National Key Research and Development Program of China (2018YFA0902000);the key project at central government level:the ability establishment of sustainable use for valuable Chinese medicine resources(2060302,China);the open foundation of Shaanxi University of Chinese Medicine state key laboratory of R&D of Characteristic Qin Medicine Resources (SUCM-QM202202,China);the fund of Traditional Chinese Medicine Institute of Anhui Dabie Mountain (TCMADM-2023-18,China);National Natural Science Foundation of China (32070364);Hainan Provincial Natural Science Foundation of China(2019RC309)
Pyran-and furanocoumarins are key representatives of tetrahydropyrans and tetrahydrofurans,respectively,exhibiting diverse physiological and medical bioactivities.However,the biosynthetic mechanisms for their core str...
supported by the National Basic Research Program of China (973 Program, 2015CB856600);the National Natural Science Founda-tion of China (21472004, 21332002)~~
The Cu(I)‐catalyzed cascade coupling/cyclization reaction of N‐tosylhydrazones with 3‐butyn‐1‐ol has been explored. This new strategy represents a simple platform for the synthesis of tetrahydrofurans in moderate...
supported by the National Natural Science Foundation of China(No.20472068);Specialized Research Fund for the Doctoral Program of Higher Education(No.200807360001);Key Laboratory of Eco-Environment -Related Polymer Materials of Ministry of Education(Northwest Normal University)
2,5-Disubstituted tetrahydrofurans were obtained from lactones and organozinc halides in moderate to high yield in the presence of Lewis acids.
1 Introduction A variety of Pd(Ⅱ)-catalyzed oxidative transformations ot allcenes with oxygen nucleophiles are catalyzed by PdX_(2)(X=OAc,Cl,etc)with CuX_(n)(n=1 or 2)under O_(2).In the so-called Wacker catalyst of s...
Project supported by the Chinese Academy of Sciences and the National Natural Science Foundation of China (No. 20202011).
A one-pot procedure for the efficient synthesis of a small library of t-RNA inhibitor analogues was developed. Thus,Rh2(OAc)4 catalyzed three-component 1,3-dipolar cycloaddition reactions of carbonyl ylides derived fr...