supported by the National Natural Science Foundation of China(Nos.21625205 and U19A2014)。
The cascade reactions of alkyl α-diazoesters and ynones using Al(OTf)_(3) as the catalyst are described.A series of 4-substituted pyrazoles were obtained via [3+2] cycloaddition,1,5-ester shift,1,3-H shift,and N-H in...
The highly regio-and stereoselective hydroborations of unactivated internal alkynes with diboron compound catalyzed by Cu(OTf)2 with spiro(phosphoamidite) as ligand in the presence of Cs2CO3 in water was developed...
the National Natural Science Foundation of China(No.20802052)for financial support
The Y(OTf)3-catalyzed aerobic oxidative cyclization reaction for the selective synthesis of dihydroqui- nazolinones and quinazolinones has been developed. This method provides a practical, effective and green synthe...
supported by the Science and Technology Development Project of Weihai (Nos.2011DXGJ13,2012DXGJ02);the Natural Science Foundation of Shandong Province (No.ZR2012BM002);the National Natural Science Foundation of China (Nos.21202028,21372054)
An efficient synthesis of functionalized 4H-chromenes by the tandem reaction of β,γ-unsaturated α- ketoesters with 2-naphthols, 1 -naphthols, and 1,3-dihydroxynaphthalenes has been accomplished with high selectivit...
supported by the Islamic Azad University,Ayatollah Amoli Branch
A polyvinylpolypyrrolidone supported triflic acid was shown to be useful as a recyclable heterogeneous catalyst for the rapid and efficient synthesis of quinoxaline derivatives in good-to-excellent yields. The catalys...
the Center of Excellence of Chemistry and Research Council of University of Isfahan for financial support of this work
An efficient, convenient and green method has been introduced for the preparation of 14-aryl(alkyl)-14H-dibenzo[a,j]xanthene and 1,8-dioxooctahydroxanthene derivatives by the reaction of aldehydes with 2-naphthol an...
supported by National Science Foundation of China(No.20772033);China postdoctoral Science Foundation(No.20080440607)
Oxonium ylide intermediates generated from α-diazocarbonyl compounds and water were trapped by Zn(Ⅱ)-activated α- dicarbonyl compounds. The reaction gave α,β-dihydroxyl acid derivatives in moderate yield.
the National Key Technology R&D Program(No.2007BAI34B00);the National Natural Science Foundation of China(No.20876147 and 20676123);the Natural Science Foundation of Zhejiang Province(No.Y4080107) for financial support.
A Yb(OTf)3-catalyzed approach for the synthesis of pyrroles under solvent-free conditions was achieved, which could afford the desired products with yields ranged from moderate to excellent.
the National Natural Science Foundation of China(Nos.20421202,20372033)for financialsupport.
In the presence of catalytic amount of In(OTf)3 (10 mol%), a series of aldimines reacted with tetraallyltin in a 2:1 molar ratio to afford the corresponding homoallylic amines in good yields. The good atom effici...
Under the catalysis of Yb(OTf)3, nucleophilic conjugate addition of pyrrole to electron deficient olefins in CH2Cl2 at ambient temperature gives corresponding 2-alkylated pyrrole derivatives in good yields with high s...