RHODIUM

作品数:162被引量:179H指数:7
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相关领域:理学更多>>
相关作者:王佰全李存耀丁云杰姜淼刘佳更多>>
相关机构:南开大学中国科学院大学中国科学院华东师范大学更多>>
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相关基金:国家自然科学基金国家重点基础研究发展计划中国博士后科学基金国家高技术研究发展计划更多>>
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Rhodium/Ming-Phos-catalyzed asymmetric annulation reaction of silacyclobutanes with terminal alkynes
《Green Synthesis and Catalysis》2024年第3期205-210,共6页Yue Sun Kaida Zhou Chun Ma Zhiming Li Junliang Zhang 
the funding support of the National Key R&D Program of China(No.2021YFF0701601);NSFC(Nos.22031004 and 21921003);Shanghai Municipal Education Commission(No.20212308);Science and Technology Commission of Shanghai Municipality(No.23ZR1404800).
Asymmetric ring-expansion reactions of silacyclobutanes(SCBs)with alkynes have evolved as one of the powerful protocols for the construction of silicon-stereogenic compounds.However,the achievement of highly enantiose...
关键词:Rhodium-catalysis Asymmetric annulation reaction Silicon-stereogenic Silacyclobutanes Terminal alkynes 
Rhodium(Ⅰ)-Catalyzed Enantioselective C(sp^(3))-H Functionalization via Carbene-Induced Asymmetric Intermolecular C-H Insertion
《Chinese Journal of Chemistry》2021年第7期1911-1915,共5页Bo Liu Ming-Hua Xu 
Financial support from the National Natural Science Foundation of China(Nos.21971103,21672229);the National Science&Technology Major Project"Key New Drug Creation and Manufacturing Pro-gram",China(No.2018ZX09711002-006);the Guangdong Provincial Key Laboratory of Catalysis(No.2020B121201002)is gratefully acknowledged.
Main observation and conclusion Transition-metal-catalyzed C-H insertion of metal-carbene represents an excellent and powerful approach for C-H functionalization.However,despite remarkable advances in metal-carbene ch...
关键词:Asymmetric catalysis C-H functionalization CARBENE C-H insertion RHODIUM 
Rh(Ⅰ)-catalyzed regio-and enantioselective allylic alkylation of Meldrum's acid
《Chinese Chemical Letters》2021年第1期385-388,共4页Min Liu Haiying Zhao Changkun Li 
financially supported by the National Natural Science Foundation of China(NSFC,Nos.21602130 and 21961023);the startup funding from Shanghai Jiao Tong University.
A Rh(Ⅰ)-catalyzed highly regio-and enantioselective allylic alkylation of Meldrum acid with racemic allylic substrates bearing alkyl groups has been developed.The applying of chiral bisoxazopinephosphine ligand is es...
关键词:RHODIUM Bisoxazolinephosphine Allylic substitution Meldrum’s acid Asymmetric catalysis 
Design and Synthesis of Polymeric Chiral Bicyclo[3.3.0] Diene as Reusable Ligand for Rhodium-Catalyzed Asymmetric 1,4-Addition
《Chinese Journal of Chemistry》2013年第1期119-122,共4页Hongyu Yang Minghua Xu 
Acknowledgement Financial support from the National Natural Science Foundation of China (Nos. 20632060, 20972172, 21021063), and the Chinese Academy of Sciences is greatly acknowledged.
A series of A-B type sterically regular bicyclio[3.3.0] diene-based polymers were designed and synthesized as immobilized chiral diene ligands for asymmetric catalysis. With polymeric diene 6b, good to excellent enant...
关键词:asymmetric catalysis chiral ligand DIENE RHODIUM IMMOBILIZATION 
Rhodium catalyzed asymmetric Pauson-Khand reaction using SDP ligands
《Science China Chemistry》2006年第1期81-87,共7页FAN Baomin1, LI Shen2, XIE Jianhua2, WANG, Lixin2, TU Yongqiang1 & ZHOU Qilin2 1. State Key Laboratory of Applied Organic Chemistry,Lanzhou University,Lanzhou 730000,China 2. State Key Laboratory of Elemento-organic Chemistry,Nankai University,Tianjin 300071, China 
This work was supported by the National Natural Science Foundation of China (Grant Nos. 20132010 and 20272026); the Major State Basic Research Development Program (Grant No. G2000077506); the Ministry of Education of China and the Committee of Science and Technology of Tianjin City for financial support.
The activity and enantiocontrol ability of the chiral catalysts prepared from spiro di-phosphine ligands, SDP, and rhodium precursor were investigated in the asymmetric catalytic Pau-son-Khand reaction. The results sh...
关键词:Pauson-Khand reaction  ASYMMETRIC catalysis  DIPHOSPHINE ligand  rhodium. 
Asymmetric Catalytic Hydrogenation Using Rhodium Diphosphinites Derived From D-glucose and D-mannitol被引量:1
《Chinese Chemical Letters》2000年第7期587-588,共2页Peng JIANG Shi Jie LU(State Key Laboratory of Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000) 
Three diphosphinites were synthesized for preparing rhodium-diphosphinite complexes. The complexes were used for asymmetric catalytic hydrogenation of amino acid precursor alpha-acetamidocinnamic acid and its methyl e...
关键词:asymmetric catalysis hydrogenation rhodium diphosphinites alpha-acetamidocinnic acid 
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