The selective activation of C-H bonds is pivotal in catalysis for converting hydrocarbons into value-added chemicals.Ethylbenzene dehydrogenation to styrene is crucial process to produce polystyrene and its derivative...
Photocatalytic water splitting using natural solar light is considered as a sustainable approach to generate H_(2) and O_(2).While H_(2) has high market value,the by-product of water splitting,oxygen,is less valuable....
Modifying the electronic density of states and the synergistic effect of the active centers by introducing a second metal present an efficient strategy to tune physi/chemi-sorption,probably lead to improving catalytic...
The C–H bond activation in alkane dehydrogenation reactions is a key step in determining the reaction rate.To understand the impact of entropy,we performed ab initio static and molecular dynamics free energy simulati...
Light olefins are important platform feedstocks in the petrochemical industry,and the ongoing global economic development has driven sustained growth in demand for these compounds.The dehydrogenation of alkanes,derive...
Hexagonal boron nitride(h-BN)is a highly selective catalyst for oxidative dehydrogenation of light alkanes to produce the corresponding alkenes.Despite intense recent research effort,many aspects of the reaction mecha...
A room-temperature electrochemical strategy for hydrogenation(deuteration)and reverse dehydrogenation of N-heterocycles over a bifunctional MoNi_(4)electrode is developed,which includes the hydrogenation of quinoxalin...
The development of bifunctional catalysts for the efficient hydrogenation and acceptorless dehydrogenation of N‐heterocycles is a challenge.In this study,Ru_(2)P/AC effectively promoted reversible transformations bet...
supported by the National Natural Science Foundation of China(21421001,21573115);the 111 project(B12015);the Foundation of State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering(2017-K13)~~
The VOx catalysts supported on dealuminated Beta zeolite(Si Beta) with varying V loadings(from 0.5 to 10 wt%) are prepared and tested for their catalytic activities in the reaction of direct dehydrogenation of propane...
supported by C1 Gas Refinery Program(2015M3D3A1A01064899)by the Ministry of Science,ICT&Future Planning;Basic Science Research Program through the National Research Foundation of Korea funded by the Ministry of Education(Grant No.:NRF-2015R1A4A1042434)
Uniform Pd nanoparticles immobilized on N-(3-trimethoxysilylpropyl)diethylenetriamine (PDETA)-functionalized fibrous silica KCC-1 (Pd/KCC-1-PDETA) were prepared with a mean Pd particle size of 2.8 nm. After characteri...