This work was supported by the Guangdong-Hong Kong-Macao Joint Laboratory of Optoelectronic and Magnetic Functional Materials(No.2019B121205002).
Alkynylplatinum(II)bzimpy complexes of trimethylammoniumbenzylethynyl ligand have been synthesized and characterized.Complexes with long alkyl chains have been found to exhibit interesting self-assembly properties in ...
This work was supported by the National Natural Science Foundation of China(No.21762011);the Guizhou Science and Technology Planning Project,China(Guizhou Science and Technology Cooperation Platform Talent)(No.20175788);the Guizhou Province Graduate Education Innovation Project,China[No.YJSCXJH(2020)188].
The host-guest interactions between cyclopentanocucurbit-[6]uril(CyP_(6)Q[6])as host and six alkyl imidazolium hydrochloride as guests(g1,g2,g3,g4,g5,and g6)have been studied by various techniques,such as^(1)H NMR spe...
Supported by the National High Technology Research and Development Program of China(No.2013AA102104) and the National Natural Science Foundation of China(Nos.20772046, 21072075).
A novel thermostable β-glucosidase(Tnap0602) with β-galactosidase activity was cloned from Thermotoga naphthophila RUK-10 and overexpressed in Escherichia coli BL21(DE3) with the aid of pET28b(+) vector. The ...
JandaJel resin-supported triphenylphosphine(JJ-TPP),was used as an effective organocatalyst for the [3+2] annulation reaction of alkyl 2-butynoates with electron-deficient alkenes to afford the corresponding cyclop...
Supported by the National Natural Science Foundation of China(No.30360119)
A series of 2-[1-(2-formylamido-3-phenylpropionyloxy)alkyl]-1,4-dihydroxy-9,10-anthraquinone(2FPADHAQ) derivatives was designed and synthesized.Their antitumor activities were tested against L1210 tumor cells and ...
Supported by the National Natural Science Foundation of China(No.20062001);the Natural Science Foundation of Guangxi Zhuang Autonomous Region,China(Nos.0991009 and 0447036)
Although there was a strong steric effect,isopentenyl and geranyl moieties were successfully introduced into C3 position in flavone skeleton so as to synthesize the 3-isopentenyl flavone and 3-geranyl flavone under tw...
Supported by the National Science and Technology Pillar Program of China(No.2011BAE06B01)
A series of rotenone O-alkyl oxime derivatives was designed and synthesized. Their structures were confirmed by elemental analyses, Fourier transform infrared(FTIR) and 1H NMR spectral studies, and the typical cryst...
Supported by the National Natural Science Foundation of China(No.21076065);the Natural Science Foundation of Heilongjiang Province of China(No.ZD200820-02);the Science&Technology Research Foundation of Education Bureau of Heilongjiang Province,China(No.11531266)
A highly selective synthesis of 2,6-dimethylnaphthanlene(2,6-DMN) by transalkylation between 2-methylnaphthanlene(2-MN) and 1,2,4,5-tetramethylbenzene(TeMB) was performed with 1-alkyl-3-methylimidazo- lium alumi...
Supported by the National Natural Science Foundation of China(Nos20731002, 10876002);the Specialized Research Fund for the Doctoral Program of Higher Education of China(No200800070015);the Program of Cooperation of the Beijing Education Commission, China(No20091739006);the Program of Cooperation of the Beijing Technology Commission, China(No Z09010300820902);the Program for New Century Excellent Talents in University of China
The polyoxometalate-imidazole ionic liquids(POM-ILs) with low melting points at 94.5 and 95.5 ℃, [Cn mim]a[MosO26](Cn mim=1-alkyl-3-methylimidazolium, n=12,14), have been successfully synthesized and characterize...
Supported by State Key Laboratory of Inorganic Synthesis and Preparative Chemistry of Jilin University;State Key Laboratory of Physical Chemistry of Solid Surfaces of Xiamen University
With alkyl-polyamine triethylene-tetramine as the structure-directing agent, aluminosilicate zeolite ZSM-5(MFI) crystals were synthesized and characterized by XRD, SEM, FTIR, and TG-DTA. The results indicate that th...