METALLACYCLE

作品数：25被引量：21H指数：3
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相关领域：理学更多>>
相关作者：张弘更多>>
相关机构：厦门大学更多>>
相关期刊：《Science China Chemistry》《Science China Materials》《Aggregate》《Chinese Journal of Chemistry》更多>>
相关基金：国家自然科学基金上海市浦江人才计划项目福建省自然科学基金河南省自然科学基金更多>>
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An NIR-Ⅱ-emissive Ru(Ⅱ)metallacycle for efficient and safe immunotherapy
《Science China Chemistry》2025年第1期5-7,共3页Chonglu Li Jianbo Zhan Biao Dong 
Immunotherapy,as a groundbreaking cancer treatment,has gained considerable attention for its utilization of the body’s immune system to combat tumors^([1]).This therapy induces tumor cell apoptosis,triggering a susta...
关键词：SUSTAINED METASTASIS thereby 
Carbonylation Reactions of a Metallapentalyne:Synthesis of Its Ester and Amide Derivatives
《Chinese Journal of Chemistry》2024年第22期2765-2772,共8页Yongfa Zhu Dafa Chen Ming Luo Haiping Xia 
supported by the National Natural Science Foundation of China(Nos.92156021,22350009,22101115 and 22371111);Financial Support for Outstanding Talents Training Fund in Shenzhen,the Guangdong Provincial Key Laboratory of Catalysis(No.2020B121201002);high level of special funds(G03050k003);Introduction of Major Talent Projects in Guangdong Province(No.2019CX01C079).
Carbonylation reactions are a valuable synthetic method to construct carbonyl compounds and carbonylation reactions of aryl halides stand out as a highly significant tool for generating carbonyl substituted arenes.How...
关键词：Carbonylation reactions Metal carbyne AROMATICITY Carbon monoxide METALLACYCLE 
A lysosomal-targeted Pt(Ⅱ) metallacycle for NIR-Ⅱ fluorescence imaging guided highly efficient tumor immunogenic cell death
《Science China Chemistry》2024年第11期3508-3509,共2页Qihang Ding Shuai Zhang Jong Seung Kim 
Cisplatin, carboplatin, and oxaliplatin are well-known firstline antineoplastic drugs that have been approved worldwide. Recently, the successful integration of chemotherapy and immunotherapy in clinical trials has hi...
关键词：drugs chemotherapy CISPLATIN DEATH 
A supramolecular oligo[2]rotaxane constructed by orthogonal platinum(Ⅱ) metallacycle and pillar[5]arene-based host–guest interactions
《Chinese Chemical Letters》2024年第10期201-204,共4页Bingbing Shi Yuchun Wang Yi Zhou Xing-Xing Zhao Yizhou Li Nuoqian Yan Wen-Juan Qu Qi Lin Tai-Bao Wei 
financially supported by the National Natural Science Foundation of China(Nos.22001214,21662031,21661028,22061039);the Science Fund for Distinguished Young Scholars of Gansu Province(No.22JR5RA131);the Longyuan Innovation and Entrepreneurship Talent Project of Gansu Province;the Major Project Cultivation Program of Northwest Normal University(No.NWNU-LKZD2022-01);the Top Leading Talents Project of Gansu Province,the Key R&D Program of Gansu Province(No.21YF5GA066);Gansu Province College Industry Support Plan Project(No.2022CYZC-18)。
Oligo[n]rotaxanes are one of the most extensively studied categories of mechanically bonded macromolecules.In this study,a supramolecular oligo[2]rotaxane is successfully constructed driven by platinum(Ⅱ)metallacycle...
关键词：arene METALLACYCLES Host-guest interactions Light-harvesting system Mechanically interlocked molecules 
NIR emissive Ru(Ⅱ)metallacycle as a sonosensitizer/sonocatalyst assisting in vivo bacterial diagnosis and eradicating multidrug-resistant biofilms
《Science China Chemistry》2024年第9期2785-2786,共2页Chonglu Li Qihang Ding Jong Seung Kim 
Microbial biofilm-related infections present a significant global health challenge,posing a major threat to public health systems[1].Biofilms,complex structures formed by the aggregation of microorganisms,are commonly...
关键词：DIAGNOSIS dic RENDERING 
Reversibly sensitizing-storing-releasing ^(1)O_(2) within a single platinum(Ⅱ)-acetylide-based metallacycle molecule via laser power modulation
《Science China Chemistry》2024年第2期604-611,共8页Ruyi Zhou Wen Lv Bo Li Bo Yu Sudi Zhang Yucheng Zhou Shujuan Liu Qiang Zhao 
supported by the National Natural Science Foundation of China (22075148,22161160318);the Natural Science Foundation of Jiangsu Higher Education Institutions of China(21KJB150013);the Youth Fund Project of Jiangsu Natural Science Foundation (BK20210583)。
Tumor hypoxia severely limits the therapeutic efficacy of photodynamic therapy(PDT) for solid tumors,which is highly dependent on tissue oxygen concentration.In this study,we developed a platinum(Ⅱ)-acetylide-based m...
关键词：METALLACYCLES singlet oxygen ENDOPEROXIDES near-infrared absorption synergistic treatment 
Trefoil-shaped metallacycle and metallacage via heteroleptic self-assembly
《Chinese Chemical Letters》2023年第12期209-214,共6页Zhilong Jiang He Zhao Jun Wang Bangtang Chen Wenzhi Lv Yiming Li Qiangqiang Dong Die Liu Weiya Liu Min Wang Fan Fu Seok-Ho Hwang Mingzhao Chen Pingshan Wang 
supported by the National Natural Science Foundation of China(Nos.22101060 for M.C.,and 21971257 for P.w.);the Guangdong Natural Science Foundation(No.2022A1515012187 to M.C.);the Science and Technology Research Project of Guangzhou(Nos.202201020201 for M.C.and 202102010432 for ZJ..Science and technology support plan of Guizhou Province[2019]2860 for W.L.The authors gratefully acknowledge the Center for Advanced Research in CSU for the NMR measurements.
Template-oriented multi-component synthesis method has been proven to be an exceedingly reasonable and excellent method for the synthesis of giant two-dimensional(2D)and three-dimensional(3D)supramolecules,but designi...
关键词：Supramolecular coordination complex ‘Mitsubishi'molecule Trefoil-shaped metallacage Heteroleptic self-assembly TERPYRIDINE 
Formal[2+1]Cycloadditions of a Metallacyclopentadiene Unit with Alkynes:Constructing Tetracyclic Conjugated Frameworks with Bridgehead Metals被引量：2
《Chinese Journal of Chemistry》2023年第16期1987-1993,共7页Zhenwei Chu Jinhua Li Dafa Chen Zhengyu Lu Weiran Meng Ming Luo Haiping Xia 
the National Natural Science Foundation of China(Nos.21931002,22071098,22101115,and 22101123);the Shenzhen Science and Technology Innovation Committee(Nos.JCYJ20200109140812302 and JCYJ20210324105013035);the Guangdong Provincial Key Laboratory of Catalysis(No.2020B121201002)。
Comprehensive Summary Metallacyclopentadienes play a vital role in transition-metal mediated and catalyzed cycloaddition reactions of alkynes.Though versatile reactions of metallacyclopentadienes with alkynes have bee...
关键词：METALLACYCLE CYCLOADDITION ALKYNES Electrophilic substitution CONJUGATION 
Visualization of supramolecular assembly by aggregation-induced emission被引量：1
《Aggregate》2023年第2期102-122,共21页Wu-Jie Guo Tuokai Peng Wenping Zhu Shixiang Ma Guang Wang Ying Li Bin Liu Hui-Qing Peng 
National Natural Science Foundation of China,Grant/Award Numbers:22105016,22005195,52002015,22275010;Ministry of Science and Technology of China,Grant/Award Number:2022YFA1505900;Open Fund of Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates,South China University of Technology,Grant/Award Number:2019B030301003;Fundamental Research Funds for the Central Universities,Grant/Award Number:buctrc202006。
Supramolecular architectures are constructed by the self-assembly of small building blocks via the use of metal-ligand coordination,π–πstacking interactions,hydrogen bonding,host-guest interactions,and other noncov...
关键词：aggregation-induced emission metallacycles/cages micelles/vesicles supramolecular gels supramolecular polymers VISUALIZATION 
Construction of a 980 nm laser-activated Pt(Ⅱ)metallacycle nanosystem for efficient and safe photo-induced bacteria sterilization被引量：1
《Science China Chemistry》2023年第1期155-163,共9页Yuling Xu Chonglu Li Jusung An Xin Ma Jingfang Yang Lishi Luo Yun Deng Jong Seung Kim Yao Sun 
supported by National Natural Science Foundation of China(22022404,22074050,21904103);the Fundamental Research Funds for the Central Universities(CCNU22QN007);the Open Research Fund of State Key Laboratory of Chemo/Biosensing and Chemometrics(2021005);the Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules Hubei University(KLSAOFM2111);the Opening Project of Key Laboratory of Optoelectronic Chemical Materials and Devices of Ministry of Education,Jianghan University(JDGD-202209);the Open Project Program of Key Laboratory for Analytical Science of Food Safety and Biology,Ministry of Education(FS2202);supported by the CRI project of National Research Foundation of Republic of Korea(2018R1A3B1052702,JSK)。
Although metal-based chemical agents have demonstrated promising bacteriostatic effects in phototherapy,their short excitation/emission wavelengths and inadequate phototherapy efficiencies make their application in vi...
关键词：supramolecular chemistry METALLACYCLE NIR-Ⅱfluorescence imaging phototheranostics deep penetration 
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