supported by the National Natural Science Foundation of China (Nos.22031003,21720102004);the Shanghai Science Technology Committee (No.19DZ2270100).
Herein,we describe the synthesis of a carborane-supported octanuclear palladacycle complex,Pd_(8)(o-C_(2)B_(10)H_(10)CS_(2)CH_(3))_(4)Cl_(4)(CH_(3)CN)_(4)(complex 1),with B(3)-H activations on o-carborane ligand.The s...
support from the National Natural Science Foundation of China(Grant No.21771048);the Natural Science Foundation of Zhejiang Provinee(Grant No.LY17B010002).
The steric and electronic properties of A/-heterocyclic carbenes(NHCs)can be modified by the exocyclic substituents at the nitrogen atoms,by 1-3 atoms'replacements of the five-membered imidazolium skeleton and by the ...
This work was supported by the National Science Fund for Distinguished Young Scholars(No.21825106);the National Natural Science Foundation of China(No.21671175);the Program for Innovative Research Team(in Science and Technology)in Universities of Henan Province(No.19IRTSTHN022)and Zhengzhou University.
Engineering the surface of the metal clusters with the core structure maintained and tuning their luminescence in a wide range is still a challenge in the nanomaterial research.We modified six mono-pyridyl ligands wit...
This work was supported by grants from the National NaturalScience Foundation of China(No.21772223);the Science andTechnology Commission ofShanghai Municipality(No.18590760800);the China Postdoctoral Science Foundation(No.BX20180341 to R.C.), the Shanghai Postdoctoral Excellence Program (No. 2018027 to R. C.), the Chinese Academy of Sciences,and Hong Kong Research Grants Council (No.14305017).
of main observation and conclusion A palladium catalyzed oxidative annulation of 1-hydroxy-o-carborane with internal alkynes via regioselective B(3)—H bond activation has been developed for facile synthesis of a seri...
The structures and second-order nonlinear optical (NLO) properties of a series of chlorobenzyl-o-carboranes derivatives (1 12) containing different push-pull groups have been studied by density functional theory ...
theNationalNaturalScienceFoundationofChina (No .2 992 5 10 1);theMajorStateBasicResearchDevelopmentProgram (No .G19990 64 80 0 )
Metallocene complex Cp tt 2ZrCl 2 (Cp tt =η 5 1,3 t Bu 2 C 5 H 3 ) (1) has been prepared from the reaction of LiCp tt with ZrCl 4 in good yield. Reactio...
theNationalNaturalScienceFoundationofChina (No .2 992 5 10 1)andtheMajorStateBasicResearchDevelop mentProgramofChina (No .G19990 6 480 0 )
Reactions of [Cp2Ln(μ-Cl)]2 (Cp= η5-C5H5, Ln = Nd, Yb, Dy, Gd, Er) with an equivalent of [(THF)3LiE2C2Bi0H10Li. (THF)]2 (E= S, Se) in THF afforded the dinuclear sandwich complexes of formula [CP2LnE2C2B10H10]2[LI(TH...