financial support from the National Natural Science Foundation of China(No.81602977);the CAMS Innovation Fund for Medical Sciences(Nos.2019-RC-HL-010,2017-I2M-1013);the Science and Technology Development Project of Jilin Province of China(No.20190304050YY);China Association of Chinese Medicine(No.2017QNRC001)。
A Lewis base catalyzed ring expansion of isatin with 2,2,2-trifluorodiazoethane(CF3 CHN2)is developed.It is characterized that the merge of tetramethylethylenediamine and CF3 CHN2 generates reactive triazene intermedi...
supported by the National Natural Science Foundation of China(No.21302081);the Scientific Fund of Sichuan Province,China(No.2014JQ0052)
A highly efficient coupling reaction of N-heterocyclic carbene precursors with sulfonyl azides has been developed, affording a variety of pyrido[1,2-c][1,2,4]triazole-based π-conjugated triazenes. The present reactio...
Natural Science Foundation of Fujian Province (No.D0410027)
A new chromogenic reagent, 1 -(5 - nitro- 3 - benzopsendothiazde)- 3 -(4 - phenylazophenyl) - triazene (NBPTPAPT) has been synthesized and used as a sensitive reagent for the spectrophotometric determination of ...
The title compound, 1 (4 chlorophenyl) 3 (2 nitrophenyl) 1 triazene (C 12 \|H 9ClN 4O 2, M r =276.68) crystallized in the orthorhombic system,space group Pbca (#15), with a=7.040(1), b=13.520(2), c=26.253(3), V=2498...
This paper introduces the synthesis of a new color reagent 1-(6-nitro-2-benzothiazolyl)3-(4-nitrophenyl)-triazene (NBTNPT) and the color reaction of NBTNPT with Cd (II) has been studied. In the presence of Triton X-10...
A new triazene reagent 1-(6-ethoxyl-2-benzothiazolyl)-3-(4-nitrophenyl)-triazene (EtOBThTPT) has been synthesized. The colour reaction of EtOBTNPT with Hg(II) has been studied. At pH = 10.1-10.7, in the presence of Tr...
A uew diazoamino reagent 1-(4-antipyrinyl)-3-(3-Chlorophenyl)-triarene(APCPT)was synthesized. The colour reaction of APCPT with Hg(II) was studied. At pH=10,5~12.2, in the presence of Tween-80,APCPT reacts with Hg(II)...
Abstract: A new triazene reagent 1-(2-benzothiazolyl)-3-(4-phenylazoghecyl )-triazece (BTPAPT) has been synthesized.The clour reaction of STPAPT with Cd (Ⅱ) has been studied. At pH=9~11,in the presence of Triton X-1...
A new reagent,1(4 antipyriny1) 3(2,4-dinitropheny1)triazene(APDNBT), was synthesized in this lab and its analytical properties and its colour reaction with cadmium were studied.