supported by the National Natural Science Foundation of China(21132002,21372172,21402138);the Major Research Project of the Natural Science Foundation of the Jiangsu Higher Education Institutions(14KJA150007);the Qing Lan Project
A series of bimetallic lanthanide bis(amido) complexes stabilized by bridged bis(guanidinate) ligands {[(Me3Si)2N]2Ln[(RN)2-CN(CH2)2]}2 [R=iPr, Ln=Sm(1), Yb(2), Y(3); R=cyclohexyl(Cy), Ln=Sm(4), and Yb(5)] were synthe...
Financial support from the National Natural Science Foundation of China(No.21172243)is gratefully acknowledged.
The asymmetric Pudovik reaction of chiral fluoroalkyl α,β-unsaturated ketimines derivated from(R)-tert-butanesulfinamide and diphenyl phosphite was achieved in the presence of Rb2CO3 at room temperature.A series of ...
A series of rare-earth metal amides supported by a cyclohexyl-linked bis(β-diketiminato) ligand were synthesized, and theft catalytic activities for hydrophosphonylation of aldehydes and ketones were developed. Rea...
Trimethylsilyl phosphite reacted with aldimines efficiently under catalysts-free conditions, giving a-aminophosphonates in good to excellent yields. Furthermore, the reaction can be scaled-up easily and the high yield...
supported by the National Natural Science Foundation of China (20772091);Tianjin Municipal Science and Technology Commis-sion (07JCZDJC04700)
The direct asymmetric three-component reaction of an aromatic (or cinnamic) aldehyde, an amine and a phosphite was investigated by employing chiral BrΦnsted acid. In general, modest to good enantioselectivities (31%...