the National Natural Science Foundation of China (20925104,90713023,20771055,20721002);the Major State Basic Research Development Program of China (2006CB806104);the National Basic Research Program of China (2007CB925101,2010CB923303)
The reaction of the 16e half-sandwich complex Cp*Co(S2C2B10H10) (1) (Cp* = pentamethylcyclopentadienyl) with excess methyl acetylene monocarboxylate, HC≡C-CO2Me, affords the 18e complexes 2-6. Compound 2 bears a B-CH...
supported by the National Natural Science Foundation of China (90922006);Natural Science Foundation of Jiangsu Province (BK2009009);NSFC for Creative Research Group (20721002)
The reactions of 6-phosphononicotinic acid (pnaH3) and metal salts result in three new compounds, namely, M(pnaH)-(H2O)3·H2O [M = Co(Ⅱ) (1), Ni(Ⅱ) (2), Zn(Ⅱ) (3)]. These compounds are isostructural and contain 21 ...
supported by the National Natural Science Foundation of China (20731004 and 20721002);the National Basic Research Program of China (2007CB925103 and 2010CB923303)
Three novel coordination polymers, [Ni2(tib)2(btec)]·2H2O (1), [Co2(tib)2(btec)]·2H2O (2) and [Zn4(tib)2(btec)Cl4]·2H2O (3), have been synthesized by using mixed ligands of 1,3,5-tris(1-imidazolyl)benzene (tib) and...
Supported by the National Natural Science Foundation of China (Nos. 20971065, 20721002);National Basic Research Program of China (2007CB925103,2010CB923303)
Four cobalt supramolecular architectures with Hmtyaa(2-(5-methyl-1,3,4-thiadiazol-2-ylthio)acetic acid) ligand have been synthesized.[Co(mtyaa)2(H2O)4]·4(H2O)(1):triclinic,space group P1 with a = 6.7537...
Project supported by the National Natural Science Foundation of China (20701019, 20971067, 20721002);the Natural Science Foundation of Ji-angsu Province (BK2008257);the Major State Basic Research Development Program (2006CB806104, 2007CB925103)
Several dinuclear lanthanide complexes of Ln2(HTH)6TPPHZ (Ln=Eu, Sm, Er, Nd, Yb, Ho; TPPHZ=Tetrapyrido (3,2-a:2’,3’-c:3’,2'-h:2'’,3’'-j) phenazine; HTH=4,5,5,6,6,6-heptafluroro-1-(2-thienyl)hexane-1,3-dione were ...