DEUTERATION

作品数：23被引量：17H指数：3
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Selective and Scalable Deuteration of Heteroarenes Using Nickel-Based Nanoparticles
《Chinese Journal of Chemistry》2024年第23期2993-2998,共6页Feiyu Qiu Lingyun Yang Yuan Gao Jiapei Yang Aiwen Lei Wu Li 
support from the National Key R&D Program of China(No.2021YFA1500100,A.L.);National Natural Science Foundation of China(22031008,A.L.;212200007,W.L.);Science Foundation of Wuhan(2020010601012192,A.L.).
Deuterium labelling possesses wide applications in pharmaceuticals,chemical science and materials science.Development of efficient methodologies for the synthesis of deuterium labelled compounds,especially hydrogen is...
关键词：DEUTERATION HETEROARENES NICKEL NANOPARTICLES PYRIDINE 
Recent Advances in Deuteration Reactions
《Chinese Journal of Chemistry》2024年第10期1145-1156,共12页Hao Li Muhammad Shabbir Wu Li Aiwen Lei 
the National Key R&D Program of China(No.2021YFA1500100,A.L.);National Natural Science Foundation of China(22031008,A.L.;212200007,W.L.);Science Foundation of Wuhan(2020010601012192,A.L.).
The deuteration of organic compounds has attracted more attentions in recent years for the potential applications in new drug discovery and synthetic chemistry.For this purpose,many efficient deuterium labeling method...
关键词：Deuterated compounds H/D exchange Reductive deuterations Dehalogenative deuterations DEUTERIUM C-Hactivation Synthetic methods 
Deuteration removes quantum dipolar defects from KDP crystals
《npj Computational Materials》2024年第1期684-693,共10页Bingjia Yang Pinchen Xie Roberto Car 
Dielectric properties of the hydrogen-bonded ferroelectric crystal KH_(2)PO_(4)(KDP)differ significantly from those of KD_(2)PO_(4)(DKDP).It is well established that deuteration affects the interplay of hydrogenbond s...
关键词：QUANTUM KDP REMOVE 
Transition metal-free photocatalytic reductive deuteration of ketone derivatives
《Green Synthesis and Catalysis》2023年第3期253-257,共5页Jiaxin Cai Yanjun Li Ziqi Ye Wenqian Wang Yu Mei Lin Lei Gong 
support from the National Natural Science Foundation of China(Nos.22071209 and 22071206);the national youth talent support program,and the Fundamental Research Funds for the Central Universities(No.20720190048).
Deuterium labelling techniques have shown widespread applications in organic synthesis,analytic chemistry,life science and material science.The design of practical deuteration reactions which is environmentally friend...
关键词：DEUTERATION PHOTOREDOX ORGANOCATALYSIS Visible light α-Deuterated alcohols 
Solvent-free mechanochemical synthesis of organic proton conducting salts incorporating imidazole and dicarboxylic acids
《Chinese Journal of Structural Chemistry》2023年第5期22-26,共5页Yating Zhou Anucha Koedtruad Zhenhong Tan Dong Zhang Lingxiang Bao Yajun Yue Jianyuan Wu Juping Xu Yuanguang Xia Wen Yin Maxim Avdeev Wang Hay Kan Takashi Kamiyama Ping Miao 
support of the National Natural Science Foundation of China(No.12005243,22205239,U1930102 and 11805034);Guangdong Basic and Applied Basic Research Foundation(No.2022B1515120014 and 2022A1515110210);China Postdoctoral Science Foundation(No.2022M721906 and 2022M721909);The neutron diffraction experiments were carried out under the fast-track proposal at Australian Nuclear Science and Technology Organisation(ANSTO)and the general user program(No.P1622061700003)at China Spallation Neutron Source(CSNS).
Solventless mechanochemical synthesis by manual grinding was applied to grow organic proton conducting salts,imidazole-succinic acid(C_(3)H_(4)N_(2)-HOOC(CH_(2))_(2)COOH)and imidazole-glutaric acid(C_(3)H_(4)N_(2)-HOO...
关键词：Organic salts Proton conducting MECHANOCHEMISTRY Powder neutron diffraction Solventless synthesis DEUTERATION 
Visible Light Promoted Direct Deuteration of Alkenes via Co(III)–H Mediated H/D Exchange被引量：1
《CCS Chemistry》2023年第5期1069-1076,共8页Zongbin Jia Sanzhong Luo 
the Natural Science Foundation of China(grant nos.91956000,22031006,21861132003),Tsinghua University Initiative Scientific Research Program,and Haihe Laboratory of Sustainable Chemical Transformations for financial support.
We report herein a visible light-mediated direct deuteration of alkenes with D_(2)O or deuterated methanol(MeOD)using a cobaloxime as a hydrogen/deuterium(H/D)exchange catalyst.The synergistic photoredox/Co catalysis ...
关键词：DEUTERATION COBALOXIME hydrogen isotope exchange alkyl cobalt PHOTOREDOX 
Highly efficient electrocatalytic deuteration of acetylene to deuterated ethylene using deuterium oxide
《Chinese Chemical Letters》2023年第5期302-305,共4页Siyu Chang Jun Bu Jinjin Li Jin Lin Zhenpeng Liu Wenxiu Ma Jian Zhang 
supported by the Natural Science Foundation of Shaanxi Province(No.2020JQ-141);the National Natural Science Foundation of China(No.22005245);the Synergy Innovation Foundation of the University and Enterprise for Graduate Students in Northwestern Polytechnical University(No.CX2021037);the National Key Research and Development Program of China(No.SQ2021YFE010191)。
Deuterated ethylene is an important building block for manufacturing various deuterated polyolefins and chemicals.However,low-cost and large-scale production of deuterated ethylene still remain a great challenge.Herei...
关键词：ELECTROCATALYSIS DEUTERATION ACETYLENE Deuterated ethylene Deuterium oxide 
Site-directed deuteration of dronedarone preserves cytochrome P4502J2 activity and mitigates its cardiac adverse effects in canine arrhythmic hearts被引量：2
《Acta Pharmaceutica Sinica B》2022年第10期3905-3923,共19页Aneesh V.Karkhanis Gopalakrishnan Venkatesan Ryuichi Kambayashi Jacqueline Wen Hui Leow Marcus Qingrui Han Hiroko Izumi-Nakaseko Ai Goto Jeremy Kah Sheng Pang Boon Seng Soh Pipin Kojodjojo Atsushi Sugiyama Eric Chun Yong Chan 
supported by the National University Heart Centre Singapore (NUHCS) Cardiovascular Research Institute (CVRI)Core Fund [Grant NUHSRO/2019/082/Core];SCEPTRE CG Seed Grant [Grant NMRC/CG/M008/2017, Singapore];Singapore Ministry of Education Tier 1 Academic Research Funding [Grant R-148-000-193-112];the National University of Singapore, Department of Pharmacy, Final Year Project Funding [Grant C148-000-003-001] provided to Eric Chun Yong Chan;from Japan Society for the Promotion of Science (JSPS) KAKENHI [grant number 20K16136] provided to Ryuichi Kambayashi
Cytochrome P4502J2(CYP2J2)metabolizes arachidonic acid(AA)to cardioprotective epoxyeicosatrienoic acids(EETs).Dronedarone,an antiarrhythmic drug prescribed for treatment of atrial fibrillation(AF)induces cardiac adver...
关键词：Arachidonic acid Atrial fibrillation CYP2J2 Drug-induced proarrhythmia Epoxyeicosatrienoic acids Mechanism-based inactivation DRONEDARONE 
Deuterated N-difluoromethylthiophthalimide:A stable,scalable reagent for radical and electrophilic deuteriodifluoromethylthiolations
《Chinese Chemical Letters》2022年第9期4293-4297,共5页Chunyang Hu Fangming Chen Guo-Ping Lu Wen-Bin Yi 
the National Natural Science Foundation of China (Nos. 21776138, 22078161);the Fundamental Research Funds for the Central Universities (Nos. 30920021124, 30918011314);the Natural Science Foundation of Jiangsu Province (No. BK20180476);the Postdoctoral Science Foundation Funded Project (No. 2019M661848);the Priority Academic Program Development of Jiangsu Higher Education Institutions;the Center for Advanced Materials and Technology in Nanjing University of Science and Technology for their financial support
A new,stable and scalable reagent for deuteriodifluoromethylthiolation(deuterated N-difluoromethylthiophthalimide,PhthSCF_(2)D)has been developed.This reagent can be applied for the photocatalytic radical deuteriodifl...
关键词：DEUTERATION Deuteriodifluoromethylthiolation PHOTOCATALYTIC ELECTROPHILIC RADICAL 
Photo‐and electro‐catalytic deuteration of feedstock chemicals and pharmaceuticals:A review被引量：3
《Chinese Journal of Catalysis》2022年第4期956-970,共15页Wei Ou Chuntian Qiu Chenliang Su 
国家自然科学基金(21972094,21902105);广东省特支计划人才项目;鹏城学者人才项目;深圳市科技计划(RCJC20200714114434086,JCYJ20190808142001745,JCYJ20200812160737002,KQTD2016053112042971);广东省基础与应用基础研究基金(2020A1515010471);广东省普通高校青年创新人才项目(2018KQNCX221).
Deuterium labeling techniques are widely utilized as efficient tools to study the absorption,distribution,metabolism,and excretion(ADME)of pharmaceuticals.Moreover,deuterium‐labeled drugs are expected to prolong the ...
关键词：PHOTOCATALYSIS ELECTROCATALYSIS Deuterium‐labelled drugs H/D atom transfer Single electron transfer 
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