This work was supported by the National Natural Science Foundation of China (No.21173158 and No.21373152) and the Ministry of Science and Tech- nology of China (No.2012YQ220113-7).
The reaction of laser-ablated vanadium, niobium and tantalum atoms with hydrogen sulfide has been investigated using matrix isolation FTIR and theoretical calculations. The metal atoms inserted into the H-S bond of H2...