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CATALYSIS: 作品数：1542被引量：2818H指数：17; 导出分析报告; 相关领域：理学更多>>; 相关作者：吴骊珠孟庆元佟振合张强刘娜更多>>; 相关机构：中国科学院清华大学华东理工大学中国科学院大学更多>>; 相关期刊：更多>>; 相关基金：国家自然科学基金国家重点基础研究发展计划中国博士后科学基金北京市自然科学基金更多>>

Author Spotlight: 《CCS Chemistry》2024年第12期2850-2854,共5页; Christopher Jones Prof.Jones received his B.S.E.from the University of Michigan,USA,in 1995,followed by his M.S.(1997)and Ph.D.(1999)in Chemical Engineering from the California Institute of Technology(CalTech),USA,wit...; 关键词：CATALYSIS DILUTE AMBIENT

Pd/Zn Dual Catalysis for Site-,Enantio-,and Diastereo-Divergent 2-(Alkoxycarbonyl)allylation ofα-Hydroxyketones with Morita–Baylis–Hillman Adducts: 《CCS Chemistry》2024年第10期2607-2618,共12页Yong Liu Chaopeng Li Rui Zhang Zibo Liu Zhaobin Han Zheng Wang Kuiling Ding; the National Key R&D Program of China(grant nos.2023YFA1506700,2022YFA1503702,and 2021YFF0701602);National Natural Science Foundation of China(NSFC,grant nos.22231011 and 22271303);Shanghai Scientific and Technological Innovation Project,China(grant no.22JC1401000).; A synergistic Pd/Zn dual chiral catalyst system has been developed for the stereodivergent transformation of Morita–Baylis–Hillman(MBH)carbonates and unprotectedα-hydroxyketones to afford the corresponding allylati...; 关键词：asymmetric catalysis Pd/Zn dual catalyst 2-(alkoxycarbonyl)allylation stereodivergent sitedivergent

A Machine Learning Model for Predicting Enantioselectivity in Hypervalent Iodine(III)Catalyzed Asymmetric Phenolic Dearomatizations: 《CCS Chemistry》2024年第10期2515-2528,共14页Ben Gao Liu Cai Yuchen Zhang Huaihai Huang Yao Li Xiao-Song Xue; supported by the Ministry of Science and Technology of China(grant no.2021YFF0701700);the National Natural Science Foundation of China(grant nos.22122104,22193012,and 21933004);the CAS Project for Young Scientists in Basic Research(grant nos.YSBR-052 and YSBR-095);the Strategic Priority Research Program of the Chinese Academy of Sciences(grant no.XDB0590000).; Catalytic asymmetric dearomatization(CADA)of phenols has emerged as a powerful strategy for constructing stereochemically complicated architectures from planar aromatic feedstocks.However,the development of novel cata...; 关键词：machine learning chiral hypervalent iodine CATALYSIS DEAROMATIZATION ENANTIOSELECTIVITY

Stereodivergent Benzylic Substitution of Racemic Secondary Benzyl Esters Enabled by Pd/Cu Dual Catalysis: 《CCS Chemistry》2024年第10期2452-2464,共13页Youbin Peng Guanlin Li Chongyu Han Yicong Luo Xiaohong Huo Wanbin Zhang; supported by the National Key R&D Program of China(grant no.2023YFA1506700);the National Natural Science Foundation of China(NSFC,grant nos.21831005,21991112,and 22171183).; Transition-metal-catalyzed asymmetric benzylic substitution of racemic benzyl esters is an efficient and straightforward route towards the construction of benzylic stereocenters but remains a challenge,due to the diff...; 关键词：amino acids asymmetric catalysis benzylic substitution bimetallic catalysis stereodivergent synthesis

Eco-Friendly Encapsulation of Metal Clusters in Porous Organic Cages for Engineerable Microenvironment and Enhanced Catalysis被引量：1: 《CCS Chemistry》2024年第9期2186-2197,共12页Siyu Ren Liangxiao Tan Jun-Hao Zhou Jian Sun Peng Zhang Xingzhong Cao Yun-Hong Zhang Jian-Ke Sun; supported by the National Natural Science Foundation of China(grant nos.22071008 and 52003029);the High-level Overseas Talents Program of China,the Excellent Young Scholars Research Fund from the Beijing Institute of Technology,and the Central University Basic Research Fund of China(grant no.2021CX01024);financial support from the China Postdoctoral Science Foundation(grant no.2022M710375);The technical support from Analysis&Testing Center of Beijing Institute of Technology is also appreciated.; Developing artificial catalysts that mimic the functionality of enzymes and adapt to the surrounding microenvironment to achieve specific activity and selectivity is a fascinating research area yet remains a great cha...; 关键词：metal cluster porous organic cage ENCAPSULATION MICROENVIRONMENT CATALYSIS

Asymmetric NiH-Catalyzed Regioselective Hydroalkynylation of Unactivated Alkenes: 《CCS Chemistry》2024年第8期1929-1940,共12页Mengyuan Liu Haoran Shi Xiao Meng Rui He Jie Huang Jiaxin Wang Jun Lv Chao Wang; supported by the National Natural Science Foundation of China(grant no.21901185);funds provided by Tianjin Normal University,China.; Herein,we disclose a ligand-controlled,directing group-assisted strategy to facilitate NiH-catalyzed hydroalkynylation of allyl amides at remoteα-position adjacent to nitrogen and initial olefinic site in a predictab...; 关键词：asymmetric catalysis hydroalkynylation regiodivergent chain-walking nickel catalysis

Research Progress in Enantioselective Radical Desymmetrization Reactions: 《CCS Chemistry》2024年第7期1612-1627,共16页Chang-Jiang Yang Lin Liu Qiang-Shuai Gu Xin-Yuan Liu; Financial support from the National Natural Science Foundation of China (grant nos.22025103,92256301,21831002,22271133,22101122,and 22201127);the National Key R&D Program of China (grant nos.2021YFF0701604 and 2021YFF0701704);New Cornerstone Science Foundation through the XPLORER PRIZE,Shenzhen Science and Technology Program (grant nos.KQTD20210811090112004 and JCYJ20220818100600001);Shenzhen Key Laboratory of Cross-Coupling Reactions (grant no.ZDSYS20220328104200001).; Enantioselective radical desymmetrization is a highly effective approach for rapidly creating enantioenriched molecules,introducing dramatically increased structural complexity from readily available prochiral or meso...; 关键词：radical desymmetrization enantioselective desymmetrization radical functionalization transition metal catalysis asymmetric catalysis

Atroposelective Synthesis of 3-Aryl-Indoles Through a One-Pot 2,3-Difunctionalization of Simple Indoles: 《CCS Chemistry》2024年第7期1672-1680,共9页Lei Dai Yu-Li Sun Jiami Guo Xueting Zhou Qingqin Huang Yixin Lu; Indole and its derivatives represent the most important heterocycles that are widely present in bioactive molecules,natural products and advanced materials,and thus functionalization of simple indoles to construct com...; 关键词：axial chirality atroposelectivity sequential catalysis difunctionalization of indoles chiral phosphoric acid

Dramatic Difference Between Cu_(20)H_(8)and Cu_(20)H_(9)Clusters in Catalysis被引量：1: 《CCS Chemistry》2024年第6期1581-1590,共10页Chun-Yu Liu Tong-Yu Liu Zong-Jie Guan Song Wang Yuan-Yuan Dong Feng Hu De-en Jiang Quan-Ming Wang; supported by the National Natural Science Foundation of China(grant nos.91961201 and 21973116);the Beijing Natural Science Foundation(grant no.2234087);the China Postdoctoral Science Foundation(grant nos.2023T160357 and 2022M721797).; Sensitivity to structure and composition is very challenging to establish in nanocatalysis due to inadequate definition of structures that are very close in composition.We synthesized a pair of atomically precise copp...; 关键词：copper cluster HYDRIDE amidinate ligand structural transformation hydrogenation catalysis

On Depolymerization: 《CCS Chemistry》2024年第2期297-312,共16页Bo Qin Xi Zhang; supported by the National Natural Science Foundation of China(grant nos.22193020 and 22193021).; Polymers have become an essential part of modern life and the global economy on account of their costeffectiveness and versatile properties.However,most postconsumer polymer wastes are unrecycled,leading to environmen...; 关键词：DEPOLYMERIZATION chemical recycling sustainable polymers circular polymer economy CATALYSIS dynamic covalent chemistry

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