POLYFLUOROARENES

作品数：6被引量：2H指数：1
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相关领域：理学更多>>
相关作者：张建熊扬曹松吴晶晶尤万里更多>>
相关机构：中国科学技术大学华东理工大学更多>>
相关期刊：《Chinese Journal of Catalysis》《Chinese Journal of Chemistry》《Science China Chemistry》《Chinese Journal of Chemical Physics》更多>>
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Dual ligands relay-promoted transformation of unstrained ketones to polyfluoroarenes and nitriles被引量：1
《Science China Chemistry》2023年第7期2037-2045,共9页Zhen-Yu Wang Huiying Xu Xu Zhang Xing Wang Hui Xu Hui Gao Hui-Xiong Dai 
supported by the Shanghai Institute of Materia Medica,the Chinese Academy of Sciencese;National Natural Science Foundation of China(21772211,21920102003);the Institutes for Drug Discovery and Development,Chinese Academy of Sciences(CASIMM0120163006);the Science and Technology Commission of Shanghai Municipality(17JC1405000,18431907100);the Program of Shanghai Academic Research Leader(19XD1424600);the National Science&Technology Major Project“Key New Drug Creation and Manufacturing Program”,China(2018ZX09711002-006);the China Postdoctoral Science Foundation(2019M662854)
C-C bond activation has emerged as a powerful tool for the construction of complex molecules.Herein,we report a dual ligands relay-promoted transformation of unstrained aryl,alkenyl and alkynyl ketones to the correspo...
关键词：C-C bond activation dual ligands relay unstrained ketones modification of drugs and natural products DFT study 
Nickel-catalyzed reductive cross-coupling of polyfluoroarenes with alkyl electrophiles by site-selective C–F bond activation被引量：1
《Chinese Chemical Letters》2022年第9期4287-4292,共6页Longlong Xi Liting Du Zhuangzhi Shi 
the National Natural Science Foundation of China (Nos. 22025104, 21972064 and 21901111);the National Natural Science Foundation of Jiangsu Province (No. BK20170632);the Excellent Youth Foundation of Jiangsu Scientific Committee (No. BK20180007);the “Innovation & Entrepreneurship Talents Plan” of Jiangsu Province;the Fundamental Research Funds for the Central Universities for their financial support
A nickel-catalyzed reductive cross-coupling reactions between polyfluoroarenes and alkyl electrophiles is reported to access substituted fluoroarenes through chelation-assisted C–F activation.Diverse primary and seco...
关键词：POLYFLUOROARENES Nickel ALKYLATION CROSS-COUPLING C-F activation 
Visible-light photoredox-catalyzed selective carboxylation of C(sp~2)-F bonds in polyfluoroarenes with CO2
《Chinese Journal of Catalysis》2022年第9期2388-2394,共7页Zhi‐Yu Bo Si‐Shun Yan Tian‐Yu Gao Lei Song Chuan‐Kun Ran Yi He Wei Zhang Guang‐Mei Cao Da‐Gang Yu 
国家自然科学基金(22101191,21822108);中国博士后面上基金(2021M692261);四川省青年科技创新研究团队项目(20CXTD0112);中央引导地方科技发展资金项目(自由探索类基础研究项目,2021ZYD0063);中央高校基本科研业务费专项资金资助.
Visible light‐driven carboxylation with CO_(2) have emerged as a sustainable and powerful way to transfer waste to treasure.However,it is still challenging for aryl fluorides due to the low reactivities of both C(sp2...
关键词：Carbon dioxide Visible-light photoredox catalysis CARBOXYLATION C-F functionalization POLYFLUOROARENES 
Pd-catalyzed cross-coupling of polyfluoroarenes with cyclic vinyl triflates
《Science China Chemistry》2014年第2期276-281,共6页YU YanBo WANG Zhen ZHANG XinGang 
financially supported by the National Basic Research Program of China (973 Program,2012CB821600);the National Natural Science Foundation of China (21172242); thesupport of Shanghai institute of Organic Chemistry，the Chinese Academy of Sciences．
An effective method for Pd-catalyzed cross-coupling between polyfluoroarenes and cyclic vinyl triflates has been developed.This protocol provides a useful and facile access to polyfluoroarylated cyclic alkenes that ar...
关键词：C-H bond functionalization cyclic vinyl triflates PALLADIUM polyfluoroarencs 
Mechanistic Study of Palladium-Catalyzed Oxidative C-H/C-H Coupling of Polyfluoroarenes with Simple Arenes
《Chinese Journal of Chemical Physics》2013年第4期415-423,J0001,共10页唐诗雅 于海珠 尤万里 郭庆祥 
Pd-catalyzed oxidative C-H/C-H coupling reaction is an emerging type of C-H acti- vation reaction, which attracts great interests because both reaction partners do not re- quire pre-functionalization. In the present s...
关键词：Pd catalysis Oxidative coupling C-H activation Mechanism Pentafluo-robenzene 
Nickel-Catalyzed ortho-Selective Hydrodefluorination of N-Containing Heterocycle-Polyfluoroarenes
《Chinese Journal of Chemistry》2013年第7期873-877,共5页Yi He Zhao Chen Chun-Yang He Xingang Zhang 
An effective and facile method for preparation of partially fluorinated aromatics via Nickel catalyzed, chelation-assisted ortho selective hydrodefluorination of polyfluoroames with triethylsilane has been developed, ...
关键词：catalytic C--F activation HYDRODEFLUORINATION nickel POLYFLUOROARENES triethylsilane 
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