grateful for the financial support from the National Natural Science Foundation of China(Nos.22101135 and 21502096);the Natural Science Foundation of Jiangsu Province(No.BK20150652);the Fundamental Research Funds for the Central Universities(Nos.KYQN2022058,KJQN201629 and XUEKEN2022032);“333 High-Level Talent Project”of Jiangsu Province.
A dehydroxylative ring-opening Giese reaction of cyclobutanone oximes enabled by photoredox/Ti dual catalysis has been reported in this work.This protocol avoids the prefunctionalization of oximes and the use of stoic...
National Natural Science Foundation of China (Nos.21421002,21991211);the Strategic Priority Research Program of the Chinese Academy of Sciences (No.XDB20000000)。
An iron-catalyzed coupling reaction of difluoroenol silyl ethers and cyclobutanone oxime esters is described. This protocol provides a convenient access to various previously unknown and potentially useful gem-difluor...
We are grateful to the National Natural Science Foundation of China(No.NSFC-21871046).
Main observation and conclusion A copper-catalyzed radical cyclization of cyclobutanone oxime esters and vinyl azide is described.This method provides facile access to cyanoalkyl-substituted phenanthridines and quinox...
We thank the Shanghai Municipal Education Commission (No. 201701070002E00030), the Science and Technology Commission of Shanghai Municipality (No. 15JC1402200), and the National Natural Science Foundation of China (Nos. 21472123, 21572131, 21620102003) for financial support.
Chiral β-Iactams and cyclobutanones are present in numerous natural and pharmaceutical products. The stereoselective construction of chiral four-membered cyclic compounds is an ongoing challenge for the chemical comm...
financial support from National Natural Science Foundation of China(NSFC,Nos.21302177,21672049 and 21672030)
An unusual formal oxy transposition of vinylogous β-silyloxy-cyclobutanone 1(a 1,5-difunctionalized substrate) under mild acidic conditions(aqueous HF in CH3CN at 0℃) to the decalinic y-lactone 2 was described.A...