This research was financially supported by the National Natural Science Foundation of China(Nos.22167010 and 81991521);the National Key Research and Development Program of China(No.2022YFC2804100);the Natural Science Foundation of the Higher Education Institutions of Jiangsu Province(No.23KJB350011);the Shandong Laboratory Program(SYS202205);the Basic Research Project of Guizhou University(No.2023-51).
A detailed chemical investigation of the Hainan soft coral Lobophytum crassum led to the identification of a class of polyoxygenated cembrane-type macrocyclic diterpenes(1-28),including three new flexible cembranoids,...
We thank the Natural Science Foundation of Tianjin City(20JCYBJC00330)for financial support.
pH is an important stimuli-responsive signal because deprotonation-protonation process is crucial for many life functions.Photoacid is a kind of photoresponsive group that can release protons upon irradiation.This pro...
supported by National Natural Science Foundation of China(No.81973166);Science and Technology Commission of Shanghai Municipality(No.22XD1424600);Natural Science Foundation of Shanghai Municipality(No.22ZR1474100);Taishan Scholar Foundation of Shandong Province(No.tsqn202306322);National Key R&D Program of China(No.2021YFC2300700);Shandong Laboratory Program(No.SYS202205);Shandong Provincial Natural Science Foundation(Nos.ZR2023LSW003 and ZR2023JQ028)。
The development of enantioselective C-H macrocyclizations to efficiently access structurally diversified macrocycles is highly desirable,but remain a big challenge.Herein,we reported the first rhodium(Ⅲ)-catalyzed as...
supported by the JST START(JPMJSF2303);JSPS KAKENHI(JP23H00304,JP22KF0295,JP23KJ1717);Kyushu University Platform of Inter-/Transdisciplinary Energy Research(Q-PIT)through its“Module-Research Program”;Kyushu University Integrated Initiative for Designing Future Society.
The integration of multiple chromophore units into a single molecule is expected to improve the performance of photon upconversion based on triplet−triplet annihilation(TTA-UC)that can convert low energy photons to hi...
supported by the National Natural Science Foundation of China(No.82173713);the Natural Science Foundation of Hunan Province(Nos.2021JJ41000 and2021JJ40812);the Key Research and Development Program of Hunan Province(No.2022SK2031);the Project of Hunan Administration of Traditional Chinese Medicine(No.B2023059);the Postgraduate Scientific Research Innovation Project of Hunan Province(No.CX20230323)。
Four novel macrocyclic trichothecenes,termed mytoxins D-G(1-4),along with four known analogs(5-8),were isolated from the ethyl acetate extract of fermented rice inoculated with the fungus Myrothecium verrucaria PA57.E...
supported by the National Natural Science Foundation of China(NSFC,Nos.22065031,22061039,22001214,22165027);the top-notch talent project in Gansu province,the Key R&D Program of Gansu Province(No.21YF5GA066);Gansu Province College Industry Support Plan Project(No.2022CYZC-18);Natural Science Foundation of Gansu Province(Nos.2020–0405-JCC-630,20JR10RA088);The star of innovation(No.2023CXZX244)。
Improving the highly selective and sensitive binding of chemosensor to target guest is always very challenging.In order to solve this issue,herein,the enrichment effect was introduced into the design of chemosensor mo...
The authors acknowledge that this work was partly supported by the National Natural Science Foundation of China(82122065 and 82073698 to G.B.L.);the Sichuan Science and Technology Program(2022YFH0027 to G.B.L.).
Recently,two companion papers published in Nature reported a first-in-class tethered macrocyclic peptide antibiotic targeting carbapenem-resistant A.baumannii(CRAB)and unveiled their unique antibacterial mechanism,whi...
the China Postdoc Council(OCPC)for the financial support of Postdoctoral International Exchange Program(No.YJ20210095);the financial support from the National Natural Science Foundation of China(No.22078150);National Key R&D Program of China(No.2021YFC2101904);the Jiangsu National Synergetic Innovation Center for Advanced Materials(SICAM);the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD),the Jiangsu Synergetic Innovation Center for Advanced Bio-Manufacture(No.XTB2201);the Top-Notch Academic Programs Project of Jiangsu Higher Education Institutions(TAPP)。
The innovation in polymer design to rival conventional polyethylene glycol(PEG)is an important approach to achieving a more sustainable society.Here,cyclic PEG-like polycarbonates having high molecular weight(4.4–49....
o National Natural Science Foundation of China(No.22178263);Natural Science Foundation of Tianjin City(No.22JCQNJC00770);Haihe Laboratory of Sustainable Chemical Transformations.The authors also thank Mr.Ben Parks from the Southern Illinois University Carbondale for proofreading the manuscript.
Organic long-persistent luminescence(LPL)materials,featuring low preparation cost,eco-friendly synthesis,and easy modification of functional groups,have exhibited extensive applications in information encryption,anti-...
In the last few decades,there has been a rapid emergence and growing interest in synthetic macrocyclic arenes,such as calixarenes[1,2],cyclophanes[3],cyclotriveratrylenes[4],pillararenes[5-7],and other novel macrocycl...