financial support from the National Natural Science Foundation of China(No.22171249);the Science&Technology Innovation Talents in Universities of Henan Province(No.23HASTIT003)。
The development of innovative and sustainable catalytic strategies for organic synthesis is a pivotal aspect of advancing material science and chemical engineering.This research presents a new catalytic method for the...
supported by grants from the Provincial Natural Science Foundation of Hunan(No.2023JJ60335)。
The first example of Nd@C_(3)N_(4)-photoredox/chlorine dual catalyzed alkylation with unactivated alkanes as the alkyl sources has been developed,which allows for the synthesis of various 4-alkylated cyclic sulfonyl k...
supported by the National Natural Science Foundation of China(22078251);Hubei Province Key Research and Development Program(2023DJC167);the research project of Hubei Provincial Department of Education(D20191504).
The development of efficient systems for the catalytic oxidation of 2-nitro-4-methylsulfonyltoluene(NMST)to 2-nitro-4-methylsulfonyl benzoic acid(NMSBA)with atmospheric air or molecular oxygen in alkaline medium prese...
the financial support from the National Natural Science Foundation of China(22331004)。
Over the past few decades,N-sulfonyl hydrazones have been recognized as alternative precursors for hazardous diazo compounds in organic synthesis,allowing for diverse innovative and original chemical transformations t...
the National Natural Science Foundation of China(No.21901199);Xi’an Jiaotong University(No.7121192002);the Fundamental Research Funds of the Central Universities(No.xtr072022003)for financial support.
Non-covalent interactions are of significance in supramolecular chemistry and biochemistry,while synthetic procedures driven by these weak interactions remain challenging and rare.Inspired by the lone pair-π interact...
the National Natural Science Foundation of China(Nos.22271235,22071198);the“Pioneer”and“Leading Goose”R&D Program of Zhejiang(No.2022SDXHDX0006);the Leading Innovative and Entrepreneur Team Introduction Program of Zhejiang(No.2020R01004)for research support。
Mannich-type reactions are a widely used method for the synthesis of amines due to the readily availability of nucleophiles and electrophiles.However,the inclusion of alkylarenes instead of active carbon pronucleophil...
Financial support from the National Key R&D Program of China(grant no.2019YFA09006600);the National Natural Science Foundation of China(grant nos.21977048 and 92053111);the Natural Science Foundation of Jiangsu Province(grant no.BK20202004);the Beijing National Laboratory for Molecular Sciences(grant no.BNLMS20200);the Jiangsu Specially-Appointed Professor Plan,and the Program for Innovative Talents and Entrepreneur in Jiangsu is gratefully acknowledged.Q.Z.is the Connie and Bob Lurie Fellow of the Damon Runyon Cancer Research Foundation(DRG-2434-21).
Cysteine(Cys)-specific bioconjugation has widespread applications in the synthesis of protein conjugates,particularly for the functionalization of antibodies.Here,we report the discovery of transstyryl sulfonyl fluori...
financial support from the University of South China。
A simple,practical and eco-friendly visible light-induced alkylation of N-sulfonyl ketamine under metal-,additive-,external photocatalyst-free conditions was developed.This photocatalytic method utilized low cost and ...
supported by the National Natural Science Foundation of China(21801007);Qingchuang Technology Support Program of University in Shandong Province(2021KJ066);funding from the STU Scientific Research Foundation for Talents(NTF20022)。
An efficient photochemical radical sulfonyl cyclization of designed dienes to medium-sized benzo[b]azocines and benzo[b]azonines was developed.This chemoselective method provides new highly functionalized eight-and ni...
The authors are grateful to NSFC(Nos.21971066 and 21772042)for financial support.Special thanks to prof;Junliang Zhang(Fudan University)for his kind suggestion on this[3 t 2]cycloaddition reaction.
A highly efficient and mild method for[3 t 2]cycloaddition ofβ-sulfonyl-α,β-unsaturated ketones with terminal allenoates was well-explored and developed.The reactions were successfully performed by applying multifu...