support from the National Key R&D Program of China(No.2021YFA1500100,A.L.);National Natural Science Foundation of China(22031008,A.L.;212200007,W.L.);Science Foundation of Wuhan(2020010601012192,A.L.).
Deuterium labelling possesses wide applications in pharmaceuticals,chemical science and materials science.Development of efficient methodologies for the synthesis of deuterium labelled compounds,especially hydrogen is...
supported by the Open Funds of the State Key Laboratory of Rare Earth Resource Utilization,China (No.RERU2023006).
The laboratory-abundant and low-toxic ethyl acetate was explored successfully for the first time as acyl group donor for the Minisci-type acylation of quinolines.In this approach,TBAC/K_(2)S_(2)O_(8) (TBAC: tert-butyl...
financial support from the National Natural Science Foundation of China (grant no.22201121);Jiangxi Provincial Natural Science Foundation (grant nos.20224BAB213006 and 20232BAB203002).
The site-selective C-H fluorination of heteroarenes is a straightforward approach to accessing valuable heteroaryl fluorides but remains a formidable challenge.Herein,we report a general strategy for visible-light-ind...
the National Key R&D Program of China(grant no.2021YFF0701600);the National Natural Science Foundation of China(grant no.22225103);Shanghai Key Laboratory for Molecular Engineering of Chiral Drugs,Shanghai Jiao Tong University,and the China Postdoctoral Science Foundation(grant nos.2020M680021 and 2021T140366),which was greatly appreciated.
Selective reduction of readily available N-heteroarenes is important in both organic synthesis and chemical biology.Herein,we describe ligand-controlled regiodivergent hydroboration of quinolines using well-defined am...
support of the National Natural Science Foundation of China(grant no.21971071);the Natural Science Foundation of Guangdong Province(grant no.2021A1515010155).
Despite their interesting applications,direct and diverse syntheses of aryl-fused 2-alkyl cyclic amines still remain challenging.Here,the concept of incorporating a C–C coupling process into the N-heteroaryl reductio...
National Key R&D Program of China(Grant no.2021YFA1500200);the National Natural Science Foundation of China(Nos.92256303,92056108 and 21871270)for financial support.
Chiral ruthenium-catalyzed enantioselective hydrogenation of tetrapyridine-type N-heteroarenes was firstly developed.The partial reduction of adjacent tetraheteroaromatic substrates proceeded smoothly in the presence ...
the Natural Science Foundation of Zhejiang Province(LQ22B020005,LZ22B020003);the National Natural Science Foundation of China(22101201,22071171)for financial support of this work.
A photoelectrochemical approach for the C-H silylation of heteroarenes through dehydrogenation cross-coupling with H2 evolution has been developed.The photoelectrochemical C-H silylation depends on hydrogen atom trans...
supported by the National Natural Science Foundation of China(22071186,22071187,22073067,22101216,22271226,21933003,22193020,22193023);the National Youth Talent Support Program;the Natural Science Foundation of Hubei Province(2020CFA0362021CFA069);the Fundamental Research Funds for the Central Universities(2042022kf1180,2042022kf1040);the Shenzhen Nobel Prize Scientists Laboratory Project(C17783101);the Guangdong Provincial Key Laboratory of Catalytic Chemistry(2020B121201002)。
Copper-catalyzed asymmetric 1,3-dipolar cycloaddition of azomethine ylides andβ-trifluoromethyl-substituted alkenyl heteroarenes was developed for the first time.A wide range of enantioenriched pyrrolidines containin...
the financial support from the National Natural Science Foundation of China (Nos. 22022102 and 22071010);the financial support from China Postdoctoral Science Foundation (No. 2021M700462)。
We report two air-stable nickel(II) half-sandwich complexes,Cp*Ni(1,2-Cy_(2)PC_(6)H_(4)O)(1) and Cp*Ni(1,2-Ph_(2)PC_(6)H4NH)(2),for cooperative B-H bond activation and their applications in catalytic hydroboration of ...
the NRF Investigatorship Award(A-0004067-00-02);the Ministry of Education(MOE)of Singapore(A-0008481-00-00)for generous financial support.
Asymmetric dearomatization reactions of various electron-deficient heteroarenes,including benzofurans,benzothiophenes,and indoles,have been described.Through a phosphine-catalyzed[3+2]annulation with vinylcyclopropane...