financial support from the National Research Council of Science&Technology(NST)grant funded by the Ministry of Science and ICT,Republic of Korea(CAP21012-100);the Korea Institute of Energy Technology Evaluation and Planning(KETEP),under the Ministry of Trade,Industry&Energy(MOTIE),Republic of Korea(20224C10300010);the KETEP grant funded by the MOTIE(20224000000440,Sector coupling energy industry advancement manpower training program)。
The metal oxide promoter decisively influences the overall performance of Fe catalysts in the direct hydrogenation of CO_(2)to C_(5+)hydrocarbons.However,the roles of metal oxide promoter for Fe catalysts,particularly...
supported by the National Natural Science Foundation of China(22171174);the Fundamental Research Funds for the Central Universities(GK202207015,GK202304033,GK202401008);the Innovation Capability Support Program of Shaanxi(2023-CX-TD-28);the Fundamental Science Research Project of Shaanxi for Chemistry,Biology(22JHZ002);the Natural Science Foundation of Shaanxi Province(2023-JC-YB-100);the China Postdoctoral Science Foundation(2023M732165);the Shaanxi Province Postdoctoral Science Foundation(2023BSHYDZZ107);the Young Talent Fund of Association for Science and Technology in Shaanxi,China(20240606)。
N-Hydroxyphthalimide(NHPI)esters have emerged as powerful sources of alkyl radicals generated by single-electron transfer,but homolysis of NHPI ester to produce an alkyl radical and a phthalimide nitrogen radical is s...
supported by the National Natural Science Foundation of China (21991121);the National Key Research and Development Program of China (2021YFF0701700)。
Pentafluorosulfanylated(SF_(5^(-))) aromatics have shown great potential in drugs, and the bioisosteric replacement of aromatic ring with bicyclo[1.1.1]pentane(BCP) unit has attracted considerable attention recently. ...
Two novel copper complexes (1,2) with N,O-donor ligands were synthesized by reaction of copper(II) malonates with 3,3’-bis(pyrazolyl)pentane and 4,4’-trimethylenedipyridine in methanol at moderate t...
the National Natural Science Foundation of China(Nos.21672037 and 21532001);the Leading Innovative and Entrepreneur Team Introduction Program of Zhejiang(No.2019R01005)。
As a highly strained small molecule,[1.1.1]propellane has been widely used in various synthetic transformations owing to the exceptional reactivity of the central bond between the two bridgehead carbons.Utilizing stra...
supported by the National Natural Science Foundation of China(21722205,21971173);the Project of Scientific and Technologic Infrastructure of Suzhou(SZS201905);the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)。
Rational design of new bioisosteres through introduction of high-value functional groups to bicyclo[1.1.1]pentane(BCP)is of particular use for drug discovery.Disclosed herein is the first access to valuable fluoroalky...
supported by NNSFC (21072053);the Scientific Research Fund of Hunan Provincial Education Department (10K025, 11C0527);the Open Foundation of Key Laboratory of Theoretical Chemistry and Molecular Simulation of Ministry of Education;Hunan University of Science and Technology (No. LKF0901)
Two anti-2,4-bis(3-R-phenyl)pentane-2,4-diols (1, R = Me; 2, R = SMe) have been synthesized and were characterized by X-ray diffraction, IR and UV spectra. X-ray diffractions indicate that intra- and intermolecula...
Projects(21072053,20772028)supported by the National Natural Science Foundation of China;Projects(10K025,11C0527)supported by the Scientific Research Fund of Hunan Provincial Education Department,China;Project(LKF0901)supported by the Open Foundation of Key Laboratory of Theoretical Chemistry and Molecular Simulation of Ministry of Education,Hunan University of Science and Technology,China
2,4-diphenylpentane- and 2,4-di-p-tolylpentane-2,4-diols were investigated employing experimental and density functional theory (DFT) method at B3LYP/6-31G (d) level. The structure of syn-2,4-di-p-tolylpentane-2,4...
Supported by National Natural Science Foundation of China (No. 20476080);Tianjin Natural Science Foundation (No. 07JCYBJC00600)
A series of electron donors,including 1,1-cyclopentanecarboxylic acid diethyl ester (CPCADEE),1,1cyclopentanedimethanol acetic diester (CPDMAD),1,1-biethoxymethyl pentane (BEMP),2,2-diethyl diethylmalonate (DEDEM)and ...