HYDROPHOSPHONYLATION

作品数:5被引量:1H指数:1
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相关领域:理学更多>>
相关机构:安徽师范大学更多>>
相关期刊:《Science China(Physics,Mechanics & Astronomy)》《Science China Chemistry》《Science Bulletin》《Chinese Journal of Chemistry》更多>>
相关基金:国家自然科学基金更多>>
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Syntheses of bimetallic lanthanide bis(amido) complexes stabilized by bridged bis(guanidinate) ligands and their catalytic activity toward the hydrophosphonylation reaction of aldehydes and ketones
《Science China Chemistry》2015年第9期1451-1460,共10页Kun Nie Chengwei Liu Yong Zhang Yingming Yao 
supported by the National Natural Science Foundation of China(21132002,21372172,21402138);the Major Research Project of the Natural Science Foundation of the Jiangsu Higher Education Institutions(14KJA150007);the Qing Lan Project
A series of bimetallic lanthanide bis(amido) complexes stabilized by bridged bis(guanidinate) ligands {[(Me3Si)2N]2Ln[(RN)2-CN(CH2)2]}2 [R=iPr, Ln=Sm(1), Yb(2), Y(3); R=cyclohexyl(Cy), Ln=Sm(4), and Yb(5)] were synthe...
关键词:bimetallic lanthanide complex bridged bis(guanidinate) ligand hydrophosphonylation reaction aldehyde ketone 
Asymmetric Pudovik Reaction of Chiral Fluoroalkyl α,β-Unsaturated Ketimines and Diphenyl Phosphite
《Chinese Journal of Chemistry》2014年第10期1003-1006,共4页Peng Li Min Jiang Jin-Tao Liu 
Financial support from the National Natural Science Foundation of China(No.21172243)is gratefully acknowledged.
The asymmetric Pudovik reaction of chiral fluoroalkyl α,β-unsaturated ketimines derivated from(R)-tert-butanesulfinamide and diphenyl phosphite was achieved in the presence of Rb2CO3 at room temperature.A series of ...
关键词:diphenyl phosphite HYDROPHOSPHONYLATION N-tert-butanesulfinyl ketimine diastereoselectivity Pudovik reaction 
Rare-earth metal amido complexes supported by bridged bis(β-diketiminato) ligand as efficient catalysts for hydrophosphonylation of aldehydes and ketones被引量:1
《Science China(Physics,Mechanics & Astronomy)》2013年第3期329-336,共8页
A series of rare-earth metal amides supported by a cyclohexyl-linked bis(β-diketiminato) ligand were synthesized, and theft catalytic activities for hydrophosphonylation of aldehydes and ketones were developed. Rea...
关键词:Rare-earth metal HYDROPHOSPHONYLATION ALDEHYDE KETONE 
Hydrophosphonylation of Aldimines under Catalysts-Free Conditions
《Chinese Journal of Chemistry》2012年第7期1658-1662,共5页蔡志华 范业成 杜广芬 何林 
Trimethylsilyl phosphite reacted with aldimines efficiently under catalysts-free conditions, giving a-aminophosphonates in good to excellent yields. Furthermore, the reaction can be scaled-up easily and the high yield...
关键词:trimethylsilyl phosphite ALDIMINES a-aminophosphonates catalysts-flee 
Asymmetric synthesis of α-aminophosphonates by means of direct organocatalytic three-component hydrophosphonylation
《Chinese Science Bulletin》2010年第17期1729-1731,共3页WANG Lian CUI ShuMin MENG Wei ZHANG GuangWu NIE Jing MA JunAn 
supported by the National Natural Science Foundation of China (20772091);Tianjin Municipal Science and Technology Commis-sion (07JCZDJC04700)
The direct asymmetric three-component reaction of an aromatic (or cinnamic) aldehyde, an amine and a phosphite was investigated by employing chiral BrΦnsted acid. In general, modest to good enantioselectivities (31%...
关键词:不对称合成 Α-氨基膦酸酯 三组分 有机催化 对映选择性 亚磷酸酯 手性  
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