O-CARBORANE

作品数:21被引量:6H指数:1
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相关领域:理学更多>>
相关作者:苗金玲聂永卞德乾更多>>
相关机构:济南大学福州大学更多>>
相关期刊:《聊城大学学报(自然科学版)》《Organic Chemistry Frontiers》《Science China Chemistry》《Chinese Journal of Structural Chemistry》更多>>
相关基金:国家自然科学基金高等学校学科创新引智计划国家重点基础研究发展计划山东省自然科学基金更多>>
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Octanuclear Palladacycles with B(3)-H Bond Activation of o-Carborane
《Chinese Journal of Chemistry》2023年第3期307-313,共7页Run-Ze Yuan Peng-Fei Cui Yue-Jian Lin Guo-Xin Jin 
supported by the National Natural Science Foundation of China (Nos.22031003,21720102004);the Shanghai Science Technology Committee (No.19DZ2270100).
Herein,we describe the synthesis of a carborane-supported octanuclear palladacycle complex,Pd_(8)(o-C_(2)B_(10)H_(10)CS_(2)CH_(3))_(4)Cl_(4)(CH_(3)CN)_(4)(complex 1),with B(3)-H activations on o-carborane ligand.The s...
关键词:CARBORANE Palladacycle Regioselective B-H activation Polynuclear complex Dithioester chemistry 
N-Heterocyclic Carbenes with a Nido-C_(2)B_(9) Carborane Backbone被引量:1
《Chinese Journal of Chemistry》2021年第9期2410-2416,共7页Zhongzheng Cui Beining Wang Junxia Li Ronglin Pang Yanrui Kang Xu-Qiong Xiao 
support from the National Natural Science Foundation of China(Grant No.21771048);the Natural Science Foundation of Zhejiang Provinee(Grant No.LY17B010002).
The steric and electronic properties of A/-heterocyclic carbenes(NHCs)can be modified by the exocyclic substituents at the nitrogen atoms,by 1-3 atoms'replacements of the five-membered imidazolium skeleton and by the ...
关键词:CARBORANES nido-Carborane anion Carbene ligands Density functional calculations Gold 
Luminescence Regulation of Silver-Thiolate Clusters Protected by 1,2-Dithiolate-o-carborane
《Chinese Journal of Chemistry》2021年第1期81-86,共6页Li-Juan Liu Thomas C.W.Mak Shuang-Quan Zang 
This work was supported by the National Science Fund for Distinguished Young Scholars(No.21825106);the National Natural Science Foundation of China(No.21671175);the Program for Innovative Research Team(in Science and Technology)in Universities of Henan Province(No.19IRTSTHN022)and Zhengzhou University.
Engineering the surface of the metal clusters with the core structure maintained and tuning their luminescence in a wide range is still a challenge in the nanomaterial research.We modified six mono-pyridyl ligands wit...
关键词:Silver clusters Surface modification 1 2-Dithiolate-o-carborane LUMINESCENCE 
Palladium-Catalyzed Oxidative Annulation of 1-Hydroxy-o-Carborane withInternal Alkynes:Facile Synthesis of Carborane-Fused Oxaborolest
《Chinese Journal of Chemistry》2020年第12期1575-1578,共4页Ruofei Cheng Zaozao Qiu Zuowei Xie 
This work was supported by grants from the National NaturalScience Foundation of China(No.21772223);the Science andTechnology Commission ofShanghai Municipality(No.18590760800);the China Postdoctoral Science Foundation(No.BX20180341 to R.C.), the Shanghai Postdoctoral Excellence Program (No. 2018027 to R. C.), the Chinese Academy of Sciences,and Hong Kong Research Grants Council (No.14305017).
of main observation and conclusion A palladium catalyzed oxidative annulation of 1-hydroxy-o-carborane with internal alkynes via regioselective B(3)—H bond activation has been developed for facile synthesis of a seri...
关键词:materials. OXIDATIVE FUSED 
Density Functional Theory Investigation on the Second-Order Nonlinear Optical Properties of Chlorobenzyl-o-Carborane Derivatives被引量:1
《Chinese Journal of Chemistry》2012年第10期2349-2355,共7页刘岩 杨国春 孙世玲 苏忠民 
The structures and second-order nonlinear optical (NLO) properties of a series of chlorobenzyl-o-carboranes derivatives (1 12) containing different push-pull groups have been studied by density functional theory ...
关键词:chlorobenzyl-o-carborane tetrathiafulvalene (TTF) FERROCENE nonlinear optical property densityfunctional theory (DFT) 
Syntheses and Characterization of Half-Sandwich Zirconium Complexes with Dichalcogenolate o-Carborane Ligands
《Chinese Journal of Chemistry》2003年第4期446-451,共6页于晓燕 金国新 胡宁海 
theNationalNaturalScienceFoundationofChina (No .2 992 5 10 1);theMajorStateBasicResearchDevelopmentProgram (No .G19990 64 80 0 )
Metallocene complex Cp tt 2ZrCl 2 (Cp tt =η 5 1,3 t Bu 2 C 5 H 3 ) (1) has been prepared from the reaction of LiCp tt with ZrCl 4 in good yield. Reactio...
关键词:half  sandwich zirconium complex METALLOCENE dichal^co^genolate   o    carborane crystal structure 
Synthesis and Characterization of Novel Lanthanocene Complexes with Dichalcogenolate o-Carboranyl Ligands
《Chinese Journal of Chemistry》2002年第11期1256-1262,1128,共7页于晓燕 金国新 翁林红 
theNationalNaturalScienceFoundationofChina (No .2 992 5 10 1)andtheMajorStateBasicResearchDevelop mentProgramofChina (No .G19990 6 480 0 )
Reactions of [Cp2Ln(μ-Cl)]2 (Cp= η5-C5H5, Ln = Nd, Yb, Dy, Gd, Er) with an equivalent of [(THF)3LiE2C2Bi0H10Li. (THF)]2 (E= S, Se) in THF afforded the dinuclear sandwich complexes of formula [CP2LnE2C2B10H10]2[LI(TH...
关键词:lanthanocene complex crystal structure dichalcogenolate o-carborane metathesis reaction 
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