National Natural Science Foundation of China(22271161,22188101);the Tianjin Science Fund for Distinguished Young Scholars(23JCJQJC00180);the Fundamental Research Funds for the Central Universities(63233165,63243134);Nankai University,for financial support.
Vicinal stereogenic centers are ubiquitous structural scaffolds in both natural products and synthetic compounds,yet their enantioselective construction remains a significant challenge in organic synthesis.Organoboron...
Project supported by the National Key Research and Development Program of China (Grant No.2022YFB3605403);the National Natural Science Foundation of China (Grant Nos.62234007,62241407,62293521,62304238,62241407,U21A20503,and U21A2071);the Key-Area Research and Development Program of Guangdong Province,China (Grant No.2020B010174002);the Cultivation Project for Youth Teachers in Jiangsu Province;Jiangsu Funding Program for Excellent Postdoctoral Talent。
Controlling the epitaxial growth mode of semiconductor layers is crucial for optimizing material properties and device performance.In this work,the growth mode ofα-Ga_(2)O_(3) heteroepitaxial layers was modulated by ...
the financial support from the National Natural Science Foundation of China(No.22271302);the Science and Technology Commission of Shanghai Municipality(Nos.20JC1417100 and 21XD1424800);CAS Key Laboratory of Synthetic Chemistry of Natural Substances;Shanghai Institute of Organic Chemistry。
A copper(Ⅰ)-catalyzed diastereodivergent addition of phosphinothioates(HP(S)ROR')toα,β-unsaturated thioamides is disclosed,which constructs vicinal P-chiral and C-chiral centers in generally high diastereoand enant...
supported by the National Natural Science Foundation of China(32270165 and 31872921);in part by China Agricultural Industry Technology System(Grant No.CARS-170304).
Vicinal oxygen chelate(VOC)proteins are members of an enzyme superfamily with dioxygenase or non-dioxygenase activities.However,the biological functions of VOC proteins in plants are poorly understood.Here,we show tha...
the National Natural Science Foundation of China(Nos.21702175,21961037,22061040 and 22161044);the Program for Tianshan Innovative Research Team of Xinjiang Uygur Autonomous Region(No.2021D14011);the Natural Science Foundation of Xinjiang Uygur Autonomous Region(No.2020D01C077)for support of this research.
An unprecedented electrochemical oxidative trifunctionalization of olefins with diaryl disulfides/aryl thiols and N-chlorosuccinimide in an aqueous system is developed.Two C-Cl bonds,one C-S bond,and one S=O bond are ...
Financial support was provided by the National Natural Science Foundation of China(22231002 and 21871095);the Key-Area Research and Development Program of Guangdong Province(2020B010188001).
Palladium-catalyzed regioselective amination of unactivated alkene remains a challenge and is of great interest.Herein,a three-component coupling of unactivated alkene,sulfonamide,and N-halo compounds accessing vicina...
The authors are grateful for the financial support provided by the National Natural Science Foundation of China(No.22001203);the startup funds from Xi'an Jiaotong University.The authors thank Dr.Lu Bai and Ms.Chao Feng from the Instrument Analysis Center of Xi'an Jiaotong University for their assistance with HRMS and NMR analysis.
A novel,efficient and pragmatic method to prepare gem-diboron products with vicinal tertiary/quaternary stereocenters using LiTMP-mediated 1,6-conjugate addition of gem-diborylalkanes to para-quinone methides was desc...
supported by the National Natural Science Foundation of China(21632003,21871116,22071085,U22A20390);the Fundamental Research Funds for the Central Universities(lzujbky-2023-stlt01);the 111 Program from the Ministry of Education of China。
An asymmetric catalytic strategy in photocatalysis utilizing a chirality-induced approach through an organocatalytic/photoredox relay catalysis strategy is successfully achieved for the rapid construction of polycycli...
National Natural Science Foundation of China(Nos.21977082,22037002 and 21472148);the Natural Science Basic Research Program of Shaanxi(No.2020JC-38).
We here present a Förster resonance energy transfer(FRET)-based and environment-sensitive fluorescent probe VG-1 for vicinal-dithiol-containing proteins(VDPS).VG-1 uniquely contalns two sites sensitive to the protein ...
partially supported by the National Natural Sci-ence Foundation of China(Grants No.61734001,61774004 and 61904002);the Beijing Outstanding Young Scientist Program(Grant No.BJJWZYJH0120191000103);the Science Challenge Project(Grant No.TZ2018003).
Near-infrared stimulated emission from a high-quality InN layer under optical pumping was observed with a threshold excitation power density of 0.3 and 4 kW cm^(−2) at T=8 and 77 K,respectively.To achieve such a low t...