the assistance of the project supported by the National Natural Science Foundation of China(22375157,22401227);the Programme of Introducing Talents of Discipline to Universities(B23025);State Key Laboratory of Electrical Insulation and Power Equipment(EIPE23402,EIPE23405);the China Postdoctoral Science Foundation(2023M742783,GZB20240599);"Medical-Engineering Cross Project of the First Affiliated Hospital of XJTU(QYJCo2)";Shaanxi Postdoctoral Science Foundation(2023BSHYDZZ12)and the"Scientists+Engineers"Team Building Project of Qin Chuang Yuan(2022KXJ-088).
Two families of cyclopentadienyl(Cp)/carboranyl heteroleptic sandwiched organolanthanide complexes,namely[Ln{η^(5):σ-Me_(2)C(C_(5)H_(4))(C_(2)B_(10)H_(10))}_(2)][Li(DME)_(3)](1Ln,Ln=Tb,Dy,Ho,Er)and[2-THF-2'-(μ^(2)-...
Project supported by the National Natural Science Foundation of China (No. 20372022) and the Major State Basic Research Development Program of China (No. 2005CB623801).
Two new complexes [η^5-C5H4CMe2-(p-fluorophenyl)]TiCL3 (1) and [η^5-C4h4C(cyclo-C5H10)-(p-fluorophenyl)]TiCl3 (2) were synthesized and characterized. Their activities and selectivities for trimerization of...
Project supported by the National Natural Science Foundation of-Chi-na (Nos. 20372036 and 20421202), the Tianjin Natural Science Foundation (No. 05YFJMJC06800).
1,2-Diphenyl-1,2-dimethyldisilanylene-bridged bis-cyclopentadienyl complex [η^5,η^5-C5H4PhMeSiSiMePh-C5H4]Fe2(CO)2μ-CO)2 (1) was synthesized by a modified procedure, from which the trans-isomer lb that was pre...
Project supported by the National Natutral Science Foundation of China (No. 20372016).
[Cp2Ln(μ-SR)]2 was reacted with Ph2C=C=O to yield ketene mono-insertion products [Cp2Ln(μ-η1:η2-OC(SR)=CPh2)]2 [R=Bn, Ln=Yb (1), Er (2), Y (3) and R--Ph, Ln=Yb (4)], indicating that the reactions of...
Project supported by the Major State Basic Research Development Program(No.G1999064801) the National Natural Science Foundation of China (No. 20372022) and the Research Fund for the Doctoral Program of Higher Education (No. 20020251002).
Complexes (R^1Cp)(R^2Ind)ZrCl2, the catalysts previously reported active for ethylene polymerization showed high activity in ethylene/1-hexene copolymerization and propylene polymerization in the presence of MAO. ...
the National Natural Science Foundation of China and the Research Funds of Excellent Young Teacher and the New Century Distinguished Scientist of National Education Ministry of China.
Six new ethylthioethylcyclopentadienyl-containing organolanthanide complexes CpTh 2LnCl [Ln=Gd (1), Dy (2)] and Cp2LnCpTh [Cp=C5H5, Ln=Yb (3), Sm (4), Dy (5), Y (6)] were synthesized by the reaction of ethylthioethyl-...
Project supported by the Major State Basic Research Development Program (No. G1999064801); and the National Natural Science Foundation of China (Nos. 20072004 and 29871010).
Yan-LongBALA, Muhammad D. XIE, Xiao-Min(HUANG, Ji-Ling*Laboratory of Organometallic Chemistry, East China University of Science and Technology, Shanghai 200237, China Benzyl-substituted cyclopentadienyl lanthanide...
ProjectsupportedbytheNaturalScienceFoundation (No .0 0 0 46 5 0 9)ofAnhuiProvince ,theNaturalScienceFoundation (No .2 0 0j10 90 )ofAnhuiEducationCommitteeandtheYouthFoundationofAnhuiNormalUniversity
The decomposition temperatures of the lanthanide organic complexes (η 5-C 5H 5) 2Ln(C 6H 5CONHO) involving cyclopentadienyl and benzohydroxamic acid ligands were calculated and predicted by the model based on A...
Project (No. 29771008) supported by the National Natural Science Foundation of China;A research grant from the State Educational Committee of China;a Fudan University Faculty Research Grant for partial support of this work are greatly acknowledged. Tif