REDUCTION

作品数:1993被引量:3721H指数:19
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相关作者:李海涛汪蕙杨华中彭映林郑雅杰更多>>
相关机构:中南大学东南大学清华大学上海大学更多>>
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相关基金:国家自然科学基金国家重点基础研究发展计划中国博士后科学基金国家高技术研究发展计划更多>>
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Reduction of Tertiary Carbon Radicals via Asymmetric Hydrogen Atom Transfer(AHAT)
《Chinese Journal of Chemistry》2024年第24期3414-3428,共15页Xue Han Chuan He 
the National Natural Science Foundation of China(22122102,22271134);Guangdong Provincial Key Laboratory of Catalysis(No.2020B121201002);Guangdong Peari River Talent Program(2019QN01Y628);ShenzhenScience and Technology Innovation Committee(RCJC20221008092723013,JCYJ20230807093104009).
In the past two decades,the development of asymmetric radical reactions has achieved tremendous progress,which has emerged as a powerful tool for the synthesis of chiral molecules in synthetic chemistry.Among the dive...
关键词:AHAT Radical reactions Asymmetric synthesis Enantioselective radical reactions Hydrogen atom transfer CHIRALITY REDUCTION Synthetic methods 
Unlocking Biomolecular Activity through Pd-Catalyzed Azides Reduction
《Chinese Journal of Chemistry》2024年第19期2305-2315,共11页Fang Fu Wei Xiong Xinyan Xu Yongjie Liu Ming Li Qianqian Qi Xingyu Liu Yuanyuan Zhang Tian Tian Xiang Zhou 
the National Natural Science Foundation of China(Nos.22177089,21721005,92153303,22037004,22177088);the Fundamental Research Funds for the Central Universities(2042021kf0211);Translational Medicine and Interdisciplinary Research Joint Fund of Zhongnan Hospital of Wuhan University(Grant No.ZNJC202309).
Comprehensive Summary Pd-mediated bioorthogonal cleavage reactions have been extensively utilized in the activation of prodrug molecules,precise regulation of protein function,and cellular engineering.However,the avai...
关键词:Decaging strategy PD-CATALYZED Azides reduction Biomolecular activation RNA regulation Biological activity Bioorganic chemistry PRODRUGS 
Preferential Formation of Ethylene via Electrocatalytic CO_(2) Reduction on Mesoporous Cu_(2)O Nanoparticles:Synergistic Effects of Pore Structure Confinement and Surface Amine
《Chinese Journal of Chemistry》2024年第16期1846-1852,共7页Haifeng Zhang Dun Li Zhifang Chen Yingying Wang Haoyu Sun Feng Liu Maochang Liu Yiqun Zheng Hongwen Huang 
financially supported by Shandong Provincial Natural Science Foundation(No.ZR2022MB120&ZR2020MB048);the University Feature Laboratory for Energy Conversion and Nanocatalysis of Shandong Province;Hundred Outstanding Talent Program of Jining University(No.2020ZYRC05).
We present a facile synthetic strategy to create mesoporous Cu_(2)O nanocrystals with tunable pore structures and surface functional groups of amine derivatives for efficient and preferable electrochemical conversion ...
关键词:AMINES ETHYLENE Cuprous oxide CO_(2)reduction Mesoporous materials 
Electrochemical Reduction of Benzo[b]thiophene 1,1-Dioxides with HFIP as Hydrogen Donor被引量:1
《Chinese Journal of Chemistry》2024年第6期585-591,共7页Ming-Zhong Guo Mei-Jin Mou Zhuo Chen Shao-Fei Ni Ming Li Li-Rong Wen Lin-Bao Zhang 
supported by the National Natural Science Foundation of China(21801152 and 21572110);We thank the Youth Innovation Science and Technology Plan of Colleges and Universities in Shandong Province(2021KJ076).
A straightforward electrochemical reduction of benzo[b]thiophene 1,1-dioxides with HFIP as the hydrogen donor has been reported in an undivided cell under metal-free conditions.Moreover,the tolerance of various functi...
关键词:ELECTROCHEMISTRY REDUCTION Benzo[b]thiophene 1 1-dioxides DEUTERIUM Hydrogen source 
Promoting Electrocatalytic CO_(2) Reduction to CO via Sulfur-Doped Co-N-C Single-Atom Catalyst被引量:5
《Chinese Journal of Chemistry》2023年第24期3553-3559,共7页Zhiming Wei Yuhang Liu Jie Ding Qinye He Qiao Zhang Yueming Zhai 
financially supported by National Natural Science Foundation of China(No.21974103);the start-up funds of Wuhan University and the Experimental Supporting System at Shanghai Synchrotron Radiation Facility.
Electrocatalytic reduction of CO_(2) to fuels and chemicals possesses huge potential to alleviate current environmental crisis.Heteroatom doping in metal-nitrogen-carbon(M-N-C)single-atom catalysts(SACs)has been found...
关键词:ELECTROCATALYTIC CO_(2)reduction Doping Heterogeneous catalysis Single-atom catalysts ATR-SEIRAS 
Engineering Coordination Environment of Cobalt Center in Molecular Catalysts for Improved Photocatalytic CO_(2) Reduction
《Chinese Journal of Chemistry》2023年第23期3305-3310,共6页Yuchen Wang Jihong Zhang Wei Yang Weixue Tao Keying Tao Jihua Deng Wenjie Shi Dichang Zhong Tongbu Lu 
supported by the National Key R&D Program of China(2022YFA1502902);the National Natural Science Foundation of China(22271218,22071182,22201209,and 21931007);the Research Fund Program of Guangdong Provincial Key Laboratory of Fuel Cell Technology(FC202210).
The creation of effective and inexpensive catalysts is essential for photocatalytic CO_(2) reduction.Homogeneous molecular catalysts,possessing definite crystal structures,are desirable to study the relationship betwe...
关键词:Co(II)-based homogeneous catalysts Coordination microenvironment PHOTOCATALYSIS CO_(2)reduction Homogenous catalysis 
Application of HSAB Theory in the Selective Reduction of Quinoline
《Chinese Journal of Chemistry》2023年第19期2446-2452,共7页Tianwei Liu Jianghua He Yuetao Zhang 
supported by the National Natural Science Foundation of China(Grant Nos.21871107,22225104,21975102,22071077).
It is very important to develop efficient synthetic strategies for site-specific functionalization of tetrahydroquinolines due to their indispensable roles in pharmaceutical and agrochemical industries.We apply hard/s...
关键词:HYDROBORATION HYDROSILYLATION Organocatalysis Quinoline REDUCTION SELECTIVITY 
Tunable System for Electrochemical Reduction of Ketones and Phthalimides被引量:2
《Chinese Journal of Chemistry》2021年第12期3297-3302,共6页Yaxin Wang Jianyou Zhao Tianjiao Qiao Jian Zhang Gong Chen 
We are grateful to the National Natural Science Foundation of China(No.22001128);the National Science Foundation of Jiangsu Province(No.BK20200847);the National Science Foundation of Nanjing University of Chinese Medicine(No.NZY22001128).
Herein,we report an efficient,tunable system for electrochemical reduction of ketones and phthalimides at room temperature without the need for stoichiometric external reductants.By utilizing NaN_(3) as the electrolyt...
关键词:ELECTROCHEMISTRY REDUCTION KETONES PHTHALIMIDES Radical reactions 
Electrosynthesis of Azobenzenes Directly from Nitrobenzenes被引量:3
《Chinese Journal of Chemistry》2021年第12期3334-3338,共5页Yanfeng Ma Shanghui Wu Shuxin Jiang Fuhong Xiao Guo-Jun Deng 
This work was supported by the National Natural Science Foundation of China(Nos.21871226,21502160,21572194);the Scientific Research Fund of Hunan Provincial Education Department(No.19B564).
The electrochemical reduction strategy of nitrobenzenes is developed.The chemistry occurs under ambient conditions.The protocol uses inert electrodes and the solvent,DMSO,plays a dual role as a reducing agent.Its synt...
关键词:Azo compounds Nitro reduction ELECTROCHEMISTRY NITROBENZENES Green chemistry 
Arificial Leaves for Solar Fuels被引量:2
《Chinese Journal of Chemistry》2021年第6期1450-1458,共9页Gong Zhang Bin Liu Tuo Wang Jinlong Gong 
the National Key R&D Program of China(2016YFB0600901);the National Natural Science Foundation of China(21525626,21722608,51861125104);the Natural Science Foundation of Tianjin City(18JCJQJC47500);the Program of Introducing Talents of Discipline to Universities(BP0618007)for financial support.
Large amounts of anthropogenic CO_(2) emissions associated with increased fossil fuel consumption have led to global warming.Upgrading CO_(2) and water into solar fuels such as hydrogen,methanol,ethanol,etc.,is believ...
关键词:CO_(2)reduction Water splitting PHOTOELECTROCHEMISTRY ELECTROCHEMISTRY PHOTOSYNTHESIS 
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