FLUOROALKYLATION

作品数:13被引量:6H指数:1
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相关领域:理学更多>>
相关机构:上海大学兰州大学更多>>
相关期刊:《Science Bulletin》《Chinese Journal of Chemistry》《Science China Chemistry》《Chinese Chemical Letters》更多>>
相关基金:国家自然科学基金上海市青年科技启明星计划更多>>
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Transition-Metal-Mediated Fluoroalkylation of Carbon Electrophiles through Cross-Electrophile Couplings
《Chinese Journal of Chemistry》2024年第24期3499-3517,共19页Yun-Cheng Luo Xingang Zhang 
supported by the National Natural Science Foundation of China(21931013,21991122);the National Key R&D Program of China(2021YFF0701700);the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB0590000);the Science and Technology Commission of Shanghai Municipality(22JC1403500,21XD1404400).
Organofluorine compounds have attracted substantial interest in life and materials sciences due to the unique properties of fluorine atom(s)that often change the physicochemical and biological properties of organic mo...
关键词:FLUOROALKYLATION Cross-electrophile coupling Dicarbofunctionalization Copper Nickel catalysis 
Copper/Photoredox-Catalyzed Regioselective 1,4-Addition to 1,3-Enynes: A Convenient Access to Perfluoroalkylated Allenes
《Chinese Journal of Chemistry》2024年第17期2023-2028,共6页Ya Chen Quanyuan Wang Keyi Peng Lilei Cheng Ziyi She Guo-Jun Deng 
supported by the National Natural Science Foundation of China(Nos.22301256 and 22271244);the Hunan Provincial Natural Science Foundation of China(2023JJ40618);the Open Research Fund of School of Chemistry and Chemical Engineering,Henan Normal University(2022c02);the Hunan Provincial Innovation Foundation for Postgraduate(CX20230644,XDCX2023Y162)
A general and broadly applicable copper and photoredox dual-catalyzed multicomponent 1,4-perfluoroalkylcyanation of 1,3-enynes has been developed.This protocol enjoys success with high regioselectivity,mild reaction c...
关键词:Fluorinated allenes 1 3-Enynes PHOTOREDOX FLUOROALKYLATION Multicomponent reactions Difunctionalization Radicals Regioselectivity 
Nucleophilic Difluoro(phenylsulfonimidoyl)methylation of Unactivated Alkyl Bromides with PhSO(NTBS)CF_(2)H: Facile Entry into gem-Difluoroalkenes
《Chinese Journal of Chemistry》2014年第8期703-708,共6页Xiao Shen Qinghe Liu Chuanfa Ni Jinbo Hu 
Support of our work by the National Basic Research Program of China(Nos.2012CB215500 and 2012CB821600);the NNSFC(No.21372246);Shanghai QMX program(No.13QH1402400);the Chinese Academy of Sciences is gratefully acknowledged.
An efficient nucleophilic difluoro(phenylsulfonimidoyl)methylation of unactivated primary alkyl bromides with PhSO(NTBS)CF_(2)H has been developed.It is particularly remarkable that,when 1.5 equiv.of alkyl bromides ar...
关键词:nucleophilic fluoroalkylation β-elimination difluoroalkene SULFOXIMINE 
A simple and effective method for fluoroalkylation——the addition of fluoroalkyl iodide to olefins in the presence of hydrogen peroxide
《Chinese Journal of Chemistry》1991年第2期184-188,共0页CHEN,Qing-Yun CHEN,Ming-Fang Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032 
This project was supported by the National Natural Science Foundation of China.
Addition of fluoroalkyl iodides to olefins in the presence of hydrogen peroxide(H_2O_(?)) in acetone,acetonitrile or ethanol gave the corresponding 1:1 adducts in good yields.Reaction of fluoroalkyl iodide with dially...
关键词:A simple and effective method for fluoroalkylation the addition of fluoroalkyl iodide to olefins in the presence of hydrogen peroxide 
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