Supported by the National Natural Science Foundation of China(No.21406036), the Natural Science Foundation of Fujian Province of China(No.2014J01034), the Project of Department of Education of Fujian Province of ChinafNos.JA11044, JA10056, JB 13011) and the Program for Innovative Research Team in Science and Technology in Fuj ian Province University, China.
By the Schiff-base condensation of formacyl calix[4]crown(2) with raw chitosan, a novel calix[4]crown- grafted chitosan chelating polymer(3) was conveniently prepared in good yield. The structure of polymer 3 was ...
supported by the National Natural Science Foundation of China(21165006);the Fund of the International Cooperation Projects of Guizhou Province(20137002);the"Chun-Hui"Fund of Chinese Ministry of Education(Z2011033 and Z2012053)
A new thiacalix[4]arene phenothiazine derivative(2) based on a thiacalix[4]crown with a 1,3-alternate conformation has been synthesized and characterized. In THF-water mixture, Compound 2 exhibits a strong fluorescenc...
Supported by the National Natural Science Foundation of China(No.20402002);Natural Science Foundation of Fujian Province,China(No.2009J01019)
Refluxing calix[4]-1,3-substituted benzaldehyde derivative(4) with glycine hydrazide derivative, we obtained a novel calix[4]arene hydrazone derivative(5) via "1+2" condensation in a yield of 78%. In the reacti...
Financial support from the National Natural Science Foundation of China(No.20802049) and Program for New Century Excellent Talents in University of Tianjin City
Calix[4]-crown-5-sulfonyl cyclothiourea derivatives 6 and 7 were synthesized from calix[4]-crown-5-monosulfonylethylenediamine derivatives 4 and 5 and carbon disulfide through nucleophilic addition and subsequent cycl...
the Research Foundation of Tongji Medical College,Huazhong University of Science and Technology(No.25514107);Project Chenguang of Wuhan City(No.200750731267)for financial support.
25,27-Dipropoxy-p-tert-butylcalix[4]crown-9 cone conformer 5 was readily synthesized via an intramolecular cyclization strategy in good yields. The structures of all the new compounds involved were confirmed by NMR, E...
Financial supports from the National Natural Science Foundation of China(No.20602015)are gratefully acknowledged.
p-tert-Butylcalix[4]diazacrown-4 telomer, which contains hard and soft ion binding sites, was synthesized. It exhibited high selectivity toward cesium ions. The binding sites may complex alkali metal ions selectively.
ProjectsupportedbytheNationalNaturalScienceFoundationofChina (No .90 10 10 18)
The novel calixcrowns with two pendant groups were prepared by the alkylation of calixcrowns with 6-methoxy-2-bromoacetylnaphthalene. 1H NMR titration and picrate extraction experiments indicated that they exhibi...
A diester-calix[4]crown-4-ether bearing mono (azophenol) moiety shows a larger spectral change toward Ca2+ than other alkali and alkaline eafth cations.