supported by the National Natural Nature Science Foundation of China(U1707603,21625101,21521005,21808011,U1507102);the National Key Research and Development Program of China(2017YFB0307303);Beijing Natural Science Foundation(2182047,2202039);the Fundamental Research Funds for the Central Universities(XK1802-6,XK1803-05,XK1902,12060093063)。
Acid catalysis,one of the most important industrial processes,suffers from the toxicity,corrosion and recyclability problems of conventional homogeneous acid catalysts.Thus,the development of green heterogeneous acid ...
the National Key R&D Program of China(2016YFA0202902);the National Natural Science Foundation of China(21572036,21871059,21861132002);the Department of Chemistry at Fudan University。
The amide C-N cleavage has drawn a broad interest in synthetic chemistry,biological process and pharmaceutical industry.Transition-metal,luxury ligand or excess base were always vital to the transformation.Here,we dev...
supported by the National Natural Science Foundation of China(21931010);the National Key Research and Development Program of China(2017YFA0207302);the Program for Changjiang Scholars and Innovative Research Team in University of the Ministry of Education,China.
N-Acylpyrrole-type amides are a class of versatile building blocks in asymmetric synthesis.We report that by employing Ni(COD)2/2,2′-bipyridine(5 mol%)catalytic system,the direct,catalytic alcoholysis of N-acylpyrrol...
the National Natural Science Foundation of China (20925310 & 20873043);the Science and Technology Commission of Shanghai Municipality (09XD1401500 & 08JC1408700);973 Project (2006CB202508);863 Program (2007AA03Z342 & 2008AA030801);the Shanghai Leading Academic Discipline Project (B409);the Cheung Kong Scholars Program
FDU-15-SO3H,a solid acid material prepared from the sulfonation of FDU-15 mesoporous polymer,has been demonstrated to serve as an efficient catalyst in the esterification of palmitic acid with methanol as well as in t...
Goodyeroside A 1,a natural product with hepatoprotective activity,was efficiently synthesized in a total yield of 47% in five steps starting from (S)-malic acid. The spectral data of the target compound 1 is identical...
the Innovation Fund of Medium or Small Science and Technology Enterprise (Grant No. 05Z074)
Non-conjugated carboxylic acids are selectively esterified in good yields in the presence of conjugated or aromatic carboxylic acids by stirring over active carbon supported methanesulfonic acid in di-chloromethane at...
Supported by the National High Technology Research and Development Program of China 863 Plan (Grant No. 2003AA321010); the Innovation Research Fund of Graduate University, Chinese Academy of Sciences (2006)
A complete study on the catalytic activity of stannous oxalate for poly(trimethylene terephthalate) (PTT) synthesis via esterification method is carried out by comparison to the well known catalysts (tetrabutyl titana...
This work was supported by the National Natural Science Foundation of China(Grant Nos.20306011&20476046);the Ph.D.Program Foundation of Chinese University(No.20040291002).
A series of catalysts of 12-Phosphotungstic acid(PW)and its cesium salts immobilizedon dealuminated ultra-stable Y zeolite(DUSY)were prepared.Their specific surface area and acidstrength were characterized,and their c...
Project supported by the National Natural Science Foundation of China
Mono-substituted Keggin ions PW11O39Cr(H2O)4 , PW11TiO403 and PW11VO404 were intercalated between the layers of the clay of anions of Zn-Al type using the ion exchange method to obtain a new type of pillared layered m...
Primary, secondary, and tertiary alcohols and polyols were esterified with carboxylic acidin the presence of HY zeolite. Yield of ester of primary alcohol is over 80 per cent, andthat of sec- and tert-alcohols, 40-50 ...