support from the National Natural Science Foundation of China(Nos.21971224,22071222,22171249);111 Project(No.D20003);the Key Research Projects of Universities in Henan Province(No.21A150053);the Natural Science Foundation of Henan Province(No.202300410375);China Postdoctoral Science Foundation(No.2021M692906);Henan Postdoctoral Foundation(No.202003014).
An SN2-based photochemical strategy using dithiocarbamate anion as catalyst was developed for the activation of benzyl halides,which are extremely challenging to be applied as radical precursors in visible light photo...
The National Natural Science Foundation of China(Nos.21901203,22171225,21925108);the Education Department of Shaanxi Province(No.20JK0934)are acknowledged for financial support.
The first intermolecular electrophilic dearomatization of halonaphthols with benzyl/allyl bromides is described. Halonaphthols are used as carbon-nucleophiles in dearomatization to form three-dimensional cyclic enones...
the University of Science and Technology of China and National Natural Science Foundation of China(Grant Nos.21925111,21790333,21702197 and 21672199)for generous and continuous financial support.
Transition-metal mediated activation of inert chemical bonds is an ongoing topic in homogeneous catalysis.In view of the abundance and accessibility of alkylarenes and benzylamines,the use of them as benzyl source in ...
Supported by the Science and Technology Program of Guangzhou,China(201804010172);National Natural Science Foundation of China(21808040,21706031,21276052,21776049);Science and Technology Planning Project of Guangdong Province,China(2012A090300006)
The modification of pillared MFI zeolites was performed by nitridation of silica pillared MFI zeolite nanosheets under NH3 atmosphere with different time. The resultant zeolites were characterized by a complementary c...
the Razi University Research Council for support of this work
K5CoW12O40 was used as a highly effective catalyst for the benzylation of 1,3-dicarbonyl compounds, β-Keto enol ethers were obtained when cyclic 1,3-dicarbonyl compounds used in this conditions instead of linear ones...
supported by the National Natural Science Foundation of China (20832002 and 21072223);the Fundamental Research Funds for the Central Universities;the Research Funds of Renmin University of China (10XNL017)
An iron-catalyzed oxidative C-C bond formation by the reactions of simple toluene derivatives with 1,3-dicarbonyl compounds is developed.A benzylic radical addition to a benzoylmethanato iron species is proposed for t...
An efficient BF3.OEt2-promoted benzylation of arenes and heteroarenes with various benzyl ether derivatives has been developed. This method provided alternative access to valuable diarylmethane in good yields under mi...
A practical method to stereospecifically synthesize trans-stilbenes was developed via the one-pot benzylation-dehydration reaction of aromatic aldehydes with benzyltrimethylsilane (BTMS), which was driven by tetrabu...
A highly efficient benzylation of arenes and heteroarenes catalyzed by HfCl4/HfO2 has been developed. Broad scope of benzylation reagents have been used in this process with high yields under mild condition. Additiona...
Selective formation of pharmaceutical intermediates like diphenylmethane, dimethyldiphenylmethane, benzyl toluene and benzoic acid by liquid phase, toluene benzylation with benzyl chloride as a benzylating agent, was ...