POLYCARBOSILANE

作品数:13被引量:42H指数:4
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相关领域:化学工程更多>>
相关作者:杨大祥余煜玺宋永才朱冬梅周万城更多>>
相关机构:国防科学技术大学装甲兵工程学院厦门大学西北工业大学更多>>
相关期刊:《Acta Metallurgica Sinica(English Letters)》《Science China(Technological Sciences)》《Journal of Wuhan University of Technology(Materials Science)》《Journal of Advanced Ceramics》更多>>
相关基金:国家自然科学基金国家高技术研究发展计划湖北省自然科学基金更多>>
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Effect of heating rate on the properties of silicon carbide fiber with chemical-vapor-cured polycarbosilane fiber被引量:6
《Journal of Advanced Ceramics》2017年第1期59-66,共8页Tae-Eon KIM Khos-Erdene KHISHIGBAYAR Kwang Youn CHO 
Silicon carbide (SiC) fiber has recently received considerable attention as promising next-generation fiber because of its high strength at temperatures greater than 1300 ℃ in air.High-quality SiC fiber is primarily ...
关键词:polycarbosilane (PCS) silicon carbide (SiC) fiber chemical vapor curing rapid heating rate high temperature tensile strength 
Study on the Pyrolysis Behavior of Polycarbosilane被引量:2
《Journal of Wuhan University of Technology(Materials Science)》2015年第4期679-683,共5页陈文怡 ZHOU Jian 
Funded by the Natural Science Foundation of Hubei Province(No.2013CFB340)
The pyrolysis behavior of polycarbosilane (PCS) and chemical reaction mechanism during the pyrolysis process were studied by thermogravimetric-mass spectrometry (TG-MS) combined with X-ray diffraction and infrared...
关键词:POLYCARBOSILANE pyrolysis behavior thermogravimetric-mass spectrometry heating ratemass loss 
Synthesis and characterization of high ceramic yield polycarbosilane precursor for SiC被引量:5
《Journal of Advanced Ceramics》2015年第4期307-311,共5页Mangesh LODHE Narendra BABU A.SELVAM M.BALASUBRAMANIAN 
The polycarbosilane(PCS)precursor for SiC with high molecular weight and medium molecular weight distribution was synthesized from polydimethylsilane at normal pressure.The chemical formula,the number average molecula...
关键词:synthesis polycarbosilane(PCS) polymer-ceramic conversion X-ray diffraction(XRD) 
Synthesis and ceramization of polycarbosilane containing beryllium被引量:6
《Journal of Central South University》2014年第1期71-75,共5页黄小忠 周珊 程勇 杜作娟 段曦东 王超英 
Project(51074193)supported by the National Natural Science Foundation of China;Projects(2011AA7024034,2011AA7053016)supported by the National High Technology Research and Development Program of China;Project(LK0903)supported by State Key Laboratory for Modification of Chemical Fibers and Polymer Materials,Donghua University,China
Polycarbosilane containing beryllium(BPCS) precursors was prepared by the reaction of polycarbosilane(PCS) with beryllium acetylacetone(Be(acac)2).The analysis of structures and components of BPCS demonstrates that th...
关键词:POLYCARBOSILANE BERYLLIUM PRECURSOR CERAMIZATION 
Influence of pyrolysis temperature on structure and dielectric properties of polycarbosilane derived silicon carbide ceramic被引量:2
《Transactions of Nonferrous Metals Society of China》2012年第11期2726-2729,共4页丁冬海 周万城 周璇 罗发 朱冬梅 
Project (50572090) supported by the National Natural Science Foundation of China;Project (KP200901) supported by the Fund of the State Key Laboratory of Solidification Processing, China
β-SiC ceramic powders were obtained by pyrolyzing polycarbosilane in vacuum at 800-1200 °C. The β-SiC ceramic powders were characterized by TGA/DSC, XRD and Raman spectroscopy. The dielectric properties of β-SiC c...
关键词:silicon carbide ceramic polycarbosilane derived SiC dielectric properties pyrolysis temperature free carbon complexpermittivity 
Effects of Heating Rate on Properties and Structures of 3D-Cf/SiC Composites by PIP Process
《Chinese Forestry Science and Technology》2012年第3期75-75,共1页Chen Zhiyan Zou Shiqin 
The properties and structures of 3D-Cf/ SiC composites prepared by rapid precursor infiltration pyrolysis process were studied.PCS solution was infiltrated into 3D-carbon fiber perform in vacuum,then these performs we...
关键词:CF/SIC COMPOSITES POLYCARBOSILANE precursor INFILTRATION PYROLYSIS high-speed PYROLYSIS 
Fabrication of SiC fibres from yttrium-containing polycarbosilane被引量:4
《Transactions of Nonferrous Metals Society of China》2012年第4期879-886,共8页杨大祥 宋永才 余煜玺 赵晓峰 肖平 
Projects (51175444,50532010) supported by the National Natural Science Foundation of China;Project (2011121002) supported by the Fundamental Research Funds for the Central Universities, China;Project (2009J1009) supported by Scientific and Technological Innovation Platform of Fujian Province,China
The yttrium as a sintering aid was introduced into polycarbosilane(PCS) to prepare yttrium-containing PCS(PYCS).Two types of yttrium-containing SiC fibres,the SiC(OY) fibres and the SiC(Y) fibres,were fabricat...
关键词:POLYCARBOSILANE YTTRIUM silicon carbide FIBRE 
Synthesis of ceramic precursor polycarbosi-lane (PCS) under supercritical fluids (SCFs) state被引量:3
《Science China(Technological Sciences)》2008年第9期1445-1450,共6页YANG DaXiang SONG YongCai LI ZongYuan 
Using xylene as supercritical fluids (SCFs) media and polydimethylsilane (PDMS) as raw material, the ceramic precursor polycarbosilane (PCS) with moderate molecular weight and narrow molecular weights distribution was...
关键词:POLYCARBOSILANE PRECURSOR SUPERCRITICAL FLUIDS synthesis SiC 
One-pot synthesis and characterization of a new, branched polycarbosilane bearing allyl groups被引量:12
《Chinese Chemical Letters》2007年第6期754-757,共4页Tian Hua Huang Zhao Ju Yu Xu Min He Mu He Huang Li Fu Chen Hai Ping Xia  Li Tong Zhang 
A highly branched polycarbosilane bearing allyl groups has been prepared by a one-pot synthesis with chloromethyltrichlorosilane, chloromethylmethyldichlorosilane and allyl chloride as the starting materials. The resu...
关键词:POLYCARBOSILANE One-pot synthesis Silicon carbide precursor Ceramic precursor 
In situ formation of nanometer-scale TiO_2/SiC functional compositional film on carbon fiber
《Science China(Technological Sciences)》2005年第1期53-60,共8页ZHOU Chunhua YIN Yansheng ZHANG Shuxiang LIU Wei 
In the toluene solution of the precursor Polycarbosilane (PCS) containing low- molecular-mass additive Ti(OC4H9)4, TiO2/SiC nanometer-scale functional compositional film with the surface TiO2 layer on CF was formed in...
关键词:polycarbosilane  TiO2/SiC NANOMETER-SCALE functional compositional film  CF  in SITU formation. 
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