SOLVENT-FREE

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Solvent-free selective oxidation of cyclohexane with molecular oxygen over manganese oxides:Effect of the calcination temperature被引量：2
《Chinese Journal of Catalysis》2016年第1期184-192,共9页吴明周 詹望成 郭耘 王筠松 郭杨龙 龚学庆 王丽 卢冠忠 
supported by the National Basic Research Program of China(973 Program,2010CB732300);the National Natural Science Foundation of China(21103048)~~
The effects of calcination temperature on the physicochemical properties of manganese oxide catalysts prepared by a precipitation method were assessed by X-ray diffraction,N2 adsorption-desorption,X-ray photoelectron ...
关键词：Manganese oxide catalyst Selective oxidation of cyclohexane OXYGEN Calcination temperature Solvent-free reaction 
The promoting role of minor amount of water in solvent-free hydrogenation of halogenated nitrobenzenes被引量：3
《Chinese Chemical Letters》2014年第2期205-208,共4页Jing-Hui Lyu Xiao-Bo He Chun-Shan Lu Lei Ma Qun-Feng Zhang Feng Feng Xiao-Nian Li Jian-Guo Wang 
supported by the National Natural Science Foundation of China(Nos.20976164,21176221 and 21136001);National Basic Research Program of China(973 Program)(Nos. 2011CB710803,2013CB733500);Zhejiang Provincial Natural Science Foundation of China(No.LY12B03005)
This study shows that minor amount of water plays a very important role in solvent-free hydrogenation of halogenated nitrobenzenes. For dried sponge Pd, the reaction cannot occur in the absence of water. For Pd/C cata...
关键词：Halogenated nitrobenzenes Solvent Free WATER HYDROGENATION 
Rare-Earth Metal Chlorides Catalyzed One-pot Syntheses of Quinolines under Solvent-free Microwave Irradiation Conditions被引量：1
《Chinese Journal of Chemistry》2013年第4期465-471,共7页Lijun Zhang Bing Wu Yongqing Zhou Jing Xia Shuangliu Zhou Shaowu Wang 
The work was supported by the National Natural Science Foundation of China （21172004, 21172003 and 21072004）, the National Basic Research Program of China （2012CB821604）, and grants from the Ministry of Education （20103424110001）.
Under microwave irradiation and solvent-free conditions, rare-earth metal chlorides （RECl3） have been efficient catalysts for one-pot synthesis of quinoline derivatives to give products in good to excellent yields t...
关键词：rare earth QUINOLINE multi-component reaction microwave irradiation RECYCLABLE 
Preparation of Cu/ZnO/Al_2O_3 catalysts in a solvent-free routine for CO hydrogenation
《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》2012年第5期395-406,共12页Hong LEI Ren-feng NIE Jin-hua FEI Zhao-yin HOU 
supported by the National Natural Science Foundation of China (Nos. 21073159 and 90610002);the National Basic Research Program (973) of China (No. 2007CB210207);the Zhejiang Provincial Natural Science Foundation of China (No. Z406142)
The synthesis of methanol and dimethyl ether(DME) from CO hydrogenation has been investigated on Cu-based catalysts.A series of Cu/ZnO/Al2O3 catalysts were prepared using a solvent-free routine which involved a direct...
关键词：Cu/ZnO/Al2O3 catalyst Solvent-free routine CO hydrogenation METHANOL Dimethyl ether 
Kinetic evaluation of the size-dependent decomposition performance of solvent-free microcellular polylactic acid foams被引量：1
《Chinese Science Bulletin》2012年第1期83-89,共7页GUO GePu MA QingYu WANG Fang ZHAO Bo ZHANG Dong 
supported by the National Basic Research Program of China(2011CB707900);the National Natural Science Foundation of China(10974098);the Natural Science Foundation of Jiangsu Province(BK2009407);the Doctoral Fund of the Ministry of Education of China(20093207120003)
A thermal gravimetric method is described for evaluating the kinetics of cell size-dependent decomposition and lifetime estima- tion for microcellular tissue engineering scaffolds made of biodegradable polylactic acid...
关键词：分解动力学 泡沫细胞 聚乳酸 无溶剂 热性能 评价 微孔 寿命估计 
CO2-Triggered Metal Catalyst- and Solvent-free Aminochlorination of Methylenecyclopropanes
《Chinese Journal of Chemistry》2011年第12期2739-2743,共5页齐明辉 邵黎雄 施敏 
Project supported by Shanghai Municipal Committee of Science and Technology （No. 08dj1400100-2）, National Basic Research Program of China （973） （No. 2009CB825300） and the National Natural Science Foundation of China （Nos. 21072206, 20472096, 20872162, 20672127, 20821002 and 20732008）.
Aminochlorination of methylenecyclopropanes （MCPs） 1 can be achieved under CO2 atmosphere using N,N-dichlorotoluenesulfonamine （TsNCl2） as the nitrogen and halogen sources at room temperature to give the correspon...
关键词：aminochlorination METHYLENECYCLOPROPANES carbon dioxide 
Highly efficient heterogeneous procedure for the conjugate addition of amines to electron deficient alkenes
《Science China Chemistry》2009年第7期874-878,共5页XueZheng Liang  NanNan Quan  Jian Wang JianGuo Yang 
Supported by the National Key Project of Scientific and Technical Supporting Programs Funded by Ministry of Science and Technology of China (Grant No. 2006BAE03B06);Shanghai Leading Academic Discipline Project (Grant No. B409);Shanghai International Cooperation of Science and Technology Project (Grant No. 06SR07101)
The novel efficient procedure has been developed for the conjugate addition of amines to electron deficient alkenes. K2CO3 supported on different carriers have been synthesized for the conjugate ...
关键词：heterogeneity CONJUGATE addition CHEMOSELECTIVITY catalysis SOLVENT-FREE 
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