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support from the National Key Research and Development Program of China(No.2017YFD0200505)。
A novel and practical method for the synthesis of 3,5-bis(trifluoromethyl)-4,5-dihydro-1H-pyrazoles by [3+2] cycloaddition reactions of α-(trifluoromethyl)styrenes with 2,2,2-trifluorodiazoethane (CF3CHN2) has been d...
supported by the National Basic Research Program of China(2013CB834505;2013CB834804);the National Natural Science Foundation of China(21390404;91427303;21402217);the Key Research Programme of the Chinese Academy of Sciences(KGZD-EW-T05)
With visible light(λ=450 nm) irradiation of a catalytic amount of platinum(Ⅱ) terpyridyl complex, 1,3,5-triaryl-2-pyrazolines can be smoothly converted to their corresponding pyrazoles and hydrogen in quantitative y...
We reported the environmental benign synthesis of chalcones,2-pyrazolines and cyclohexanones under microwave irradiation.Chalcones were obtained by the condensation of each of 2-hydroxyacetophenone derivatives with a-...
partial financial support by Guangdong Natural Science Foundation(No.7006672);South China Agricultural University Foundation(Nos.2009B010100001, 2009C020604002)
A series of novel 5-phenyl-3-(2,2':5',2″-terthien-5-yl)-4,5-dihydro-lH-pyrazolines were synthesized in this report. Their photoactivated cytotoxicities on the 5podoptera litura (SL) cell line were evaluated us...
UGC(BSR)-India for givingfinancial support as JRF&SRF
An efficient and facile synthesis of a library of hitherto novel 1,2,3-triazolyl-N-acetyl/N-propionylpyrazoline hybrids (16 examples) in excellent yields (90%-96%) has been accomplished from easily accessible 1,2,...
The present manuscript describes solid-state synthesis of some reported steroidal pyrazolines by a novel eco-friendly route. The synthesized pyrazolines were compared with those obtained from conventional methods in t...
1,3,5-Trisubstituted pyrazolines are rapidly and conveniently oxidized to their corresponding pyrazoles by 1,3-dichloro-5,5- dimethylhydantoin(DCH) in solution and solvent-free conditions under microwave irradiation...
Project No.20572040 was supported by National Natural Science Foundation of China.
1,3,5-Trisubstituted pyrazolines were oxidized to the corresponding pyrazoles in high yield with tris(4-bromophenyl)aminium (TBPA**) hexachloroantimonate in chloroform at room temperature.