate diphosphine l...
supported by the Basic Science Center of Transformation Chemistry of Key Components of Air,National Natural Science Foundation of China(no.21988101);M.Z.acknowledges China Postdoctoral Science Foundation(no.2019M650294);L.Z.acknowledges the financial support from NSFC(nos.21973044 and 21703099);Natural Science Foundation of Jiangsu Province for Youth(no.BK20170964)。
Cobalt-bis(dinitrogen)complexes[LCo(N_(2))_(2)]−(3,4)with simple and commercially available bidentate phosphine ligands(L:Cy_(2)PCH_(2)CH_(2)PCy_(2))were synthesized and structurally characterized.Further N2 functiona...
G.C.thanks NSFC-91753124,NSFC-21672105,NSFC-21421062,and NSFC-21725204 for financial support of this work.
Main observation and conclusion A set of Pd-catalyzed ortho-directed C-H glycosylation reactions with glycosyl chloride donors using various N-linked bidentate auxil-iaries has been developed for synthesis of C-arygly...
supported by the National Natural Science Foundation of China(51572022 and 51872025);the National Key Research and Development Program of China(2016 YFB0701100);the National Key Research and Development H863 Program of China(18H86303ZT0032702)。
Interfacial conjugation was employed to engineering preparation of TiO2@NH2-MIL-101(Fe)heterojunction photocataysts through carboxylate bidentate linkage with TiO2 and NH2-MIL-101(Fe),which can enhance the electron tr...
supported by the Joint Research Program of National Natural Science Foundation, China;National Science Foundation, Sri Lanka (NSFC-NSF SL) (No.21861142020);the Program of China–Sri Lanka Joint Research and Demonstration Center for Water Technology and China– Sri Lanka Joint Center for Education and Research by Chinese Academy of Sciences, China;the Chinese Academy of Sciences–The World Academy of Sciences (CAS–TWAS) President’s Fellowship Program for International Ph.D.students.
It has recently been proposed that recalcitrant dissolved organic carbon(DOC) in groundwater plays a potent etiological role in the peculiar distribution of chronic kidney disease of unknown etiology(CKDu).This study ...
A series. Ce-co-oX Catalysts. prepared by co-precipitation method, CO-SCR performance.Studied. influence CO, CE ratio. activity. CO-SCR. investigated, Ce (0.3)-Co (0.7)-OXSample showed Highest NO conversion efficiency...
Financial support by Natural Science Foundation of China (NSFC) (Nos. 21325626, 21176179, U1510203);the Program for New Century Excellent Talents in University (No. NCET-13-0411);the Program of Introducing Talents of Discipline to Universities (No. B06006)
The mechanism of dimethyl carbonate(DMC) formation from CO2 and methanol is investigated using three well-shaped CeO2 catalysts, nanorod, nanocube and octahedron, which are packed with different crystal planes. In s...
financially supported by the National Basic Research Program of China(2015CB856600);the National Natural Science Foundation of China(21422206,21272206);the Fundamental Research Funds for the Central Universities(2014QNA3008);the Natural Science Foundation of Zhejiang Province(Z12B02000)
A copper-catalyzed acyloxylation of C(sp2)–H bond with sterically bulky benzoic acids was achieved.This protocol is compatible with a broad range of functional groups and could proceed in gram scale,providing an effi...