the Scientific Research Foundation of Yancheng Institute of Technology(No.1542036);the National Natural Science Foundation of China for financial support(No.NSFC-21472018);the National Science Foundation(NSF,Grant No.CHE-1401700);the Open Fund of Jiangsu Collaborative Innovation Center for Ecological Building Material and Environmental Protection Equipments and Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province(No.JH201832);the Funding for School-Level Research Projects of Yancheng Institute of Technology(No.xjr2020011).
Main observation and conclusion We have developed an efficient synthesis of acrylonitriles via mild base promoted tandem nucleophilic substitution-isomerization ofα-cyanohydrin methanesulfonates with alkenylboronic a...
Water-promoted sulfonylation of propargyl esters leading to highly regioselective and stereoselective formation of (Z)-β-sulfonyl enoates in excellent yields, by a simple, mild, rapid and environmentally benign rea...
We thank the support of National Natural Science Foundation of China (Grant 21302224, 51172285, 21176259, 51303212, 51303202), China Postdoctoral Science Foundation (2014M560590, 2015T80758), Fundamental Research Funds for the Central Universities (15CX05010A), Shandong Provincial Natural Science Foundation (ZR2013BQ028, ZR2013EMQ013), Project of Science and Technology Program for Basic Research of Qingdao (14-2-4-47-jch) and the State Key Laboratory of Fine Chemicals (KF 1203).
Photoinduced electron transfer process is a crucial step in photooxidation to obtain synthetic chemicals. How- ever, the driving forces of electron transfer as priority in all have been rarely studied in stepwise deta...
Ketones and β-diketones were nitrosated and converted to their corresponding aoximinoketones using task-specific ionic liquids, l-(4-nitritobutyl)-3-methylimidazolium chloride, IL-ONO, and 1-butyl-3-methylimidazoli...
Project supported by the National Natural Science Foundation of China (No. 20602011), New Century Excellent Talents in University, the Ministry of Education, China (No. NCET-07-0283), and ‘111' Project (No. B07023).
BF3·OEte (Boron trifluoride etherate), an inexpensive and commercially easily available Lewis acid stoichiometrically employed for Beckamann rearrangement in general, was now found to efficiently catalyze Beckmann ...
A mixture of ammonium nitrate or nitro urea and silica sulfuric acid was found to be efficient and environmentally friendly nitrating media for the preparation of orto-nitro phenols in dichloromethane at room temperat...
Project supported by the National Natural Science Foundation of China (No. 20671002) and Science and Technological Fund of Anhui Province for Outstanding Youth (No. 08040106834).
Zn(OH)F microbesoms have been synthesized on a large scale by a facile solution-based method using polymer as crystal growth modifier. The obtained products were characterized by X-ray powder diffraction (XRD), X-...
ZrOCl2 was found to be an effective Lewis acid catalyst for the solventless chemoselective conversion of aldehydes into geminal-diacetates in high yields at room temperature. Regeneration of the aldehydes from the ace...
Project supported by the National Natural Science Foundation of China (Nos. 20332020, 20472079).
In this article, a general, simple, and inexpensive catalyst system was developed for the amidation of aryl bromide by using CuI as catalyst, amino acid as ligand, and K3PO4 as base.
Project supported by the National Natural Science Foundation of China (Nos. 20172039, 20472062) and Jiangsu Provincial Key Laboratory of Fine Petrochemical Technology (No. KF0402).
A one-pot synthesis of a series of 5-oxo-5,6,7,8-tetrahydro-4H-benzo-[b]-pyran derivatives via three-component coupling reactions of aldehydes, dimedone and malononitrilein room temperature ionic liquids (RTILs) wit...