support of the National Natural Science Foundation of China (Nos.22271201,92056116,22171194,22201194);the Science & Technology Department of Sichuan Province (Nos.2022YFH0095 and 2021ZYD0052);the Fundamental Research Funds for the Central Universities (No.20826041D4117)。
A series of novel crown aldoxime ethers were synthesized,demonstrating notable thermal and hydrolysis stability.The showcased acid-catalyzed and photo-induced cis/trans isomerization,which enables orthogonal control o...
Chiral compounds play a crucial role in the development of pharmaceuticals,pesticides,fragrances,and materials due to their unique stereochemical configurations.Asymmetric catalysis,which employs chiral catalysts to f...
supported by the KRISS(Korea Research Institute of Standards and Science)MPI Lab.program。
The increasing demand for hydrogen energy to address environmental issues and achieve carbon neutrality has elevated interest in green hydrogen production,which does not rely on fossil fuels.Among various hydrogen pro...
support from the National Key R&D Program of China (2022YFA1503703,2021YFF0701604);the National Natural Science Foundation of China (21825105,22231004,22271135);Guangdong Innovative Program (2019BT02Y335);Shenzhen Science and Technology Program (KQTD20210811090112004,JCYJ20210324120205016,JCYJ20210324105005015).
Indole-based atropisomers are a very important class of axially chiral compounds.However,the atroposelective synthesis of axially chiral 2-arylindole remains largely unexplored.In this study,we report the successful s...
funded by the Key Projects of Xinjiang Production and Construction Corps(2022AB007);the Key Projects of innovation team of Xinjiang eighth division Construction Corps 2023TD04);Liaoning Innovation Capability Fund(2021-NLTS-12-02).
The catalytic performance of different acidic catalysts for diethyl oxalate synthesis from the one-step transesterification of dimethyl oxalate and ethanol was evaluated.The effects of different factors(e.g.,acidity,e...
supported by the project:“Obtención de biocombustibles y compuestos químicos de alto valor agregado a partir de biomasas de desecho ricas en pectina”,CONAHCYT agreement:CB 255527-2016;the Fellowship with reference number:654271 from the Mexican Council for Science and Technology,CONAHCYT was assigned to Eva Estela Rivera Cedillo as PhD student.
The transformation of biomasses from agro-industrial waste can significantly impact the production of green chemicals from sustainable resources.Pectin is a biopolymer present in lignocellulosic biomass as Orange Peel...
supported by the National Natural Science Foundation of China(No.22001034);Jiangxi Provincial Natural Science Foundation(No.20212BAB213001);the Open Fund of the Jiangxi Province Key Laboratory of Synthetic Chemistry(No.JXSC202008)。
Polyoxometalates(POMs)have conducive properties such as controlled Bronsted and Lewis acidity,high thermal stability,nontoxic nature,tunable solubility,and less corrosiveness.POMs have been extensively applied in cata...
supported by the National Key Research and Development Program of China(No.2022YFB3805100);the National Natural Science Foundation of China(No.22222812 and 22178330);the Anhui Provincial Key Research and Development Plan(No.202104b11020030);the Natural Science Foundation of Anhui Province(No.2108085MB33).
A series of poly(alkyl-biphenyl pyridinium)anion exchange membranes(AEMs)with a hydrophobic side chain were prepared for mono-/divalent anion separation using electrodialysis(ED).A poly(alkyl-biphenyl pyridinium)polym...
The authors acknowledge the financial support from the Shenzhen Innovation of Science and Technology Commission(20200925151614002);the Guangdong Provincial Key Laboratory of Catalysis(2020B121201002)。
Propargylic alcohols have been known as useful substrates in a wide range of asymmetric reactions.In particular,chiral phosphoric acid(CPA)catalyzed reactions of functionalized propargylic alcohols have opened robust ...
This work was supported by the NSFC(Grant 21772019);the Venture and Innovation Support Program for Chongqing Overseas Returnees(cx2019007 and cx2020047)。
We here report a direct ring-opening/semipinacol rearrangement reaction of 4-(1-hydroxycyclobutyl)-1,2,3-triazole,in which N-acyl substituted 1,2,3-triazole was generated in situ and would trigger thermo-dynamically c...